• Resources Recycling
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• v.19 no.5
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• pp.3-12
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• 2010

Platinum group metals with high purity are important raw materials for high technology industry. Since there are no domestic ores containing PGMs, it is of importance to develop a separation process by which ultra pure PGMs can be recovered from diverse spent resources. Data on the chemical properties and dissolution behavior of PGMs were obtained from the literature. A method for the thermodynamic analysis of the HCl solution with chlorine gas was introduced. Utilizing the difference in the chemical properties and dissolution behavior of PGMs would lead to an efficient separation process to recover ultra pure PGMs.

• Proceedings of the Membrane Society of Korea Conference
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• 2005.11a
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• pp.96-101
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• 2005

A theory for the material transports through ion exchange membrane has been developed on the basis of nonequilibrium thermodynamics by removing the assumption of solvent flow in the previous paper and applied to a detailed study of the ionic transport properties of new charged mosaic membrane(CMM) system. The CMM having two different fixed charges in the polymer membrane indicated unique selective transport behavior then ion-exchange membrane. The separation behavior of ion transport across the CMM with a parallel array of positive and negative functional charges were investigated. It was well-known the analysis of the volume flux and solute flux based on nonequilibrium thermodynamics. Our suggests preferential salt transport across the charged mosaic membranes. Transport properties of heavy metal ions, $Mg^{2+}$, $Mn^{2+}$and sucrose system across the charged mosaic membrane were estimated. As a result, we were known metal salts transport depended largely on the CMM. The reflection coefficient indicated the negative value that suggested preferential material transport and was independent of charged mosaic membrane thickness.

• Macromolecular Research
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• v.16 no.2
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• pp.113-119
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• 2008

A series of amphiphilic dendrons n-18 (n: generation number, 18: octadecyl chain) based on an aliphatic polyether denderitic core and octadecyl peripheries were synthesized using a convergent dendron synthesis consisting of a Williamson etherification and hydroboration/oxidation reactions. This study investigated their thermal and self-assembling behavior in the solid state using differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) absorption spectroscopy, and small angle X-ray scattering (SAXS). DSC indicated that the melting transition and the corresponding heat of the fusion of the octadecyl chain decreased with each generation. FT-IR showed that the hydroxyl focal groups were hydrogen-bonded with one another in the solid state. DSC and FT-IR indicated microphase-separation between the hydrophilic dendritic cores and hydrophobic octadecyl peripheries. SAXS data analysis in the solid state suggested that the lower-generation dendrons 1-18 and 2-18 self-assemble into lamellar structures based upon a bilayered packing of octadecyl peripheries. In contrast, the analyzed data of higher-generation dendron 3-18 is consistent with 2-D oblique columnar structures, which presumably consist of elliptical cross sections. The data obtained could be rationalized by microphase-separation between the hydrophilic dendritic core and hydrophobic octadecyl peripheries, and the degree of interfacial curvature associated with dendron generation.

• Structural Engineering and Mechanics
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• v.77 no.1
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• pp.19-35
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• 2021

Existing methods to estimate the probability of seismic pounding occurrence of adjacent buildings do not account for nonlinear behavior or only apply to simple lumped mass systems. The present study proposes an efficient method based on subset simulation for fragility and risk assessment of seismic pounding occurrence between nonlinear adjacent buildings neglecting pounding effects with application to finite element models. The proposed method is first applied to adjacent buildings modeled as elastoplastic systems with substantially different dynamic properties for different structural parameters. Seismic pounding fragility and risk of adjacent frame structures with different floor levels is then assessed, paying special attention to modeling the non-linear material behavior in finite element models. Difference in natural periods and impact location are identified to affect the pounding fragility simultaneously. The reliability levels of the minimum code-specified separation distances are also determined. In addition, the incremental dynamic analysis method is extended to assess seismic pounding fragility of the adjacent frame structures, resulting in higher fragility estimates for separation distances larger than the minimum code-specified ones in comparison with the proposed method.

