• Title/Summary/Keyword: Separation Process

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Separation of Cd(II) from Aqueous Solutions by A New Consecutive Process Consisting of Supported Liquid Membrane and Electrodialysis

  • Altin, Sureyya;Altin, Ahmet
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.14-21
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    • 2019
  • Supported liquid membrane process usually is used for recovering or enrichment of valuable metals in the industrial wastewater. But, even if the metals in the wastewater was separated with high chemical selectivity, it cannot be enough concentrated since separation performance of supported liquid membrane (SLM) process is limited by concentration gradient between feed solution and stripping solution. If metal concentration in the stripping solution to be enough low, transport of metal through membrane can be accomplishment constantly. Therefore, Electrodialysis (ED) has been placed after SLM process and the stripping solution of SLM was used as the feed solution for the ED process. Transport of ions in the solutions is successfully performed by ED process. Thus, the metal concentration in the stripping solution does not rise as to stop ion transport. Besides, valuable metals easily are concentrated by ED process for re-use. In this study, effects of operation parameters like initial Cd(II) concentration, HCl concentration in the feed solution of SLM and applied voltage are investigated on separation efficiency, flux and permeability of the both processes. As the feed solution concentration increased, all performance values has increased. When initial concentration of 100 mg/L is used, separation performances (SP) are 55% and 70%, for SLM and consecutive process, respectively. The best HCl concentration in the feed solution of SLM has determined as 2 M, in this conditions SP are 64% and 72%, for SLM and consecutive process, respectively. With increased of applied voltage on ED process, SP of the consecutive process has been raised from 72% to 83%. According to the obtained experimental data, consecutive process has better separation performance than SLM. When the separation performances of both processes were compared for the same operating conditions, it was determined higher the separation efficiency, permeability and flux values of the consecutive process, 8%, 9% and %10.6, respectively. Consequently, the use of the consecutive process increases the performance efficiency of both processes. The consecutive process studied has quite a good chemical separation efficiency, and enrichment capability. Moreover, this process requires few water and energy.

Continuous Microalgae Separation Process Using Ultrasonic Waves (초음파를 이용한 미세조류 연속분리공정)

  • Kim, Sung Bok;Jeong, Sang Hwa
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.4
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    • pp.407-413
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    • 2015
  • Research for renewable energy is being performed since it has the merits of little pollution of the environment and sustainable energy resources. Microalgae is attractive as a renewable energy resource. Biomass of the microalgae can be produced by mass culturing, and bulk harvest technology of is needed to produce biomass continuously. Recently, ultrasonic waves were used to harvest the cultivated microalgae continuously. In this study, the separation process using ultrasonic waves was performed to effectively harvest the microalgae. An ultrasonic wave separation resonator was designed and manufactured based on the acoustic field analysis. Separation experiments using design of experiment were carried out, and the influence of experimental variables from the ultrasonic wave separation process was investigated. Mixing conditions of variables were estimated to obtain high separation efficiency and a large microalgae harvest. Experimental results for suitable mixing conditions were compared with simulation results calculated from the state equation.

The Concept of Synchronization in the Process of Separation-Individuation Between a Parent and an Adolescent

  • Moon, Duk-Soo;Bahn, Geon Ho
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.33 no.2
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    • pp.41-47
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    • 2022
  • Objectives: Humans experience the process of separating-individuating themselves from an object via the conflict between dependence and independence within the self. The separation-individuation theory focuses on the psychological process of individualizing oneself. Although adolescents' individuation from their parents is based on intrapsychic events, there is an increasing need for an intersubjective understanding of it. We applied intersubjectivity to adolescents and parents to interpret and find solutions for problems arising during their individuation process. Methods: This study retrospectively reviewed a case of a son and his father treated by the author. From the study subject, contents that represent adolescents and parents' interaction and separation in the individualization process were extracted and analyzed, and their experiences shared in this process were reconstructed from the therapist's perspective. Results: From the case involving an adolescent boy with conduct problems and his interactions with his father, the authors observed the phenomenon of intersubjectivity and proposed the concept of "synchronized individuation" between adolescents and parents. As adolescents rapidly grow and change, they experience various dynamic interactions with their parents. Through learning to tolerate the conflicts and ambivalent tension inherent in this individuation process, adolescents and their parents develop their new identity. Conclusion: "Synchronized individuation" should be understood as complementary to, rather than exclusive from, the existing concept of the separation and individuation. It offers a new paradigm with which to understand adolescent-parent conflicts in the process of separation-individuation.

