• Title/Summary/Keyword: Separation Behavior

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In Situ Detection of the Onset of Phase Separation and Gelation in Epoxy/Anhydride/Thermoplastic Blends

  • Choe, Young-Son;Kim, Min-Young;Kim, Won-Ho
    • Macromolecular Research
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    • v.11 no.4
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    • pp.267-272
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    • 2003
  • The isothermal cure reactions of blends of epoxy (DGEBA, diglycidyl ether of bisphenol A)/anhydride resin with polyamide copolymer (poly(dimmer acid-co-alkyl polyamine)) or PEI were studied using differential scanning calorimetry (DSC). Rheological measurements have been made to investigate the viscosity and mechanical relaxation behavior of the blends. The reaction rate and the final cure conversion were decreased with increasing the amount of thermoplastics in the blends. Lower values of final cure conversions in the epoxy/thermoplastic blends indicate that thermoplastics hinder the cure reaction between the epoxy and the curing agent. Complete miscibility was observed in the uncured blends of epoxy/thermoplastics up to $120^{\circ}C$ but phase separations occurred in the early stages of the curing process at higher temperatures than $120^{\circ}C$. According to the rheological measurement results, a rise of G' and G" at the onset of phase separation is seen. A rise of G' and G" is not observed for neat epoxy system since no phase separation is seen during cure reaction. At the onset of phase separation the rheological behavior was influenced by the amount of thermoplastics in the epoxy/thermoplastic blends, and the onset of phase separation can be detected by rheological measurements.

Sleep Behavior and Sleeplessness in Children (소아 수면 행태와 불면증)

  • Lee, Sung-Hoon
    • Sleep Medicine and Psychophysiology
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    • v.3 no.2
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    • pp.56-64
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    • 1996
  • The sleeplessness in childhood is quite different from that in adulthood in terms of causes, developmental process, and treatment. Sleep behavior in childhood is strongly influenced by parental personality and familial and cultural background. In understanding and management of sleeplessness of children, it is especially important to understand the separation anxiety and the ways of its management in bedtime because bedtime routine with children one of separation process from parents. Co-sleeping, parental intervention, transional object and bedtime routines can be appeared in order to reduce the anxiety from bedtime separation. Causes of sleeplessness in infant and toddler are bad sleep-onset association, nocturnal drinking, colic, and food allergy. In preschool and school aged children, limit-setting sleep problem and fears and nightmare can be causes of sleeplessness. When good sleep environment and habits are established sound sleep and more mature personality can be developed.

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Pervaporation separation of polyion complex composite membranes for the separation of water/alcohol mixtures: characterization of permeation behavior by using molecular modeling techniques

  • Kim, Sang-Gyun;Lee, Yoon-Gyu;Jonggeon Jegal;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.91-94
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    • 2003
  • In this work, the physicochemical properties for permeant molecules and polyion complex membrane prepared by complexation between SA and chitosan were determined by using molecular modeling methods, and the permeation behaviors of water and alcohol molecules through the PIC membrane have been investigated. In the case of penetrant molecule, the experimental results showed that the prepared membrane was excellent pervaporation performance result in most solution, and the selectivity and permeability of the membrane were dependent on the molecular size, the polarity and the hydrophilic surface of permeant organics. However, the separation behavior of methanol aqueous solution exhibited other permeation tendency with other feed solutions and contradictory result. That is, the membrane were preferentially permeable to methanol over water despite water molecule has stronger polarity and small molecular size than methanol molecule. In this study, the results were discussed from the viewpoint of chemical and physical properties between permeant molecules and membrane in the diffusion state.

