• 제목/요약/키워드: Separation Behavior

검색결과 657건 처리시간 0.027초

Synchrotron SAXS Study on the Micro-Phase Separation Kinetics of Segmented Block Copolymer

  • Lee, Han-Sup;Yoo, So-Ra;Seo, Seung-Won
    • Fibers and Polymers
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    • 제2권2호
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    • pp.98-107
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    • 2001
  • The phase transition behavior isothermal micro-phase separation kinetics of polyester-based thermoplastic elastomer were studied using the synchrotron X-ray scattering(SAXS) method. The structural changes occurring during heating period were investigated by determining the changes of the one-dimensional correlation function, interfacial thickness and Porod constant. Based on the abrupt increases of the domain spacing and interfacial thickness, a major structural change occurring well below the melting transition temperature is suggested. Those changes are explained in terms of melting of the thermodynamically unstable hard domains or/and the interdiffusion of the hard and soft segments in the interfacial regions. SAXS profile changes during the micro-phase separation process were also clearly observed at various temperatures and the separation rate was found to be sensitively affected by the temperature. The peak position of maximum scattering intensity stayed constant during the entire course of the phase separation process. The scattering data during the isothermal phase separation process was interpreted with the Cahn-Hilliard diffusion equation. The experimental data obtained during the early stage of the phase separation seems to satisfy the Cahn-Hilliard spinodal mechanism. The transition temperature obtained from the extrapolation of the diffusion coefficient to zero value turned out to be about 147$\pm$$2^{\circ}$, which is close to the order-disorder transition temperature obtained from the Porod analysis. The transition temperature was also estimated from the inveriant growth rate. By extrapolating the inveriant growth rate to zero, a transition temperature of about 145$\pm$$\pm$$2^{\circ}$ was obtained.

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NACA 0012 에어포일의 경계층 거동이 근접 후류에 미치는 영향 (Influence of Boundary Layer Behavior on the Near-Wake of an NACA 0012 Airfoil)

  • 양재훈;김동하;장조원
    • 한국항공운항학회지
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    • 제14권4호
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    • pp.24-30
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    • 2006
  • An experimental study was carried out in order to investigate the influence of boundary layer behavior on the near-wake at low Reynolds numbers. An X-type hot-film probe(55R51) was used to measure the near-wake of an NACA 0012 airfoil at static angles of attack ${\alpha}=0^{\circ}$, $3^{\circ}$, and $6^{\circ}$, and the Reynolds numbers Re=2.3${\times}10^4$, 3.3${\times}10^4$, and 4.8${\times}10^4$. The results of the study show that the characteristics of the boundary layer on the airfoil surface have a close relationship with the mean velocity and turbulence intensity profiles of a near-wake. Therefore, the development of the boundary layer, the position of the separation point, and the existence and non-existence of reattachment on the airfoil surface were represented by the differences in mean velocity and turbulence intensity profiles of the near-wake.

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산업근로자의 건강증진 행태에 관한 관련요인분석 (A Study on Health Promotion Behavior and It′s Related Factors of Industrial Workers)