Study on removal of microplastics using magnetic separation

  • Ueda, Reo;Akiyama, Yoko;Manabe, Yuichiro;Sato, Fuminobu
    • Progress in Superconductivity and Cryogenics
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    • v.24 no.3
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    • pp.12-18
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    • 2022
  • In recent years, the impact of microplastics (MPs) on ecosystems is a serious problem. Since MPs are difficult to recover once they are dispersed into the environment, it is important to remove them at the source. We proposed a magnetic separation of primary MPs (plastics manufactured in minute sizes) sized 10-100 ㎛ that has not been removed in the sewage process, based on the magnetic seeding process. In this study, we used magnetite as a magnetic seeding agent, and conducted magnetic separation experiments in the continuous process using a superconducting solenoidal magnet to investigate the feasibility of practical magnetic separation system of MPs. As a result, 85% separation rate was obtained by continuous separation using high gradient magnetic separation (HGMS) with hydrophobically treated magnetite as a magnetic seeding agent.

A Efficient Image Separation Scheme Using ICA with New Fast EM algorithm

  • Oh, Bum-Jin;Kim, Sung-Soo;Kang, Jee-Hye
    • Journal of the Korean Institute of Intelligent Systems
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    • v.14 no.5
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    • pp.623-629
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    • 2004
  • In this paper, a Efficient method for the mixed image separation is presented using independent component analysis and the new fast expectation-maximization(EM) algorithm. In general, the independent component analysis (ICA) is one of the widely used statistical signal processing scheme in various applications. However, it has been known that ICA does not establish good performance in source separation by itself. So, Innovation process which is one of the methods that were employed in image separation using ICA, which produces improved the mixed image separation. Unfortunately, the innovation process needs long processing time compared with ICA or EM. Thus, in order to overcome this limitation, we proposed new method which combined ICA with the New fast EM algorithm instead of using the innovation process. Proposed method improves the performance and reduces the total processing time for the Image separation. We compared our proposed method with ICA combined with innovation process. The experimental results show the effectiveness of the proposed method by applying it to image separation problems.

Development of Curdlan Separation Process with Density Gradient Centrfugation (Density Gradient를 이용한 식품소재를 커들란의 분리공정개발)

  • 김봉영;이중헌
    • KSBB Journal
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    • v.16 no.5
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    • pp.523-525
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    • 2001
  • Curdlan is one biopolymer composed of ${\beta}$1,3-glucan and dissolved in a alkali solution but formed salt under neutral or acid condition. It was produced by Agrobactrium species and the separation process is necessary to make pure curdlan from the culture broth. The pH swing separation method was as feasible separation process using solubility changes with the pH difference. however, this method requires a lot of acid and alkali solution also produces a lot of waste. Therefore, an efficient process which could save energy and minimize toxic waste was developed. A density gradient separation process was developed in this research. High density sucrose solution was used as a separation agent. Curdlan was separated from the culture broth when the density of the sucrose solution was 1.15 g/L. Since the curdlan was produced on the surface of cell wall. the pre-treatment of culture broth was necessary. Curdlan recovery yield was increased up to 83% with the homogenization of the culture broth and further increased up to 87% with the treatment of alkai-acid solution.

