• 제목/요약/키워드: Separation Behavior

검색결과 657건 처리시간 0.033초

In Situ Detection of the Onset of Phase Separation and Gelation in Epoxy/Anhydride/Thermoplastic Blends

  • Choe, Young-Son;Kim, Min-Young;Kim, Won-Ho
    • Macromolecular Research
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    • 제11권4호
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    • pp.267-272
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    • 2003
  • The isothermal cure reactions of blends of epoxy (DGEBA, diglycidyl ether of bisphenol A)/anhydride resin with polyamide copolymer (poly(dimmer acid-co-alkyl polyamine)) or PEI were studied using differential scanning calorimetry (DSC). Rheological measurements have been made to investigate the viscosity and mechanical relaxation behavior of the blends. The reaction rate and the final cure conversion were decreased with increasing the amount of thermoplastics in the blends. Lower values of final cure conversions in the epoxy/thermoplastic blends indicate that thermoplastics hinder the cure reaction between the epoxy and the curing agent. Complete miscibility was observed in the uncured blends of epoxy/thermoplastics up to $120^{\circ}C$ but phase separations occurred in the early stages of the curing process at higher temperatures than $120^{\circ}C$. According to the rheological measurement results, a rise of G' and G" at the onset of phase separation is seen. A rise of G' and G" is not observed for neat epoxy system since no phase separation is seen during cure reaction. At the onset of phase separation the rheological behavior was influenced by the amount of thermoplastics in the epoxy/thermoplastic blends, and the onset of phase separation can be detected by rheological measurements.

소아 수면 행태와 불면증 (Sleep Behavior and Sleeplessness in Children)

  • 이성훈
    • 수면정신생리
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    • 제3권2호
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    • pp.56-64
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    • 1996
  • The sleeplessness in childhood is quite different from that in adulthood in terms of causes, developmental process, and treatment. Sleep behavior in childhood is strongly influenced by parental personality and familial and cultural background. In understanding and management of sleeplessness of children, it is especially important to understand the separation anxiety and the ways of its management in bedtime because bedtime routine with children one of separation process from parents. Co-sleeping, parental intervention, transional object and bedtime routines can be appeared in order to reduce the anxiety from bedtime separation. Causes of sleeplessness in infant and toddler are bad sleep-onset association, nocturnal drinking, colic, and food allergy. In preschool and school aged children, limit-setting sleep problem and fears and nightmare can be causes of sleeplessness. When good sleep environment and habits are established sound sleep and more mature personality can be developed.

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Pervaporation separation of polyion complex composite membranes for the separation of water/alcohol mixtures: characterization of permeation behavior by using molecular modeling techniques

  • Kim, Sang-Gyun;Lee, Yoon-Gyu;Jonggeon Jegal;Lee, Kew-Ho
    • 한국막학회:학술대회논문집
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    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
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    • pp.91-94
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    • 2003
  • In this work, the physicochemical properties for permeant molecules and polyion complex membrane prepared by complexation between SA and chitosan were determined by using molecular modeling methods, and the permeation behaviors of water and alcohol molecules through the PIC membrane have been investigated. In the case of penetrant molecule, the experimental results showed that the prepared membrane was excellent pervaporation performance result in most solution, and the selectivity and permeability of the membrane were dependent on the molecular size, the polarity and the hydrophilic surface of permeant organics. However, the separation behavior of methanol aqueous solution exhibited other permeation tendency with other feed solutions and contradictory result. That is, the membrane were preferentially permeable to methanol over water despite water molecule has stronger polarity and small molecular size than methanol molecule. In this study, the results were discussed from the viewpoint of chemical and physical properties between permeant molecules and membrane in the diffusion state.

