• Title/Summary/Keyword: Separation condition

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A Study on the Separation of $CO_2$from Flue Gas by Chemical Absorption (화학흡수법에 의한 연소폐가스 중 지구온난화 가스 $CO_2$분리에 관한 연구)

  • 안성우;김영국;송호철;박진원
    • Journal of Energy Engineering
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    • v.6 no.2
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    • pp.203-211
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    • 1997
  • This study is on the separation of Global warming effect gas, CO$_2$by chemical absorption from mixture of CO$_2$-N$_2$which was modeled after flue gas of fire power plant. Investigation of optimum condition for absorbent was carried out by using sparged vessel apparatus. Through packed tower experiments, applicabilities of two absorption models were tested by comparing experimental results with theoretical values. Absorbent used in the experiments was Monoethanolamine (MEA) and gas mixture was made in the mole composition of 15% CO$_2$and 85% N$_2$. Through estimations of CO$_2$loading and CO$_2$removal efficiency, optimum concentration of absorbent was found in the range of 4-5 M. To find a rate of absorption, an enhancement factor was introduced. Values of rate of absorption were calculated by Film model and Higbie model, respectively. Higbie model showed good agreement with experimental results. Therefore, this models is considered to be applicable to the CO$_2$separation process for flue gas from fire power plant.

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Design of Naphtha Splitter Unit with Petlyuk Distillation Column Using Aspen HYSYS Simulation (Aspen HYSYS를 이용한 나프타 분리공정의 Petlyuk Distillation Column 설계)

  • Lee, Ju-Yeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.21-27
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    • 2018
  • FRN (Full range Naphtha) is distilled from crude oil in a Naphtha Splitter Unit and is separated into the Light Straight Naphtha, Heavy Naphtha, and kerosene according to the boiling point in sequence. This separation is conducted using a series of binary-like columns. In this separation method, the energy consumed in the reboiler is used to separate the heaviest components and most of this energy is discarded as vapor condensation in the overhead cooler. In this study, the first two columns of the separation process are replaced with the Petlyuk column. A structural design was exercised by a stage to stage computation with an ideal tray efficiency in the equilibrium condition. Compared to the performance of a conventional system of 3-column model, the design outcome indicates that the procedure is simple and efficient because the composition of the liquid component in the column tray was designed to be similar to the equilibrium distillation curve. An analysis of the performance of the new process indicated an energy saving of 12.3% under same total number of trays and with a saving of the initial investment cost.

Separation of Neodymium from NdEeB Permanent Magnetic Scrap (NdFeB계 영구자석 스크랩으로부터 네오디뮴의 분리회수)

  • Yoon Ho-Sung;Kim Chul-Joo;Lee Jin-Yeung;Kim Sung-Don;Kim Joon-Soo;Lee Jae-Chun
    • Resources Recycling
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    • v.12 no.6
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    • pp.57-63
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    • 2003
  • In this study, the separation of neodymium was investigated from NdFeB permanent magnet scrap. Decomposition and leach-ing process of NdFeB permanent magnet scrap by oxidation roasting and sulfuric arid leaching were examined. Neodymium could be separated from iron by double salt precipitation using sodium sulfate. The optimum conditions established for decom-position and leaching are as follows: oxidation roasting temperature is $500^{\circ}C$ for sintered scrap and $700^{\circ}C$ for bonded scrap, concentration of sulfuric acid in leaching solution is 2.0 M, leaching temperature and time is $50^{\circ}C$ and 2 hrs, and pulp density is 15%. The leaching yield of neodymium and iron was 99.4% and 95.7% respectively. The optimum condition for separation of neodymium by double-salt precipitation was 2 equivalents of sodium sulfate and $50^{\circ}C$ The yield of neodymium was above 99.9%.

