• Title/Summary/Keyword: Separation Point

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Study of Thermally Induced Phase Separation of Polyvinylidene Fluoride-Silica Mixture for the Preparation of Porous Polymeric Membrane (다공성 분리막 제조를 위한 폴리플루오르화비닐리덴-실리카 혼합물의 열유도상분리 연구)

  • Kim, Se Jong;Lee, Jeong Woo;Nam, Sang Yong
    • Membrane Journal
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    • v.27 no.2
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    • pp.189-198
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    • 2017
  • In this study, we used thermally induced phase separation (TIPS) to produce water treatment membrane and poly(vinylidene fluoride) (PVDF), silica with excellent mechanical properties and chemical resistance to evaluate characterization of the membrane. The diluents used for the characterization were dioctyl phthalate (DOP) and dibutyl phthalate (DBP). We observed the crystallization temperature, cloud point and SEM images to see the manufacture conditions according to the ratio of PVDF and silica. The crystallization temperature and cloud point increased with the contents of silica. Through the phase diagram drawn from these results, the conditions for the preparation of the membrane confirmed.

A Study on the 'In-between Space' of the Traditional Residential Space in Korea and Japan - Focused on Spatial Characteristics and Sociocultural Roles - ($\cdot$일 전통 주거공간의 '중간영역'에 관한 연구 - 공간적 특성과 사회문화적 역할을 중심으로 -)

  • Park Hyung-Jin;Park Se-Jung;Kim Moon-Duck
    • Korean Institute of Interior Design Journal
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    • v.14 no.3 s.50
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    • pp.84-94
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    • 2005
  • The purpose of this study is to establish the identity of the traditional residential space in Korea and Japan as analyzing the spatial characteristics and sociocultural roles of the 'in-between space' shown in their traditional dwelling space. Although they share culture area, it is meaningful to clarify the identity of both countries with many differences as the point of localization In globalization and the point of presenting the current and future directions of residential culture in both countries. Records and field studies have been carried out for the spatial characteristics and the sociocultural role focused on Ma-dang and Dae-chung in case of the 'in-between space' in Korean traditional dwellings and Inner housing, Doma, and Engawa in Japan. According to these findings, the spatial characteristics in common between Korea and Japan are open, half-open, separation, mitigation, integration, variation, continuation, hierarchy, mediation, and expansion. The 'in-between space', built by the separate Chae and Kan, of Korean traditional dwellings shows the separation by closed walls and the exclusive use by the fixed walls. In case of Japan, the integrated in-between space built by the separation of Kan shows open and connective tendencies and the variableness of walls has the tendency making ambiguous space with spatial softness. The sociocultural role of the 'in-between space' in Korean traditional dwelling space functions as the mitigation between the interior and exterior of the house as well as the male and female. Because the conception for protecting the private life is too weak, the sociocultural role of the 'in-between space' in Japanese traditional dwelling space seldom forms the space for an individual or the specific person among family. The space to welcome a guest functions as the mitigation between residents and outsiders as it is located in the inside of the private dwelling space.

A Study on Vehicle Big Data-based Micro-scale Segment Speed Information Service for Future Traffic Environment Assistance (미래 교통환경 지원을 위한 차량 빅데이터 기반의 미시구간 속도정보 서비스 방안 연구)

  • Choi, Kanghyeok;Chong, Kyusoo
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.21 no.2
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    • pp.74-84
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    • 2022
  • Vehicle average speed information which measured at a point or a short section has a problem in that it cannot accurately provide the speed changes on an actual highway. In this study, segment separation method based on vehicle big data for accurate micro-speed estimation is proposed. In this study, to find the point where the speed deviation occurs using location-based individual vehicle big data, time and space mean speed functions were used. Next, points being changed micro-scale speed are classified through gradual segment separation based on geohash. By the comparative evaluation for the results, this study presents that the link-based speed is could not represent accurate speed for micro-scale segments.