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NUCLIDE SEPARATION MODELING THROUGH REVERSE OSMOSIS MEMBRANES IN RADIOACTIVE LIQUID WASTE

  • LEE, BYUNG-SIK
    • Nuclear Engineering and Technology
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    • 제47권7호
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    • pp.859-866
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    • 2015
  • The aim of this work is to investigate the transport mechanism of radioactive nuclides through the reverse osmosis (RO) membrane and to estimate its effectiveness for nuclide separation from radioactive liquid waste. An analytical model is developed to simulate the RO separation, and a series of experiments are set up to confirm its estimated separation behavior. The model is based on the extended Nernst-Plank equation, which handles the convective flux, diffusive flux, and electromigration flux under electroneutrality and zero electric current conditions. The distribution coefficient which arises due to ion interactions with the membrane material and the electric potential jump at the membrane interface are included as boundary conditions in solving the equation. A high Peclet approximation is adopted to simplify the calculation, but the effect of concentration polarization is included for a more accurate prediction of separation. Cobalt and cesium are specifically selected for the experiments in order to check the separation mechanism from liquid waste composed of various radioactive nuclides and nonradioactive substances, and the results are compared with the estimated cobalt and cesium rejections of the RO membrane using the model. Experimental and calculated results are shown to be in excellent agreement. The proposed model will be very useful for the prediction of separation behavior of various radioactive nuclides by the RO membrane.

파이로테크닉 분리 너트 거동에 대한 설계 인자의 영향 분석 (Influence of Design Parameters on the Behavior of Pyrotechnic Separation Nut)

  • 우정민;김정호;조진연;장승교;이효남;양희원
    • 한국항공우주학회지
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    • 제47권9호
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    • pp.617-628
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    • 2019
  • 벤트홀로 연결된 두 개의 가변 체적 챔버를 가지고 있는 파이로테크닉 분리 너트는 복잡한 과정을 통해 분리를 수행하므로 많은 설계 인자를 가지고 있다. 접촉부의 각도, 구성품의 질량, 누름봉 돌출부 안쪽 지름, 환형 챔버의 초기 부피, 확장 챔버의 초기 부피, 화약질량, 벤트홀 지름과 같은 설계 인자들의 변화에 따라 분리 너트의 성능이 어떻게 달라지는지를 파악하면 설계 개선 방향을 결정하는데 도움이 될 수 있다. 이에, 선행 연구를 통해 개발한 파이로테크닉 분리 너트 거동 예측 모델을 이용하여 매개변수 연구를 수행하였다. 다른 설계 인자의 값은 고정한 상태에서 한 설계인자의 값을 독립적으로 변화시키며 분리 시간이 어떻게 달라지는지, 변화의 원인이 무엇인지를 분석하였다.

부모자녀놀이치료 프로그램이 부모자녀 상호작용에서의 공감 및 문제행동에 미치는 효과 - 분리불안아동을 대상으로 - (The Effectiveness of Filial Therapy on Empathy in Parent-child Interaction and Problem Behavior of Children with Separation Anxiety Disorder)

  • 백지은;이정숙
    • 아동학회지
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    • 제30권4호
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    • pp.99-117
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    • 2009
  • This study examined the effectiveness of the Filial Therapy program for children with Separation Anxiety Disorder (SAD). Subjects were 8 mother-child dyads each in the experimental and comparison groups. Mann-Whitney U-test and the Wilcoxon Matched-Pairs Signed-Ranks Test were performed following the therapeutic program. After application of the Filial Therapy program, results showed that, compared to the control group, (1) parents of SAD children in the experimental group significantly increased their level of empathic interactions with their children. AND (2) the experimental group children significantly reduced level of somatic complaints, anxious/depressed, and social problems. Conclusions were that Filial Therapy is an effective program for improvement of parent-child relationship of SAD children but not for changing problem behavior of SAD children.

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12-18개월 영아의 애착 행동 특성 연구 (Attachment Behavior Characteristics of Infants in the Strange Situation Procedure)

  • 김은하;최해훈;이순행;방희정
    • 아동학회지
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    • 제26권4호
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    • pp.35-53
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    • 2005
  • The attachment of Korean infants with their mothers was analyzed by individual attachment and interaction behaviors. The Strange Situation was used with 35 12- 18-month-old infants. Results were similar to the findings of Ainsworth et al(l978), in that exploratory and attachment behavior systems of Korean infants changed depending on separation with their mothers. Then again we could discover the orginal attachment characteristics of Korean infants. Korean infants showed meaningful differences in individual attachment and interaction behaviors from the second separation(episode 6), and the difference between attachnet type were also definite from the second separation. Also, the recovery of exploratory behavior from episode 7 with the advent of a stranger was a distinguishable characteristic compared to Ainsworth et al(l978). This empirical evidence mandates the inclusion of episodes 6 in future studies on attachment of Korean infants.