Numerical Analysis of Stall Characteristics for Turboprop Aircraft (터보프롭 항공기의 실속 특성 수치해석)

  • Park, Young Min;Chung, Jin Deog
    • Aerospace Engineering and Technology
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    • v.11 no.2
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    • pp.65-72
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    • 2012
  • Numerical simulations were performed to study the stall characteristics of turboprop aircraft. Stall characteristics were qualitatively investigated using the computational results of various configurations based on the combinations of propeller and high lift device. For the analysis of stall characteristics, three-dimensional Navier-Stokes solver with Spalart-Allmaras turbulence model was used and the relative motion between propeller and wing was simulated using sliding mesh technique. For the cruise configurations, major flow separation was occurred at the fuselage/wing fairing and the separation was reduced under propeller slipstream condition. For the high lift device configuration without propeller, major flow separation was occurred at the outboard side of nacelle. With rotating propeller, early stall onset due to low relative velocity and high effective angle of attack was observed on the outboard wing section. Regarding rotating direction of propeller, inboard-down direction was preferred due to the stall delay effect of propeller slipstream.

NUMERICAL INVESTIGATION OF PLUME-INDUCED FLOW SEPARATION FOR A SPACE LAUNCH VEHICLE (우주발사체의 플룸에 따른 유동박리 현상에 대한 수치적 연구)

  • Ahn, S.J.;Hur, N.;Kwon, O.J.
    • Journal of computational fluids engineering
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    • v.18 no.2
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    • pp.66-71
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    • 2013
  • In this paper, the supersonic flows around space launch vehicles have been numerically simulated by using a 3-D RANS flow solver. The focus of the study was made for investigating plume-induced flow separation(PIFS). For this purpose, a vertex-centered finite-volume method was utilized in conjunction with 2nd-order Roe's FDS to discretize the inviscid fluxes. The viscous fluxes were computed based on central differencing. The Spalart-Allmaras model was employed for the closure of turbulence. The Gauss-Seidel iteration was used for time integration. To validate the flow solver, calculation was made for the 0.04 scale model of the Saturn-5 launch vehicle at the supersonic flow condition without exhaust plume, and the predicted results were compared with the experimental data. Good agreements were obtained between the present results and the experiment for the surface pressure coefficient and the Mach number distribution inside the boundary layer. Additional calculations were made for the real scale of the Saturn-5 configuration with exhaust plume. The flow characteristics were analyzed, and the PIFS distances were validated by comparing with the flight data. The KSLV-1 is also simulated at the several altitude conditions. In case of the KSLV-1, PIFS was not observed at all conditions, and it is expected that PIFS is affected by the nozzle position.

Accurate Measurement of Isotope Amount Ratios of Lead in Bronze with Multicollector Inductively Coupled Plasma Mass Spectrometry

  • Lee, Kyoung-Seok;Kim, Jin-Il;Yim, Yong-Hyeon;Hwang, Euijin;Kim, Tae Kyu
    • Mass Spectrometry Letters
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    • v.4 no.4
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    • pp.87-90
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    • 2013
  • Isotope amount ratios of lead in a bronze sample have been successfully determined using multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS). Matrix separation conditions were tested and optimized using ion exchange chromatography with anion-exchange resin, AG1-X8, and sequential elution of the 0.5 M HBr and 7 M $HNO_3$ to separate lead from very high contents of copper and tin in bronze matrix. Mercury was also removed efficiently in the optimized separation condition. The instrumental isotope fractionation of lead in the MC-ICP-MS measurement was corrected by the external standard sample bracketing method using an external standard, NIST SRM 981 lead common isotope ratio standard followed by correction of procedure blank to obtain reliable isotope ratios of lead. The isotope ratios, $^{206}Pb/^{204}Pb$, $^{207}Pb/^{204}Pb$, $^{208}Pb/^{204}Pb$, and $^{208}Pb/^{206}Pb$, of lead were determined as $18.0802{\pm}0.0114$, $15.5799{\pm}0.0099$, $38.0853{\pm}0.0241$, and $2.1065{\pm}0.0004$, respectively, and the determined isotope ratios showed good agreement with the reference values of an international comparison for the same sample within the stated uncertainties

Heat Transfer and Flow Measurements on the Turbine Blade Surface (터빈 블레이드 표면과 선형익렬에서의 열전달 및 유동측정 연구)

