• 제목/요약/키워드: Separation Time

검색결과 1,792건 처리시간 0.027초

방향계 폴리에테르이미드막의 물-알콜 혼합액의 투과증발 특성에 관한 연구 : II.skin layer의 density변화에 의한 물-이소프로판올 혼합액의 투과증발 (Study on the Pervaporation Characteristic of Water-alcohol Mixtures through Aromatic Polyetherimide Membranes : II. the Pervaporation of Water-isopropanol Mixtures by the Density Change of Skin Layer)

  • 김상균;제갈종건;이규호
    • 공업화학
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    • 제8권5호
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    • pp.853-859
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    • 1997
  • 표면층에 치밀층 구배 구조를 갖는 비대칭 폴리에테르이미드막에 대하여 치밀 구조층의 화학적 개질을 통한 막 형태의 변화와 물/이소프로판올 혼합액의 투과증발 거동을 연구하였다. 치밀 정도는 증발 시간에 의해 조절되었고, 증발 시간이 0분에서 4분으로 증가되었을 때, 투과량은 감소하였고, 선택도는 증가하였다. 또한, 수산화나트륨 용액으로 개질 된 폴리에테르이미드막을 통한 투과증발 거동은, 치밀 표면층의 개질 시간이 증가될수록 선택성은 증가하였고, 투과량은 감소하였다. 전자현미경으로 확인된 형태 변화는 개질 시간의 증가에 따라 치밀 표면층의 density 증가를 보여주었고, 이러한 결과는 위의 관찰들과 일치하였다.

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열적으로 유도된 상 분리에 의해 제조된 폴리스티렌 미세 다공성 막 (Microporous Polystyrene Membranes Produced via Thermally Induced Phase Separation)

  • Song, Seung-Won;Torkelson, John M.
    • 멤브레인
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    • 제5권3호
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    • pp.119-128
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    • 1995
  • 폴리스티렌과 싸이클로헥산 용액으로부터 제조된 멤브레인의 미세구조 형성에 미치는 coarsening의 효과를 주사전자현미경(SEM)을 이용하여 연구하였다. 고분자 용액의 열 분석은 DSC를 이용하여 행하여졌으며 demixing peak의 개시 온도로부터 binodal 곡선이 결정되었다. 열적으로 유도된 상 분리(TIPS) 공정과 freeze drying 기법을 이용하여 제조된 고분자 막의 미세 구조는 coarsening 시간과 quench 경로에 의해 큰 영향을 받음이 확인되었다. Spinodal decomposition이 상 분리 기구인 경우에는 멤브레인의 미세구조가 서로 잘 연결되고 거의 일정한 cell 크기를 갖게 되며, 용매를 제거하기 이전에 상 분리 시간을 증가시킴으로써 멤브레인의 pore 크기를 증가시킬 수 있음이 판명되었다. 또한 멤브레인의 cell 또는 pore 크기 증가는 coarsening time과 quench depth에 크게 의존함이 확인되었다. 본 연구에서는 특히 고분자 용액의 농도가 이로부터 제조되는 고분자 막의 구조에 미치는 역할을 규명하였다.

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개질 비대칭 폴리에테르이미드막을 통한 물-이소프로판올 혼합물 투과증발 분리: NaOH용액의 농도와 개질반응 시간에 따른 몰폴로지 변화 (Pervaporation Separation of Water-isopropanol Mixtures through Modified Asymmetric Polyetherimide Membrane: the Effect of NaOH Concentration and Modification Reaction Times on the Morphology of the Morphology of the Modified Membranes)

  • 김상균;제갈종건;이규호
    • 공업화학
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    • 제10권4호
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    • pp.515-522
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    • 1999
  • 상분리 방법으로 비대칭 폴리에테르이미드막을 제조하였고, 수산화나트륨 수용액으로 막의 표면층을 개질 했을 때의 몰폴로지 변화를 반응기간과 반응용액 농도에 대하여 살려보았다. 표면층 몰폴로지는 개질 용액의 농도가 증가함에 따라 치밀한 구조에서 둥근 입자상의 형태로 변화되었고, 개질 시간이 증가될수록 치밀 영역이 증가되었다. 그러나 반응 농도가 아주 높거나 장시간 개질을 하면 비대칭 폴리에테르이미드막의 표면에서 치밀 구조층이 없어지는 결과를 나타냈다. 결과적으로, 표면의 몰폴로지는 개질 용액의 농도와 시간에 따라 크게 좌우됨을 알 수 있었다. 이러한 결과는 폴리에테르이미드가 수산화나트륨에 의해서 폴리아믹산으로 가수분해되면서 나타나는 현상으로 추측되었다.