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NUCLIDE SEPARATION MODELING THROUGH REVERSE OSMOSIS MEMBRANES IN RADIOACTIVE LIQUID WASTE

  • LEE, BYUNG-SIK
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.859-866
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    • 2015
  • The aim of this work is to investigate the transport mechanism of radioactive nuclides through the reverse osmosis (RO) membrane and to estimate its effectiveness for nuclide separation from radioactive liquid waste. An analytical model is developed to simulate the RO separation, and a series of experiments are set up to confirm its estimated separation behavior. The model is based on the extended Nernst-Plank equation, which handles the convective flux, diffusive flux, and electromigration flux under electroneutrality and zero electric current conditions. The distribution coefficient which arises due to ion interactions with the membrane material and the electric potential jump at the membrane interface are included as boundary conditions in solving the equation. A high Peclet approximation is adopted to simplify the calculation, but the effect of concentration polarization is included for a more accurate prediction of separation. Cobalt and cesium are specifically selected for the experiments in order to check the separation mechanism from liquid waste composed of various radioactive nuclides and nonradioactive substances, and the results are compared with the estimated cobalt and cesium rejections of the RO membrane using the model. Experimental and calculated results are shown to be in excellent agreement. The proposed model will be very useful for the prediction of separation behavior of various radioactive nuclides by the RO membrane.

Influence of Design Parameters on the Behavior of Pyrotechnic Separation Nut (파이로테크닉 분리 너트 거동에 대한 설계 인자의 영향 분석)

  • Woo, Jeongmin;Kim, Jeong Ho;Cho, Jin Yeon;Jang, Seung-Gyo;Lee, Hyo-Nam;Yang, Hee Won
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.47 no.9
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    • pp.617-628
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    • 2019
  • The currently considered pyrotechnic separation nut is separated through the complicated process, because it has many internal moving parts and two variable-volume chambers connected by the vent hole. Therefore, it has many design parameters. Some of these are the contact angles between internal moving parts, the masses of the internal moving parts, the inner diameter of the push rod protrusion, the initial volumes of the chambers, the mass of the explosive charge, and the diameter of the vent hole. To improve the pyrotechnic separation nut, it is necessary to understand how the behavior of the separation nut is changed according to design parameters. In this point of view, parametric studies are carried out using the previously proposed prediction model for pyrotechnic separation nut behaviors. In each case, the parameter of the interest is changed while the others are kept unchanged. From the results, it is investigated how each design parameter influences the separation behavior.

The Effectiveness of Filial Therapy on Empathy in Parent-child Interaction and Problem Behavior of Children with Separation Anxiety Disorder (부모자녀놀이치료 프로그램이 부모자녀 상호작용에서의 공감 및 문제행동에 미치는 효과 - 분리불안아동을 대상으로 -)

  • Baek, Ji-Eun;Lee, Jung-Sook
    • Korean Journal of Child Studies
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    • v.30 no.4
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    • pp.99-117
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    • 2009
  • This study examined the effectiveness of the Filial Therapy program for children with Separation Anxiety Disorder (SAD). Subjects were 8 mother-child dyads each in the experimental and comparison groups. Mann-Whitney U-test and the Wilcoxon Matched-Pairs Signed-Ranks Test were performed following the therapeutic program. After application of the Filial Therapy program, results showed that, compared to the control group, (1) parents of SAD children in the experimental group significantly increased their level of empathic interactions with their children. AND (2) the experimental group children significantly reduced level of somatic complaints, anxious/depressed, and social problems. Conclusions were that Filial Therapy is an effective program for improvement of parent-child relationship of SAD children but not for changing problem behavior of SAD children.

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Attachment Behavior Characteristics of Infants in the Strange Situation Procedure (12-18개월 영아의 애착 행동 특성 연구)

  • Kim, Eun Ha;Choi, Hae Hoon;Lee, Soon Hang;Bang, Hee Jeong
    • Korean Journal of Child Studies
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    • v.26 no.4
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    • pp.35-53
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    • 2005
  • The attachment of Korean infants with their mothers was analyzed by individual attachment and interaction behaviors. The Strange Situation was used with 35 12- 18-month-old infants. Results were similar to the findings of Ainsworth et al(l978), in that exploratory and attachment behavior systems of Korean infants changed depending on separation with their mothers. Then again we could discover the orginal attachment characteristics of Korean infants. Korean infants showed meaningful differences in individual attachment and interaction behaviors from the second separation(episode 6), and the difference between attachnet type were also definite from the second separation. Also, the recovery of exploratory behavior from episode 7 with the advent of a stranger was a distinguishable characteristic compared to Ainsworth et al(l978). This empirical evidence mandates the inclusion of episodes 6 in future studies on attachment of Korean infants.

