• Title/Summary/Keyword: Separation & recovery

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Triboelectrostatic Separation of Mixed Three Kinds of Plastics by a Two-stage Separation Process (2단계(段階) 분리공정(分離工程)에 의한 3종(種) 혼합(混合)플라스틱의 마찰하전(摩擦荷電) 정전선별(靜電選別))

  • Park, Chul-Hyun;Jeon, Ho-Seok;Baek, Sang-Ho;Park, Jai-Koo
    • Resources Recycling
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    • v.16 no.5
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    • pp.57-64
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    • 2007
  • Triboelectrostatic separation of mixed three kinds of plastics, PVC, PET and PMMA, in the range of similar gravity has been performed through a two-stage separation process. Polypropylene (PP) and high-impact polystyrene (HIPS) were found to be the most effective materials for a tribo-charger in the separation of PVC, PET and PMMA. In the 1st stage using the PP cyclone charger, PVC grade and recovery depended considerably on the air velocity (10 m/s), the relative humidity (<30%), the electric field (>200 kV/m) and the splitter position (+2 cm from the center) in the triboelelctrostatic separator unit. At an optimum condition a PVC grade of 99.6% and a recovery of 97.5% was achieved. In the 2nd stage using the HIPS cyclone charger, a PMMA grade of 98.3% and a recovery of 97.0% was obtained under the conditions of 10m/s air velocity, over 250 kV/m electric field, central splitter position and less than 40% relative humidity.

Development of Material Separation Process for Recycling Waste Coffee Capsules (폐 커피 캡슐의 재활용을 위한 재질분리 공정 개발)

  • Baek, Sang-Ho;Han, Yosep;Kim, Seongmin;Davaadorj, Tsogchuluun;Jeon, Ho-Seok
    • Resources Recycling
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    • v.30 no.3
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    • pp.70-81
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    • 2021
  • This study evaluated the recyclability of waste plastics in used coffee capsules disposed of as municipal waste. For recycling, a new material separation process was developed to remove the coffee grounds through primary crushing, washing, sieving, and secondary crushing, followed by corona discharge electrostatic separation. Furthermore, for the under 10 mm size fraction samples, the aluminum removal and the plastic recovery were 95.4% and 98.3%, respectively, under optimal conditions. In addition, for the 15 mm fraction samples, the aluminum removal and the plastic recovery were 91.3% and 97.2%, respectively. To evaluate the recyclability of the separated waste plastics, the samples were pelleted, and their material properties were analyzed. No hazardous substances were detected, and the results were similar to those for homo-PP. Therefore, it was confirmed tha t sufficient functiona lity existed a s recycled PP. However, owing to the da rk color of the pellets, limited applications to black or dark products are expected.

Gas Transport Properties of Soluble Polyimides Containing Alicyclic Dianhydride (지환족 다이안하이드라이드를 포함하는 용해성 폴리이미드의 기체투과특성)

  • Kim, Eun Hee;Park, Chae Young;Kim, Jeong-Hoon
    • Membrane Journal
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    • v.24 no.2
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    • pp.100-106
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    • 2014
  • In this work, soluble polyimides were synthesized and characterized from 5-(2,5-dioxotetrahydrofuryl)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride (DOCDA) and two diamines such as 4,4'-diaminodiphenylether (ODA), 1,4-phenylenediamine (p-PDA). Their thermal properties were analyzed with differential scanning calorimeter (DSC). The gas permeability coefficients (P) and ideal selectivity for $CH_4$ and $CO_2$ of the prepared polyimide membranes were measured with a time-lag apparatus. DOCDA-ODA, DOCDA-p-PDA showed good permeability and selectivity; the permeabilities of $CO_2$ was 6.10, 0.74 barrers and the selectivity of $CO_2/CH_4$ were 67.03, 46.25, respectively. Therefore, DOCDA-ODA showed good possibility as gas separation membrane.

Photovoltaic Performance of Crystalline Silicon Recovered from Solar Cell Using Various Chemical Concentrations in a Multi-Stage Process (습식 화학 공정에 의한 태양전지로부터 고순도 실리콘 회수 및 이를 이용한 태양전지 재제조)

  • Noh, Min-Ho;Lee, Jun-Kyu;Ahn, Young-Soo;Yeo, Jeong-Gu;Lee, Jin-Seok;Kang, Gi-Hwan;Cho, Churl-Hee
    • Korean Journal of Materials Research
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    • v.29 no.11
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    • pp.697-702
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    • 2019
  • In this study, using a wet chemical process, we evaluate the effectiveness of different solution concentrations in removing layers from a solar cell, which is necessary for recovery of high-purity silicon. A 4-step wet etching process is applied to a 6-inch back surface field(BSF) solar cell. The metal electrode is removed in the first and second steps of the process, and the anti-reflection coating(ARC) is removed in the third step. In the fourth step, high purity silicon is recovered by simultaneously removing the emitter and the BSF layer from the solar cell. It is confirmed by inductively coupled plasma mass spectroscopy(ICP-MS) and secondary ion mass spectroscopy(SIMS) analyses that the effectiveness of layer removal increases with increasing chemical concentrations. The purity of silicon recovered through the process, using the optimal concentration for each process, is analyzed using inductively coupled plasma atomic emission spectroscopy(ICP-AES). In addition, the silicon wafer is recovered through optimum etching conditions for silicon recovery, and the solar cell is remanufactured using this recovered silicon wafer. The efficiency of the remanufactured solar cell is very similar to that of a commercial wafer-based solar cell, and sufficient for use in the PV industry.