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Blind Source Separation of Instantaneous Mixture of Delayed Sources Using High-Order Taylor Approximation

  • Zhao, Wei;Yuan, Zhigang;Shen, Yuehong;Cao, Yufan;Wei, Yimin;Xu, Pengcheng;Jian, Wei
    • ETRI Journal
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    • 제37권4호
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    • pp.727-735
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    • 2015
  • This paper deals with the problem of blind source separation (BSS), where observed signals are a mixture of delayed sources. In reference to a previous work, when the delay time is small such that the first-order Taylor approximation holds, delayed observations are transformed into an instantaneous mixture of original sources and their derivatives, for which an extended second-order blind identification (SOBI) approach is used to recover sources. Inspired by the results of this previous work, we propose to generalize its first-order Taylor approximation to suit higher-order approximations in the case of a large delay time based on a similar version of its extended SOBI. Compared to SOBI and its extended version for a first-order Taylor approximation, our method is more efficient in terms of separation quality when the delay time is large. Simulation results verify the performance of our approach under different time delays and signal-to-noise ratio conditions, respectively.

Fabrication and Simulation of Fluid Wing Structure for Microfluidic Blood Plasma Separation

  • Choe, Jeongun;Park, Jiyun;Lee, Jihye;Yeo, Jong-Souk
    • Applied Science and Convergence Technology
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    • 제24권5호
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    • pp.196-202
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    • 2015
  • Human blood consists of 55% of plasma and 45% of blood cells such as white blood cell (WBC) and red blood cell (RBC). In plasma, there are many kinds of promising biomarkers, which can be used for the diagnosis of various diseases and biological analysis. For diagnostic tools such as a lab-on-a-chip (LOC), blood plasma separation is a fundamental step for accomplishing a high performance in the detection of a disease. Highly efficient separators can increase the sensitivity and selectivity of biosensors and reduce diagnostic time. In order to achieve a higher yield in blood plasma separation, we propose a novel fluid wing structure that is optimized by COMSOL simulations by varying the fluidic channel width and the angle of the bifurcation. The fluid wing structure is inspired by the inertial particle separator system in helicopters where sand particles are prevented from following the air flow to an engine. The structure is ameliorated in order to satisfy biological and fluidic requirements at the micro scale to achieve high plasma yield and separation efficiency. In this study, we fabricated the fluid wing structure for the efficient microfluidic blood plasma separation. The high plasma yield of 67% is achieved with a channel width of $20{\mu}m$ in the fabricated fluidic chip and the result was not affected by the angle of the bifurcation.

Separation of Burnup Monitors in Spent Nuclear Fuel Samples by Liquid Chromatography

  • Joe, Kih-Soo;Jeon, Young-Shin;Kim, Jung-Suck;Han, Sun-Ho;Kim, Jong-Gu;Kim, Won-Ho
    • Bulletin of the Korean Chemical Society
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    • 제26권4호
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    • pp.569-574
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    • 2005
  • A coupled column liquid chromatography system was applied for the separation of the burnup monitors in spent nuclear fuel sample solutions. A reversed phase column was studied for the adsorption behavior of uranyl ions using alpha-hydroxyisobutyric acid as an eluent and used for the separation of plutonium and uranium. A cation exchange column prepared by coating 1-eicosylsulfate onto the reversed phase column was used for the separation of the lanthanides. In addition, retention of Np was checked with the reversed phase column and cation exchange column, respectively, according to the oxidation states to observe the interference effect for the separation of burnup monitors. This chromatography system showed a great reduction in separation time compared to a conventional anion exchange method. A good agreement from the burnup data was obtained between for this method and a conventional anion exchange method to within 1% of a difference for the spent nuclear fuel samples of about 40 GWD/MTU.