Dispersion in the Unsteady Separated Flow Past Complex Geometries (복합지형상에서 비정상 박리흐름에 의한 확산)

  • Ryu, Chan-Su
    • Journal of the Korean earth science society
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    • v.22 no.6
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    • pp.512-527
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    • 2001
  • Separated flows passed complex geometries are modeled by discrete vortex techniques. The flows are assumed to be rotational and inviscid, and a new techlnique is described to determine the stream functions for linear shear profiles. The geometries considered are the snow cornice and the backward-facing step, whose edges allow for the separation of the flow and reattachment downstream of the recirculation regions. A point vortex has been added to the flows in order to constrain the separation points to be located at the edges, while the conformal mappings have been modified in order to smooth the sharp edges and to let the separation points free to oscillate around the points of maximum curvature. Unsteadiness is imposed to the flow by perturbing the vortex location, either by displacing the vortex from the equilibrium, or by imposing a random perturbation with zero mean to the vortex in equilibrium. The trajectories of passive scalars continuously released upwind of the separation point and trapped by the recirculating bubble are numerically integrated, and concentration time series are calculated at fixed locations downwind of the reattachment points. This model proves to be capable of reproducing the trapping and intermittent release of scalars, in agreement with the simulation of the flow passed a snow cornice performed by a discrete multi-vortex model, as well as with direct numerical simulations of the flow passed a backward-facing step. The results of simulation indicate that for flows undergoing separation and reattachment the unsteadiness of the recirculating bubble is the main mechanism responsible for the intense large-scale concentration fluctuations downstream.

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Continuous Separation of Lysozyme from Egg White by Ion Exchange Column Chromatography (이온교환 칼럼 크로마토그래피를 이용한 난백에서 Lysozyme의 연속추출)

  • Park, Seong-Joon;Kim, Hyeon-Seok;Kim, Hyean-Wee;Ahn, Tae-Hoe;Park, Ki-Moon;Choi, Chun-Un
    • Korean Journal of Food Science and Technology
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    • v.22 no.6
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    • pp.711-715
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    • 1990
  • Continuous column chromatographic separation of lysozyme from egg white was investigated. A weak acid type cation exchange resin, Duolite C-464, was used because of high lysozyme recovery and ease of column operation in this experiment. The resin was equilibrated at $pH\;7.9{\pm}0.1$ in Na+form. Continuous lysozyme separation was processed by repeating cycles(one cycle : resin equilibration, flow egg white, rinse, lysozyme elution) in automated preparative Liquid Chromatography(LC) system(column size ; i.d. 50 mm, resin bed volumn ; 1020 ml). At comparison of UV levels in rinse end point and elution end point of every cycle, the UV levels of rinse end point are maintained below 30% for 19 cycles and that of elution end point are also maintained below 30% for 17 cycles, stably, but was increased above 50% after 18 cycle. That indicated the eluting ability of lysozyme was reduced conspicuously after 18 cycle in continuous cycling process. The recovery of lysozyme was maintained above 90% from one to 17 cycle, but was decreased to 72% and 65% in 18 cycle and 19 cycle, respectively.

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Fabrication and Properties of the SiC Candle Filter by Vacuum Extrusion and Ramming Process (진공 압출성형 및 래밍성형 공정에 의한 탄화규소 캔들 필터 제조 및 특성)

  • Shin, Myung-Kwan;Han, In-Sub;Seo, Doo-Won;Kim, Se-Young;Woo, Sang-Kuk;Lee, Seoung-Won;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.662-667
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    • 2009
  • Porous SiC candle filter preforms were fabricated by extrusion and ramming process. To fabricate SiC candle filter preform, commercially available 85 ${\mu}m\;{\alpha}-$-SiC powder and 44 ${\mu}m$ mullite, CaC$O_3$ powder were used as the starting materials. The candle type preforms were fabricated by vacuum extrusion and ramming process, and sintered at $1400{^{\circ}C}$ 2 h in air atmosphere. The effect of forming method on porosity, density, strength (flexural and compressive strength) and microstructure was investigated. Also, corrosion test of the sintered candle filter specimens as forming method was performed at $600{^{\circ}C}$ in IGCC syngas atmosphere. The sintered SiC filter which was formed by ramming process has more higher density and exhibit higher strength than extruded filter. Its maximum density and 3-point bending strength were 2.00 g/$cm^3$ and 45 MPa, respectively.

Pervaporation Characteristics of NaA Zeolite Membrane for Water/Ethanol Mixture (NaA 제올라이트 분리막의 물/에탄올 투과증발 특성)

  • Ahn, Hyoseong;Lee, Hyeryeon;Lee, Yongtaek
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.243-248
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    • 2005
  • Membrane pervaporation processes could have advantages over distillation for separation of water/organics mixtures: a low energy demand and the ability to separate azeotropic mixtures or isomers. Zeolite membranes might show better thermal, mechanical and chemical stabilities than polymer membranes. Water could be effectively separated from water/organic mixtures using the NaA zeolite membrane because of its high hydrophilicity. In this study, water was separated by pervaporation using the NaA zeolite membrane from water/ethanol mixtures. As a mole fraction of ethanol increased, the total permeation flux and the water flux decreased while the separation factor increased, reached a maximum point, and decreased. As an experimental temperature increased, the total permeation flux increased while the separation factor increased at the lower mole fraction of ethanol than 0.8 and it decreased at the higher mole fraction of ethanol than 0.8. The total permeation flux and the separation factor could be maintained constant during the long term experiment longer than 160 hours. It was found that the NaA zeolite membrane synthesized in our study showed better performance on water/ethanol separation than that of a distillation process or PVA polymeric pervaporation membranes.