Extraction of Pure Si from an Al-Si Alloy Melt during Solidification by Centrifugal Force (Al-Si 합금 융체로부터 순 실리콘의 원심분리 추출)

  • Cho, Ju-Young;Kang, Bok-Hyun;Kim, Ki-Young
    • Korean Journal of Metals and Materials
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    • v.49 no.11
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    • pp.874-881
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    • 2011
  • The present study describes a new technique to extract the primary silicon from an Al-Si alloy melt using centrifugal force during its solidification. The primary silicon was separated from an Al-50 wt.%Si alloy by centrifugal force in the form of a foam, which facilitated subsequent acid leaching to extract the pure silicon due to its wide surface area. The foam recovery after centrifugal separation was decreased as centrifugal acceleration was increased. The final recovery after acid leaching became closer to the solid fraction of the alloy, which was calculated from the Al-Si binary phase diagram, with increasing centrifugal acceleration due to the effective removal of the attached Al on the foam. The purity of the primary silicon obtained by the centrifugal separation method was over 99.99%, with only aluminum being also present.

Ion-Exchange Separation of Thorium in Monazite (이온交換樹指에 依한 토리움分離)

  • Choi, Han-Suk;Ha, Young-Gu
    • Journal of the Korean Chemical Society
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    • v.5 no.1
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    • pp.56-59
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    • 1961
  • Ion exchange procedure was studied for the separation of thorium from the acidic solution obtained by means of decomposition of monazite with alkali solution. Present cation exchange method consists of adsorption of cations from the sample solution (ca. 0.6N HCl acidic) onto Amberlite IR-120 resin, elution of all of the rare earth cations with 700 ml. of 2N Hydrochloric acid, and recovery of the thorium by elution with 200ml. of 6N sulfaric acid. Thorium recovery by the ion-exchange method mentioned above, was quantitative, and it is concluded that this ion-exchange method may be used not only for industrial separation of thorium from rare earths but also for quantitative determination of thorium with relative error, ${\pm}1.0.$.

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Study on the Multi-stage Hollow Fiber Membrane Modules for SF6 Gas Separation (불화가스 분리를 위한 중공사막 모듈의 다단 기체분리공정 연구)

  • Jeong, Su Jung;Lim, Joo Hwan;Koh, Hyung Chul;Ha, Seong Yong
    • Membrane Journal
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    • v.26 no.2
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    • pp.159-165
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    • 2016
  • Polyimide hollow fiber membrane modules were prepared in order to investigate the process of multi stage gas separation. The modules performance was carried out using 50/50 of $N_2/SF_6$ mixed gas. The membrane modules has been tested for measuring gas flow rate and concentration under various stage cut at 0.5 MPa. The membrane modules showed a high recovery ratio at the same stage cut as $N_2/SF_6$ selectivity increased. Two stage process was fulfilled for improving $SF_6$ recovery ratio and $SF_6$ concentration. Eventually, two stage process showed higher performance of $SF_6$ recovery ratio and concentration ($SF_6$ recovery ratio = 95%, $SF_6$ conc. = 98%).

Large-scale Recovery of Recombinant Protein Inclusion Bodies Expressed in Escherichia coli

  • Middelberg. Anton P.J.
    • Journal of Microbiology and Biotechnology
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    • v.6 no.4
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    • pp.225-231
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    • 1996
  • The production of recombinant proteins in Escherichia coli often leads to the formation of an intracellular inclusion body. Key process steps that can determine the economics of large-scale protein production from inclusion bodies are fermentation, inclusion body recovery, and protein refolding. Compared with protein refolding and fermentation, inclusion body recovery has received scant research attention. Nevertheless, it can control the final product yield and hence process cost for some products. Optimal separation of inclusion bodies and cell debris can also aid subsequent operations by removing contaminant particulates that foul chromatographic resins and contain antigenic pyrogens. In this review, the properties of inclusion bodies and cellular debris are therefore examined. Attempts to optimise the centrifugal separation of inclusion bodies and debris are also discussed.

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Development of Triboelectrostatic Separation Technique for Material Separation of ABS and PS Mixed Plastic Waste (ABS와 PS 혼합(混合) 폐플라스틱 재질분리(材質分利)를 위한 마찰하전형정전선별(摩擦荷電型靜電選別) 기술개발(技術開發))

  • Lee, Eun-Seon;Baek, Sang-Ho;Kim, Su-Kang;Choi, Woo-Zin;Chin, Ho-Ill;Jeon, Ho-Seok
    • Resources Recycling
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    • v.22 no.6
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    • pp.33-40
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    • 2013
  • Due to the environmental problem caused by plastics largely used in various fields, the importance of recycling is being emphasized. A research on material separation of ABS and PS mixed plastic waste, using a triboelectrostatic separator, was carried out for recovery the ABS. As a results of research on charging characteristic for choosing charging material, it was confirmed that ABS was optimum charging material for a tribo-charger in the material separation of ABS and PS. In the material separation using ABS charger, ABS grade of 99.5% and recovery of 92.5% were achieved at 20 kV, splitter position +2 cm from the center and 30% relative humidity. Therefore, material separation technique for recycling ABS and PS mixed plastic waste was established.