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Separation of Mixed Plastics using the Drum type Tribo-Electrostatic Separation Process (드럼형 마찰대전장치를 이용한 혼합플라스틱의 정전선별)

  • Kim Do Kyun;Cho Hee Chan;Jeon Ho Seok
    • Resources Recycling
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    • v.13 no.1
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    • pp.39-46
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    • 2004
  • Triboelectrostatic separation process is a technology that different particles charged after contact and rubbing different materials are separated in a high electric field. This technology has an advantage in that it can be used for separating non-conducting materials such as plastics unlike other electrostatic separation processes. There are two objectives in this study. One is to develop an effective continuous tribo-electrostatic separation process. The other is to apply the developed device for the separation of mixed plastics. Results show that almost all tested plastics reaches over 95% in yield and grade after separation.

Developmental Trend of Polyimide Membranes for Gas Separation (Polyimide계 기체분리막의 개발 동향)

  • Oh, Dae-Youn;Nam, Sang-Yong
    • Membrane Journal
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    • v.21 no.4
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    • pp.307-320
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    • 2011
  • Polymeric gas separation membrane is the fastest growing field in membrane separation process. Polymeric gas separation membrane process is competitive compare to cryogenic process and pressure swing adsorption process. Aromatic polymer materials such as polysulfones, polypheneylene oxides, polycarbonates and polyimides have been used for gas separation. Recently, glassy polymer likes polyimide in aromatic polymers has been developed for achievement of high selectivity and permeability coefficients. The accurate understanding on a type and structure of polymer material is very important, because the factor that polymer material affect gas separation property. In the study, trend and the development direction on synthesis and permeation properties of polyimide is confirmed.

EUTECTIC(LiCl-KCl) WASTE SALT TREATMENT BY SEQUENCIAL SEPARATION PROCESS

  • Cho, Yung-Zun;Lee, Tae-Kyo;Choi, Jung-Hun;Eun, Hee-Chul;Park, Hwan-Seo;Park, Geun-Il
    • Nuclear Engineering and Technology
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    • v.45 no.5
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    • pp.675-682
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    • 2013
  • The sequential separation process, composed of an oxygen sparging process for separating lanthanides and a zone freezing process for separating Group I and II fission products, was evaluated and tested with a surrogate eutectic waste salt generated from pyroprocessing of used metal nuclear fuel. During the oxygen sparging process, the used lanthanide chlorides (Y, Ce, Pr and Nd) were converted into their sat-insoluble precipitates, over 99.5% at $800^{\circ}C$; however, Group I (Cs) and II (Sr) chlorides were not converted but remained within the eutectic salt bed. In the next process, zone freezing, both precipitation of lanthanide precipitates and concentration of Group I/II elements were preformed. The separation efficiency of Cs and Sr increased with a decrease in the crucible moving speed, and there was little effect of crucible moving speed on the separation efficiency of Cs and Sr in the range of a 3.7 - 4.8 mm/hr. When assuming a 60% eutectic salt reuse rate, over 90% separation efficiency of Cs and Sr is possible, but when increasing the eutectic salt reuse rate to 80%, a separation efficiency of about 82 - 86 % for Cs and Sr was estimated.

Separation of Madecassoside and Madecassic Acid Isomers by High Performance Liquid Chromatography Using β -Cyclodextrin as Mobile Phase Additive

  • Kai, Guiqing;Pan, Jian;Yuan, Chuanxun;Yuan, Yuan
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.551-554
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    • 2008
  • An improved HPLC method for the separation of madecassoside isomers (madecassoside and asiaticoside-B) has been developed. The isomers can be separated with high resolution from extracts of Centella asiatica by HPLC using $\beta$-cyclodextrin as a mobile phase added on a $C_{18}$ column. The result shows that the isomers can be separated with a mobile phase consisting of methanol:water (50:50, v/v) with 4 mmol/L $\beta$-CD. To elucidate the mechanism of the separation of madecassoside and asiaticoside-B, this paper studied the separation of their aglycon parts (madecassic acid and terminolic acid), another pair of isomers. The isomers can also be separated with high resolution with a mobile phase consisting of methanol:water (65:35, v/v) with 4 mmol/L $\beta$-CD and the pH of the mobile phase was adjusted to 4. The paper also studied the separation of the two isomers by HPLC using $\alpha$-CD and Glucosyl-$\beta$-CD as a mobile phase additive in order to elucidate the mechanism of the separation process.