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Gas Separation of Pyrolyzed Polymeric Membranes: Effect of Polymer Precursor and Pyrolysis Conditions

  • Jung, Chul-Ho;Kim, Gun-Wook;Han, Sang-Hoon;Lee, Young-Moo
    • Macromolecular Research
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    • 제15권6호
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    • pp.565-574
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    • 2007
  • In this study, five representative, commercially available polymers, Ultem 1000 polyetherimide, Kapton polyimide, phenolic resin, polyacrylonitrile and cellulose acetate, were used to prepare pyrolyzed polymer membranes coated on a porous {\alpha}-alumina$ tube via inert pyrolysis for gas separation. Pyrolysis conditions (i.e., final temperature and thermal dwell time) of each polymer were determined using a thermogravimetric method coupled with real-time mass spectroscopy. The surface area and pore size distribution of the pyrolyzed materials derived from the polymers were estimated from the nitrogen adsorption/desorption isotherms. Pyrolyzed membranes from polymer precursors exhibited type I sorption behavior except cellulose acetate (type IV). The gas permeation of the carbon/{\alpha}-alumina$ tubular membranes was characterized using four gases: helium, carbon dioxide, oxygen and nitrogen. The polyetherimide, polyimide, and phenolic resin pyrolyzed polymer membranes showed typical molecular sieving gas permeation behavior, while membranes from polyacrylonitrile and cellulose acetate exhibited intermediate behavior between Knudsen diffusion and molecular sieving. Pyrolyzed membranes with molecular sieving behavior (e.g., polyetherimide, polyimide, and phenolic resin) had a $CO_2/N_2$ selectivity of greater than 15; however, the membranes from polyacrylonitrile and cellulose acetate with intermediate gas transport behavior had a selectivity slightly greater than unity due to their large pore size.

비행 조건에 따른 비행체 단분리의 주위 유동장 해석 (A Flow Characteristics for a Separation Behavior of Two-body Vehicle)

  • 박근홍;김기언
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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    • pp.266-267
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    • 2017
  • 본 연구에서는 중첩된 두 비행물체에서 단분리 시 일어나는 주위 유동장 해석에 초점을 맞춰 해석을 수행하였다. 수치적인 해석을 위하여 정지된 비행체에서 분리되는 실린더 형태의 부스터를 중첩격자를 이용하여 모델링 하였으며 상용해석코드인 CFD-FASTRAN$^{TM}$을 사용하여 계산하였다. 실제 현상을 모사하기 위하여 경계조건 및 외력을 도출하였으며 각 비행조건에 따른 부스터 분리 시 주위 유동장 해석을 수행하였다. 단분리 시의 비행속도와 받음각 조건에 대한 해석결과를 이용하여 실제 분리 현상을 모사할 수 있는 수치적인 경계조건을 파악하고 안전한 단분리 예측에 본 연구결과를 활용하고자 한다.

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비행체 단분리 거동 예측에 대한 수치 연구 (A Study of Numerical Analysis for Stage Separation Behavior of Two-body Vehicle)

  • 박근홍
    • 한국추진공학회지
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    • 제22권4호
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    • pp.91-98
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    • 2018
  • 본 연구에서는 중첩된 두 비행물체에서 단분리 시 일어나는 주위 유동장 분석에 초점을 맞춰 해석을 수행하였다. 수치 해석을 위하여 정지된 비행체에서 분리되는 실린더 형태의 부스터를 중첩격자를 이용하여 모델링 하였으며 상용해석코드인 $CFD-FASTRAN^{TM}$을 사용하여 계산하였다. 실제 현상을 모사하기 위해서는 부스터에 대한 스프링 반발력, 중력, 상대 속도 등의 고려가 필수적인 요소였다. 연구결과, 부스터의 분리 시간은 비행 마하수와 받음각이 증가함에 따라 감소하는 것을 확인할 수 있었으며, 현재까지의 결과를 종합하여 볼 때 본 연구에서 수행한 모델링과 경계조건 등의 구성이 비행시험의 안전한 부스터 분리와 이후 시퀀스를 예측하는데 많은 도움을 줄 것으로 판단된다.