  • 강영우;남철현
    • 보건교육건강증진학회지
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    • 제14권2호
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    • pp.17-42
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    • 1997
  • From September 2, 1995 through October 31, this questionnaire was made by the 1, 200 industrial workers who work for 15 enterprises of 5 types of business. And it was for helping to devise a policy and to develop a program for industrial workers' health promotion by understanding the consciousness behavior level of industrial workers in our country and the related factors which are under the influence of it and health promotion behavior. The summary and conclusions are as follows. 1. In health promotion score level by related factors, the health diagmosis level score was 7. 37(81.9/100) of the perfect score 9, nutrition level score was 7.00(77.8/100), health education behavior level score was 6.00(66.7/100), exercise behavior level score was 6.01(66.8/100), occupational disease knowledge level score was 6.00(66.7/100). 2. Health diagnosis behavior level was significantly high when the age is older, when the occupation term is longer, when the economic status is better. And wjem tje satosfoed degree for vocational aptitude, working environment, and the education contents. 3. Nutrition (dietary habit) status level was high in men, in the age group of 40 over, in the group of having their spouse, in the group of being paid over one million won a month, in the upper economic classes (P〈0.001). It was also high in graduates middle school and in daytime workers (P〈0.05). 4. Health education behavior level was high in the older ahe hroup, in a single life (separation by death, divouce, separation) and in the longer occupation term(P〈0.001). 5. Exercises behavior level was high in men, in the workers who are paid 500~990 thousand won a month, in the better economic classes(P〈0.01). 6. Knowledge level on an occupational disease was high in men, in the older age group, in the group of having a spouse, In the workers who are paid 500~990 thousand won a month, in the group of having a longer occupation term, and in the residents living not in a large city(P〈0.01). 7. When health status was higher, health promotion behavior, behavior level, health diagnosis (P〈0.001), nutrition(P〈0.05), health education behavior (P〈0.05), exercise behavior(P〈0.01) and the knowledge level on an occupation disease was high. 8. The main factors which are under the influence on the degree of practicing healthy life were the level of knowledge and behavior, sex, his/her health status, and the satisfied degree of working environment. These variables could explain it 18.0%. 9. The factors which are under the influence on health promotion behavior and behavior levels were the variables of the satisfied degerr of education contents, sex, health knowledge, economic status, health status, occupation terms, monthly income, working tiredness. These variables could explain it 21.3%. By these results, it is inportant for industrial workers' health promotion to level up the health diagnosis behavior, dietary habit considering nutrition, behavior on health education, behavior for exercise, and knowledge on an occupational disease. Especially we should develop the proper program considered sex, health status, satisfied degree of working environment and education contents, economic status, eccupation terms, knowledge on health, and behavior level. Because health promotion business gies in gear with productivity promotion.

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가소화 저항 향상을 위한 기체분리막 소재 개발 동향 (Review on Membrane Materials to Improve Plasticization Resistance for Gas Separations)

  • 조진희;지원석
    • 멤브레인
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    • 제30권6호
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    • pp.385-394
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    • 2020
  • 기체분리공정에서 사용되는 분리막은 높은 기체 투과 및 분리성능과 고온·고압 조건에서 높은 안정성을 보여야 한다. 하지만 고분자분리막(특히, 유리상 고분자)은 응축 가능한 기체 분자(예를 들어, CO2, H2S, hydrocarbon 등)에 노출되면 고분자 사슬이 부풀어 오르는 가소화 현상을 보여 안정성 측면에서 한계를 보인다. 이러한 가소화 현상은 고압의 복합기체 분리공정에서 선택도를 감소시켜 장기적으로는 고분자분리막이 분리공정에 도입될 수 없는 문제를 가져온다. 이러한 가소화 현상 문제를 해결하기 위해서 분리막 연구자들은 분리막 열처리, 고분자 혼합, 고분자구조의 열적 재배열, 혼합매질분리막 제작, 가교화 방법 등을 통하여 분리막의 가소화 저항을 향상시켰다. 본 총설에서는 고분자 분리막의 가소화 저항의 개념 및 현상에 대해서 알아보고 이를 해결할 수 있는 인자들과 그와 연관된 연구들을 살펴보도록 할 것이다.

축소모형실험을 통한 이격거리에 따른 근접터널의 거동 (Behavior of Closely-Spaced Tunnel According to Separation Distance Using Scaled Model Tests)

  • 안현호;최정인;심성현;이석원
    • 한국지반공학회논문집
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    • 제24권7호
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    • pp.5-16
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    • 2008
  • 국내에서는 대부분의 도로터널이 병설터널로 건설되어 왔다. 그러나 이러한 병설터널을 건설할 때 충분한 터널 간 이격거리를 확보하지 못한다면 터널의 안정성에 문제가 될 수 있다. 근접 병설터널의 적정 이격거리에 대하여 일반적으로 지반이 완전 탄성체일 경우에는 터널 간 중심 간격이 굴착 직경(D)의 2배, 지반이 연약 지층인 경우 5배 이상으로 하면 터널 상호간에 거의 영향을 미치지 않는 것으로 보고되고 있다. 본 연구에서는 균일재료를 사용하여 근접 병설터널에 대한 축소 모형실험을 수행하고 굴착과정 중에 터널 주변에서 발생하는 변위를 측정하였다. 터널 간 이격거리가 근접터널의 거동에 미치는 영향을 조사하였다. 실험 결과는 터널 굴착과정과 파괴 단계에서 발생된 변위 벡터와 균열양상으로 표현하였다. 터널 굴착과정 중 천단부에서 발생하는 변위를 분석하여보면, 후행터널 굴착으로 추가적으로 선행터널에서 발생하는 변위는 터널 간 중심 간격이 터널직경의 두 배(2.0D)까지는 이격거리가 증가함에 따라 감소하는 경향을 보인다. 그러나 중심 간격이 2.0D를 넘으면 추가변위는 발생하지 않았다.

