DOI QR코드

DOI QR Code

폴리술폰 중공사막을 이용한 Flaring Gas에서의 이산화탄소 분리 및 전산모사

Separation and Simulation for Carbon Dioxide from Flaring Gas Using Polysulfone Hollow Fiber Membrane

  • 투고 : 2014.12.06
  • 심사 : 2015.02.23
  • 발행 : 2015.04.30

초록

Flaring gas에서 $CO_2$ 제거를 위해 폴리술폰 고분자를 이용한 중공사막을 제조하였다. 제조된 중공사막은 1단과 2단 공정의 전산모사와 실제 공정을 통해서 $CH_4$ 농도 99% 이상 $CO_2$ 농도 1% 미만의 운전조건과 성능을 확인하였다. 또한 $25Nm^3/h$ 급 bench scale $CO_2$ 분리막 연속공정에서 100시간의 운전시간 동안 $CO_2$의 농도를 1% 미만으로 안정적으로 운전하였고 이때의 $CH_4$ 회수율은 약 98%였다.

Polysulfone (PSF) hollow fiber membrane was prepared to separate $CO_2$ from the flaring gas. Fabricated PSF membrane system was fulfilled under 1 stage, 2 stage membrane process and simulation in order to confirm the operating condition for 99% of $CH_4$ and 1% of $CO_2$ concentration. Also, $25Nm^3/h$ bench scale $CO_2$ separation membrane system was operated under 1% of $CO_2$ concentration during 100 hr, and $CH_4$ recovery ratio was 98%.

키워드

참고문헌

  1. A. J. Ragauskas, C. K. Williams, B. H. Davison, G. Britovsek, J. Cairney, C. A. Eckert, et al., "The path forward for biofuels and biomaterials", Science, 311, 484-489 (2006). https://doi.org/10.1126/science.1114736
  2. Michael F. Farina, Flare gas reduction recent global trends and policy considerations, GE Energy global strategy and planning (2010).
  3. K. S. Jang, W. J. Cho, and J. W. Go, "Introduction of DME process", Daewoo engineering Journal, 25, 153-162 (2009).
  4. B. Freeman, "Assessment of post-combustion capture technology developments," Electric Power Research Institute, 1-125 (2007).
  5. J. T. Chung, C. S. Lee, H. C. Koh, S. Y. Ha, S. Y. Nam, W. J. Jo, and Y. S. Baek, "Polymeric membrane modules for substituting the $CO_2$ absorption column in the DME", Membr. J., 22, 142 (2012).
  6. H. C. Koh, S. Y. Ha, and S. Y. Nam, "Preparation and properties of hollow fiber membrane for gas separation using CTA", Membr. J., 21, 98 (2010).
  7. S. J. Kim, S. M. Woo, H. Y. Hwang, H. C. Koh, S. Y. Ha, H. S. Choi, and S. Y. Nam, "Preparation and properties of chlorine resistance loose reverse osmosis hollow fiber membrane", Membr. J., 20, 304 (2010).
  8. I. Pinnau and B. D. Freeman, "Formation and modification of polymeric membranes", American Chemical Society, Washington DC membr. Sci., 744, 1 (1999).
  9. Muller, Dr. Heinz-Joachim and Floyd, Elizabeth, "Modified membrane", Australian patent office AU 2002214802 B2, 7, 25 (2002).
  10. J. Phattaranawik, R. Jiraratananon, and A. G. Fane, "Effect of pore size distribution and air flux on mass transport in direct contact membrane distillation", J. Membr. Sci., 215, 75 (2003). https://doi.org/10.1016/S0376-7388(02)00603-8
  11. S. J. Kim, H. E. Kim, W. J. Cho, and S. Y. Ha, "Membrane process development for $CO_2$ separation of flaring gas", Membr. J., 23, 384 (2013).