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Gas Separation of Pyrolyzed Polymeric Membranes: Effect of Polymer Precursor and Pyrolysis Conditions

  • Jung, Chul-Ho;Kim, Gun-Wook;Han, Sang-Hoon;Lee, Young-Moo
    • Macromolecular Research
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    • v.15 no.6
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    • pp.565-574
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    • 2007
  • In this study, five representative, commercially available polymers, Ultem 1000 polyetherimide, Kapton polyimide, phenolic resin, polyacrylonitrile and cellulose acetate, were used to prepare pyrolyzed polymer membranes coated on a porous {\alpha}-alumina$ tube via inert pyrolysis for gas separation. Pyrolysis conditions (i.e., final temperature and thermal dwell time) of each polymer were determined using a thermogravimetric method coupled with real-time mass spectroscopy. The surface area and pore size distribution of the pyrolyzed materials derived from the polymers were estimated from the nitrogen adsorption/desorption isotherms. Pyrolyzed membranes from polymer precursors exhibited type I sorption behavior except cellulose acetate (type IV). The gas permeation of the carbon/{\alpha}-alumina$ tubular membranes was characterized using four gases: helium, carbon dioxide, oxygen and nitrogen. The polyetherimide, polyimide, and phenolic resin pyrolyzed polymer membranes showed typical molecular sieving gas permeation behavior, while membranes from polyacrylonitrile and cellulose acetate exhibited intermediate behavior between Knudsen diffusion and molecular sieving. Pyrolyzed membranes with molecular sieving behavior (e.g., polyetherimide, polyimide, and phenolic resin) had a $CO_2/N_2$ selectivity of greater than 15; however, the membranes from polyacrylonitrile and cellulose acetate with intermediate gas transport behavior had a selectivity slightly greater than unity due to their large pore size.

A Flow Characteristics for a Separation Behavior of Two-body Vehicle (비행 조건에 따른 비행체 단분리의 주위 유동장 해석)

  • Park, Geunhong;Kim, Kiun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.266-267
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    • 2017
  • A numerical investigation of the stage separation behavior of two-body vehicle focusing on its flow characteristics were carried out. For this simulation, separation of a booster from vehicle was modeled by a chimera grid system and calculated by using commercial code, CFD-FASTRAN$^{TM}$. Consideration of a spring force, gravity and relative acceleration of a booster was the essential factor that simulates the realistic situation. In this study, It was validated that the booster separation time decreases with increase in flight mach number and angle of attack. In view of the results so far achieved, it was expected that the dynamics modeling and boundary condition set up applied in this study will be helpful in a estimation of a safe stage separation and event sequence of flight test.

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A Study of Numerical Analysis for Stage Separation Behavior of Two-body Vehicle (비행체 단분리 거동 예측에 대한 수치 연구)

  • Park, Geunhong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.4
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    • pp.91-98
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    • 2018
  • A numerical investigation of stage separation behavior of a two-body vehicle focusing on its flow characteristics is carried out. For this simulation, the separation of a booster from a vehicle is modeled using a chimera grid system and calculated with commercial code, $CFD-FASTRAN^{TM}$. Consideration of spring force, gravity and relative acceleration of a booster is the essential factor of a realistic simulation. In this study, it is validated that the booster separation time decreases with an increase in flight Mach number and angle of attack. In view of results thus far achieved, it is expected that the dynamics modeling and boundary condition set-up applied in this study will be useful for estimating safe stage separation and event sequencing of flight tests.