Removal of arsenic from aqueous phase using magnetized activated carbon and magnetic separation

  • Kwon, H.W.;Shin, T.C.;Kim, J.J.;Ha, D.W.;Kim, Min Gyu;Kim, Young-Hun
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.2
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    • pp.1-5
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    • 2018
  • Arsenic (As) is one of the elements having most harmful impact on the human health. Arsenic is a known carcinogen and arsenic contamination of drinking water is affecting on humans in many regions of the world. Adsorption has been proved most preferable technique for the removal of arsenic. Many researchers have studied various types of solid materials as arsenic adsorbent, and iron oxide and its modified forms are considered as the most effective adsorbent in terms of adsorption capacity, recovery, and economics. However, most of all iron oxides have small surface area in comparing with common adsorbents in environmental application such as activated carbon but the activated carbon has weak sorption affinity for arsenic. We have used an activated carbon as base adsorbent and iron oxide coating on the activated carbon as high affinity sorption sites and giving magnetic attraction ability. In this study, adsorption properties of arsenic and magnetic separation efficiency of the magnetized activated carbon (MAC) were evaluated with variable iron oxide content. As the iron oxide content of the MAC increased, adsorption capacity has also gradually increased up to a point where clogging by iron oxide in the pore of activated carbon compensate the increased sorption capacity. The increase of iron oxide content of the MAC also affected magnetic properties, which resulted in greater magnetic separation efficiency. Current results show that magnetically modified common adsorbent can be an efficiency improved adsorbent and a feasible environmental process if it is combined with the magnetic separation.

PVA-based Graft Copolymer Composite Membrane Synthesized by Free-Radical Polymerization for CO2 Gas Separation (자유 라디칼 중합법을 활용한 CO2 기체분리용 PVA 기반 가지형 공중합체 복합막)

  • Park, Min Su;Kim, Jong Hak;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.4
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    • pp.268-274
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    • 2021
  • One of the chronic problems in the issue of global warming is the emission of greenhouse gases. Carbon dioxide (CO2), which accounts for the highest proportion of various greenhouse gases, has been continuously researched by humans to separate it. From this point of view, a poly(vinyl alcohol) (PVA)-based copolymer with acrylic acid monomer was utilized in a gas separation membrane in this study. We employed a free radical polymerization to fabricate PVA-g-PAA (VAA) graft copolymer. It was utilized in the form of a composite membrane on a polysulfone substrate. The proper amount of acrylic acid reduced the crystallinity of PVA and increased CO2 solubility in separation membranes. In this perspective, we suggest the novel approach in CO2 separation membrane area by grafting and solution-diffusion.

Protein Separation with CTAB/Hexanol/Isooctane Reverse Micellar System (CTAB/Hexanol/Isooctane 역미셀계를 이용한 단백질 분리)

  • 김영숙;신해헌;권윤중;변유량;홍석인
    • Microbiology and Biotechnology Letters
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    • v.18 no.5
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    • pp.517-524
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    • 1990
  • The solubilization and desolubilization of proteins in CTAB/hexanol/isooctane reverse micellar system were investigated for the selective separation of proteins. Several proteins were used, including bovine serum albumin (BSA), pepsin, trysin and ribonuclease-a. Most proteins could be solubilized into reverse micelles in the pH range above the isoelectric point of each protein, where the net charge of protein was opposite to that of surfactant. However BSA was solubilized above pH 10, which is serveral pH units above the pI 4.9. The kinds of anions in aqueous phase influenced on protein solubilization while no significant trend was observed with different cations, Protein solubilization decreased with increase of the ion size in the order of F -, C1-, Br- and I -. The size of CTAB micelles did not change significantly with increasing ionic strength, but the solubilization decreased. Protein desolubilization showedropposite behaviors to the solubilization. Several model mixtures such as pepsin/ trypsin, pepsin/ribonuclease-a and BSAlribonucleaee-a were successfully separated from each other without changing enzymatic activities.

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