  • Lee, Dae Hee;Sim, Jae Kyung;Park, Sung Bong;Lee, Jae Ho;Yoon, Soon Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.5
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    • pp.567-576
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    • 1999
  • An experimental study has been conducted to investigate the effects of the free stream turbulence intensity and Reynolds number on the heat transfer and flow characteristics In the linear turbine cascade. Profiles of the time-averaged velocity, turbulence intensity, and Reynolds stress were measured in the turbine cascade passage. The static pressure and heat transfer distributions on the blade suction and pressure surfaces were also measured. The experiments were made for the Reynolds number based on the chord length, Rec = $2.2{\times}10^4$ to $1.1{\times}10^5$ and the free stream turbulence intensity, $FSTI_1$ = 0.6% to 9.1 %. The uniform heat flux boundary condition on the blade surface was created using the gold film Intrex and the surface temperature was measured by liquid crystal, while hot wire probes were used for the flow measurements. The results show that the free stream turbulence promotes the boundary layer development and delays the flow separation point on the suction surface. It was found that the boundary layer flows on the suction surface for all Reynolds numbers tested with $FSTI_1$ = 0.6% are laminar. It was also found that the heat transfer coefficient on the blade surface increases as the free stream turbulence intensity increases and the flow separation point moves downstream with an increasing Reynolds number. The results of skin friction coefficients are in good agreement with the heat transfer results in that for $FSTI_1{\geq}2.6%$, the turbulent boundary layer separation occurs.

Hydrogen Separation from Binary and Ternary Mixture Gases by Pressure Swing Adsorption (PSA 공정에 의한 이성분 및 삼성분 혼합기체로부터 수소분리)

  • Kang, Seok-Hyun;Jeong, Byung-Man;Choi, Hyun-Woo;Ahn, Eui-Sub;Jang, Seong-Cheol;Kim, Sung-Hyun;Lee, Byung-Kwon;Choi, Dae-Ki
    • Korean Chemical Engineering Research
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    • v.43 no.6
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    • pp.728-739
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    • 2005
  • An experiment and simulation were performed for hydrogen separation of mixtures by PSA (pressure swing adsorption) process on activated carbon. The binary ($H_2/Ar$; 80%/ 20%) and ternary ($H_2/Ar/CH_4$; 60%/ 20%/ 20%) mixtures were used to study the effects of feed composition. The cyclic performances such as purity, recovery, and productivity of 2bed-6step PSA process were experimentally and theoretically compared under non-isothermal and non-adiabatic conditions. The develped process produced the hydrogen with 99% purity and 75% recovery from both processes. Therefore, optimal separation condition was referred multicomponent gas mixtures.

Separation and Simulation for Carbon Dioxide from Flaring Gas Using Polysulfone Hollow Fiber Membrane (폴리술폰 중공사막을 이용한 Flaring Gas에서의 이산화탄소 분리 및 전산모사)

  • Lim, Joo Hwan;Lee, Chung Seop;Kim, Hack Eun;Bae, Myong Won;Mo, Yong Gi;Ha, Seong Yong
    • Membrane Journal
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    • v.25 no.2
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    • pp.99-106
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    • 2015
  • Polysulfone (PSF) hollow fiber membrane was prepared to separate $CO_2$ from the flaring gas. Fabricated PSF membrane system was fulfilled under 1 stage, 2 stage membrane process and simulation in order to confirm the operating condition for 99% of $CH_4$ and 1% of $CO_2$ concentration. Also, $25Nm^3/h$ bench scale $CO_2$ separation membrane system was operated under 1% of $CO_2$ concentration during 100 hr, and $CH_4$ recovery ratio was 98%.

Analysis of a Hydrogen Generation Membrane Reactor (수소 생산용 막반응기의 해석)

  • Kim Hyung Gyu;Suh Jung Chul;Baek Young Soon
    • Journal of the Korean Institute of Gas
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    • v.8 no.3 s.24
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    • pp.16-23
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    • 2004
  • A membrane reactor concept, which combines the typical characteristics of chemical reaction with separation process, has been analyzed and simulated in this study. The advantages of the use of a membrane reactor include chemical equilibrium shift towards higher reactant conversion and purer product than the traditional reactors. A membrane reactor model which incorporates a catalytic reaction zone and a separation membrane is proposed. The water-gas shift reaction to produce hydrogen was chosen as a model reaction to be investigated. The membrane reactor is divided into smaller parts by number of n and each part (named cell), which contains both reaction and product separation function is modeled. One of the membrane outlet streams is connected to the next cell, which is repeated up to the last cell. The simulation results can be used for various purposes including decision of optimum operating condition and membrane reactor design.

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