Zephyr 커널에서 커널 공간과 사용자 공간의 분리 구현 (Separation of Kernel Space and User Space in Zephyr Kernel)

  • 김은영;신동하
    • 대한임베디드공학회논문지
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    • 제13권4호
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    • pp.187-194
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    • 2018
  • The operating system for IoT should have a small memory footprint and provide low power state, real-time, multitasking, various network protocols, and security. Although the Zephyr kernel, an operating system for IoT, released by the Linux Foundation in February 2016, has these features but errors generated by the user code can generate fatal problems in the system because the Zephyr kernel adopts a single-space method that both the user code and kernel code execute in the same space. In this research, we propose a space separation method, which separates kernel space and user space, to solve this problem. The space separation that we propose consists of three modifications in Zephyr kernel. The first is the code separation that kernel code and user code execute in each space while using different stacks. The second is the kernel space protection that generates an exception by using the MPU (Memory Protection Unit) when the user code accesses the kernel space. The third is the SVC based system call that executes the system call using the SVC instruction that generates the exception. In this research, we implemented the space separation in Zephyr v1.8.0 and evaluated safety through abnormal execution of the user code. As the result, the kernel was not crashed by the errors generated by the user code and was normally executed.

규제액면기법의 전사방식 광조형 시스템을 위한 이형력 감소 (Reducing Separation Force for Projection Stereolithography based on Constrained Surface Technique)

  • 김혜정;하영명;박인백;김민섭;조광호;이석희
    • 한국정밀공학회지
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    • 제30권9호
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    • pp.1001-1006
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    • 2013
  • Projection-based stereolithography is divided into constrained-surface and free-surface type according to controlling liquid layer. The constrained-surface type has a uniform layer thickness due to the use of a projection window, which covers the pattern generator such as liquid crystal display. However, the adhered resin on the projection window causes trouble and requires great separation force when the cured layer is separated from the window. To minimize the separation force, we developed a system to measure the separation force. The influence of material covering the pattern generator and the resin temperature is investigated in the system. Several structures according to the resin temperature and the velocity of z-axis elevation are compared. As a result, the fabrication condition to minimize the separation force reduces the process time.

Numerical Analysis on Separation Dynamics of Strap-On Boosters in the Dense Atmosphere

  • Choi, Seongjin;Ko, Soon-Heum;Kim, Chongam;Rho, Oh-Hyun;Park, Jeong-joo
    • International Journal of Aeronautical and Space Sciences
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    • 제2권2호
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    • pp.1-18
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    • 2001
  • A numerical technique for simulating the separation dynamics of strap-on boosters jettisoned in the dense atmosphere is presented. Six degree of freedom rigid body equations of motion are integrated into the three-dimensional unsteady Navier-Stokes solution procedure to determine the dynamic motions of strap-ons. An automated Chimera overlaid grid technique is introduced to achieve maximum efficiency for multi-body dynamic motion and a domain division technique is implemented in order to reduce the computational cost required to find interpolation points in the Chimera grids. The flow solver is validated by comparing the computed results around the Titan IV launch vehicle with experimental data. The complete analysis process is then applied to the. H-II launch vehicle, the central rocket in japans space program, the CZ-3C launch vehicle developed in China and the KSR-III, a three-stage sounding rocket being developed in Korea. From the analyses, separation trajectories of strap-on boosters are predicted and aerodynamic characteristics around the vehicles at every time interval are examined. In addition, separation-impulse devices generally introduced for safe separation of strap-ons are properly modeled in the present paper and the jettisoning force requirements are examined quantitatively.

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건식비중분리법에 의한 고품질순환잔골재생산시스템의 개요 및 성능평가 (Outline and Performance Evaluation of High Quality Recycled Fine Aggregate Manufacturing System Using Drying Gravity Separation Method)

  • 김무한;김규용;최경렬;이도헌;송하영;노경민
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2006년도 춘계학술논문 발표대회 제6권1호
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    • pp.111-114
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    • 2006
  • Recently, it is increased on the concern for the reuse of waste concrete because of the shortage of natural aggregate and the increase of waste concrete. And recycled coarse aggregate is used variously, but the existing wet method producted recycled fine aggregate has problem like the high price facilities, the long time progress of the work and the poor of recycled fine aggregate. The aim of this study is to investigate outline and performance evaluation of the drying specific gravity separation method to product high duality recycled fine aggregate. Finally, this study is shown investigate process flowing of drying separation type with gravity manufacture, producte system and function of detail devices. The performance of the method of drying specific gravity separation is certificated as the qualities of recycled fine aggregate satisfied the KS

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