NUMERICAL STUDY OF AN EXTERNAL STORE RELEASED FROM A FIGHTER AIRCRAFT

  • Yoon, Young-Hyun;Cho, Hwan-Kee;Chung, H.S.;Lee, S.H.;Han, C.H.
    • 한국전산유체공학회지
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    • 제13권4호
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    • pp.80-85
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    • 2008
  • The prediction of the separation trajectories of external stores released from a military aircraft is an important task in the aircraft design area having the objective to define the operational and release envelopes. This paper presents the results obtained for store separation by employing commercial softwares, FLUENT and CFD-FASTRAN. FLUENT treats the rigid body motion by employing a remeshing scheme. CFD-FASTRAN uses Chimera(overset) grid and interpolations. It was found that, for the prediction of the trajectories and behavior of the stores separated from the wing, both codes show the good agreement with the experimental results.

용존공기부상(DAF) 공정을 이용한 생물학적 플록의 부상분리 (Flotation Separation of Biological Floc Using the Dissolved Air Flotation Process)

  • 곽동희;김성진;임영환
    • 상하수도학회지
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    • 제18권5호
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    • pp.649-655
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    • 2004
  • The behavior of biological particles in DAF (dissolved air flotation) process was analyzed by employing PBT (Population balance theory). After decline growth phase of activated sludge, the value of the initial collision-attachment efficiency was increased over than 0.35 corresponding relatively high value in the whole life cycle of microorganism. For practical application of DAF as a solid separation process. It is desirable that microbial particles should be operated to perform high solid removal efficiency in biological wastewater treatment.

Performance Analysis of a Hydrodynamic Separator for Treating Particulate Pollutants in Highway Rainfall Runoff

  • Yu, Jianghua;Yi, Qitao;Kim, Young-Chul
    • Environmental Engineering Research
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    • 제14권4호
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    • pp.262-269
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    • 2009
  • This study examined the separation characteristics of particles in the rainfall runoff from paved roads using a ${\varphi}7.5$ cm hydrocyclone. The volume fraction and total suspended solids concentrations in the overflow and underflow from the hydrocyclone, as well as the separation efficiency were determined. The results indicated that the overflow volume increased with increasing operational pressure, but decreased with decreasing ratio of underflow outlet to inlet sizes ($D_u/D_i$), while the underflow to overflow volumes showed contrary behavior. The total suspended solid (TSS) concentration ratio between the overflow and inflow ($TSS_{over/in}$) decreased as a function of the operational pressure, while the corresponding ratio of underflow to inflow ($TSS_{under/in}$) increased. There was no visible difference in the $TSS_{over/in}$ with increasing $D_u/D_i$ ratio, but the $TSS_{under/in}$ decreased sharply. The particle removal efficiency was mainly affected by the particle size.

Solution NMR spectroscopy for investigation of liquid-liquid phase separation

  • Saio, Tomohide;Okumura, Masaki;Lee, Young-Ho
    • 한국자기공명학회논문지
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    • 제24권2호
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    • pp.47-52
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    • 2020
  • Liquid-liquid phase separation (LLPS) of biomolecules, a newly-found phase behavior of molecules in the liquid phase, has shown to its relationship to various biological function and misfolding diseases. Extensive studies have increasingly revealed a general mechanism of LLPS and characterized the liquid droplet; ho wever, intermolecular interactions of proteins and structural states of LLPS-inducing proteins inside of the droplet remain largely unknown. Solution NMR spectroscopy has emerged as a powerful approach as it provides invaluable information on protein intermolecular interactions and structures at the atomic and residue level. We herein comprehensively address useful techniques of solution NMR including the effect of paramagnetic relaxation enhancement for the study on the LLPS and droplet based on recent studies.