• Steel and Composite Structures
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• v.10 no.5
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• pp.457-473
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• 2010

In this study, specimens were made with profile thicknesses and shear reinforcement as parameters. The bending and shear behavior were checked, and comparative analysis was conducted of the results and the theoretical values in order to see the applicability of T-section Modular Composite Profiled Beams (TMPB). In TMPB, the profiles of formwork functions play a structural role resisting the load. Also, the module concept, which is introduced into TMPB, has advantages: it can be mass-produced in a factory, it is lighter than an existing H-beam, it can be fabricated on the spot, and its section size is freely adjustable. The T1 specimens exhibited ductile behavior, where the whole section displayed strain corresponding to yielding strain at least without separation between modules. They also exhibited maximum strength similar to the theoretical values even if shear reinforcement was not applied, due to the marginal difference between shear strength and maximum bending monment of the concrete section. A slip between modules was incurred by shear failure of the bolts in all specimens, excluding the T1 specimen, and therefore bending moment could not be fully displayed.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.292-297
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• 2003

A stochastic approach has been presented for superplastic deformation of Ti-6AJ-4V alloy, and probability function are used to heterogeneous phase distributions. The experimentally observed spatial correlation function are developed, and microstructural evolutions together with superplastic deformation behavior have investigated by means of the probability function. The result have shown that the probability varies approximately linearly with separation with distance, and significant deformation enhanced probability changes during the deformation. The stress-strain behavior with the evolutions of probability function can be correctly predicted by the model. The finite clement implementation using Monte Carlo simulation associated with phase re-distributions shows that better agreement with experimental data of failure strain on the test specimen.

• Korean Journal of Child Studies
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• v.18 no.2
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• pp.5-18
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• 1997

The purpose of the current study was to determine whether preschoolers' attachment relationships with their parents and socioemotional behaviors are related to their day care experiences in infancy and at the present time. The participants consisted of 59 preschoolers and their mothers from 2-parent, white, middle-class dual earner families in Madison, Wisconsin. Preschoolers' attachment quality was measured by two representational instruments: the Separation Anxiety Test and "My Family and Friends". Mothers completed questionnaires about their family background and their children's day care history. The quality of current day care was obtained from directors' reports about regulatable features of the day care centers. Teachers completed the Preschool Behavior Questionnaire. Data was analyzed by hierarchical multiple regression analysis. The results showed that the quality of preschoolers' attachment relationships with parents were significantly related to the amount of day care during infancy, the quality of current care, and children's gender. In addition, the amount of infant day care appeared to have negative relations with children's socioemotional behavior problems as evaluated by teachers.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.28 no.6
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• pp.685-692
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• 2004

A stochastic approach has been presented for superplastic deformation of Ti-6Al-4V alloy, and probability functions are used to model the heterogeneous phase distributions. The experimentally observed spatial correlation functions are developed, and microstructural evolutions together with superplastic deformation behavior have been investigated by means of the two-point and three-point probability functions. The results have shown that the probability varies approximately linearly with separation distance, and deformation enhanced probability changes during the process. The stress-strain behavior with the evolutions of probability function can be correctly predicted by the model. The finite element implementation using Monte Carlo simulation associated with reconstructed microstructures shows that better agreement with experimental data of failure strain on the test specimen.

• Journal of Korean Association for Spatial Structures
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• v.15 no.3
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• pp.69-76
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• 2015

Cheomseongdae is the masonry stone structure with the cultural and historical values. But, this structure has the various damages such as cracks, gaps, slope variations and ground subsidence. So, the interests for the safety security in the structural parts have been increased. Therefore, this study performs the structural modelling which considers the several damage cases, and then evaluates the structural behavior characteristics through the discrete element analysis. Especially, this study checks the swelling and displacement gap of the whole structure and the separation between the neighboring members.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 1991.04a
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• pp.84-90
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• 1991

Underground structures usually consist of rock masses or concretes which can be cracked or have cracks. This study aims to develop an analysis program which can deal with the effect of discontinuous behavior due to those cracks using the block theory. It is assumed that rock masses form blocks along the discontinuity lines, and deformation within the block is relatively small. The behavior of discontinuity plane of the structures is divided into sliding along the discontinuity plane. separation of discontinuity by tensile force, and degradation of asperity angle of discontinuity plane by external force with sliding of rock Basses. These behaviors are implemented using constitutive relation and relevent load-displacement relation defined through normal and shear stiffnesses. Time varying displacements and block velocities are calculated by explicit time stepping algorithm. The effect of rock supports including rockbolts is also considered, and the tending effects which occurs in relatively thin lining is also considered.