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http://dx.doi.org/10.14579/MEMBRANE_JOURNAL.2014.24.2.100

Gas Transport Properties of Soluble Polyimides Containing Alicyclic Dianhydride  

Kim, Eun Hee (Resources Separation & Recovery Research Group (RSRRG), Environmental Resources and Process Research Center, Korea Research Institute of Chemical Technology)
Park, Chae Young (Resources Separation & Recovery Research Group (RSRRG), Environmental Resources and Process Research Center, Korea Research Institute of Chemical Technology)
Kim, Jeong-Hoon (Resources Separation & Recovery Research Group (RSRRG), Environmental Resources and Process Research Center, Korea Research Institute of Chemical Technology)
Publication Information
Membrane Journal / v.24, no.2, 2014 , pp. 100-106 More about this Journal
Abstract
In this work, soluble polyimides were synthesized and characterized from 5-(2,5-dioxotetrahydrofuryl)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride (DOCDA) and two diamines such as 4,4'-diaminodiphenylether (ODA), 1,4-phenylenediamine (p-PDA). Their thermal properties were analyzed with differential scanning calorimeter (DSC). The gas permeability coefficients (P) and ideal selectivity for $CH_4$ and $CO_2$ of the prepared polyimide membranes were measured with a time-lag apparatus. DOCDA-ODA, DOCDA-p-PDA showed good permeability and selectivity; the permeabilities of $CO_2$ was 6.10, 0.74 barrers and the selectivity of $CO_2/CH_4$ were 67.03, 46.25, respectively. Therefore, DOCDA-ODA showed good possibility as gas separation membrane.
Keywords
polyimide; gas separation membrane; permeability; selectivity;
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1 J. N. Barsema, G. C. Kapantaidakis, N. F. A. van der Vegt, G. H. Koops, and M. Wessling, "Preparation and characterization of highly selective dense and hollow fiber asymmetric membranes based on BTDATDI/ MDI co-polyimide", J. Membr. Sci., 216, 195 (2003).   DOI   ScienceOn
2 J. J. Krol, M. Boerrigter, and G. H. Koops, "Polyimide hollow fiber gas separation membranes: preparation and the suppression of plasticization in propane/propylene environments", J. Membr. Sci., 184, 275 (2001).   DOI   ScienceOn
3 E.I. DUPONT DE NEMOURS AND COMPANY, US, 6-142237 (1994).
4 C. Hulubei, E. Hamciuc, and M. Bruma, "New polyimides based on Epiclon", Rev. Roum. Chim., 52, 1063 (2007).
5 K. Xie, J. G. Liu, H. W. ZHOU, S. Y. Zhang, M. H. He, and S. Y. Yang, "Soluble fluoro-polyimides derived from 1,3-bis(4-amino-2-trifluoromethyl- phen oxy) benzene and dianhydrides", Polymer, 42, 7267 (2001).   DOI   ScienceOn
6 S. S. Hosseini and T. S. Chung, "Carbon membranes from blends of PBI and polyimides for $N_{2}/CH_{4}$ and $CO_{2}/CH_{4}$ separation and hydrogen purification", J. Membr. Sci., 328, 174 (2009).   DOI   ScienceOn
7 M. D. Guiver, G. P. Robertson, Y. Dai, F. Bilodeau, Y. S. Kang, K. J. Lee, J. Y. Jho, and J. O. Won, "Structural Characterization and Gas-Transport Properties of Brominated Matrimid Polyimide", J. Polym. Sci., Part A: Polym. Chem., 40, 4193 (2002).   DOI   ScienceOn
8 B. D. Reid, F. A. Ruiz-Trevino, I. H. Musselman, K. J. Balkus, and J. P. Ferraris, "Gas Permeability Properties of Polysulfone Membranes Containing the Mesoporous Molecular Sieve MCM-41", Chemistry of materials, 13, 2366 (2001).   DOI
9 H. Yamamoto, Y. Mi, S. A. Stern, and A. K. St. Clair, "Structure/permeability relationships of polyimide membranes. II", J. Polym. Sci. Part B: Polym. Phys., 28, 2291 (1990).   DOI
10 H. Y. Ha, S. W. Nam, and S. A. Hong, "Fabrication and Application of Inorganic Membranes", Membrane Journal, 9, 63 (1993).
11 T. M. Moy and J. E. McGrath, "Synthesis of hydroxyl- containing polyimides derived from 4,6-diamino- resorcinol dihydrochloride and aromatic tetracarboxylic dianhydrides", J. Polym. Sci., Part A: Polym. Chem., 32, 1903 (1994).   DOI   ScienceOn
12 S. Itamara, M. Yamada, S. Tamura, T. Matsumoto, and T. Kurosaki, "Soluble polyimides with polyalicyclic structure. 1. Polyimides from bicyclo[2.2.2] oct-7-ene-2-exo,3-exo,5-exo,6-exo-tetracarboxylic 2,3:5,6-dianhydrides", Macromolecules, 26, 3490 (1993).   DOI   ScienceOn
13 M. Kusama, T. Matsumoto, and T. Kurosaki, "Soluble Polyimides with Polyalicyclic Structure.3. Polyimides from (4arH,8acH)-Decahydro-1t,4t:5c,8cdimethanonaphthalene- 2t,3t,6c,7c-tetracarboxylic 2,3:6,7-Dianhydride", Macromolecules, 27, 1117 (1994).   DOI   ScienceOn
14 M. Yamada, M. Kusama, T. Matsumoto, and T. Kurosaki, "Soluble polyimides with polyalicyclic structure. 2. Polyimides from bicyclo[2.2.1]heptane- 2-exo-3-exo- 5-exo-6-exo-tetracarboxylic 2,3:5,6-dianhydride", Macromolecules, 26, 4961 (1993).   DOI   ScienceOn
15 N. Ariga, Jpn. KoKai Tokkyo Koho 57-121035, 57-177050 (1982).
16 S. H. Hsiao, C. P. Yang, and C. K. Lin, "Syntheses and Properties of Polyimides based on Bis(p-aminophenoxy) biphenyls", J. Polym. Res., 2, 1 (1995).   DOI
17 M. Mulder, "Basic Principles of Membrane Technolo gy", Kluwer Academic Publisher, Dordrecht (1991).
18 W. S. W. Ho and K. K. Sirkar, "Membrane Handbook", Van Nostrand Reinhold, New York (1992).
19 D. R. Paul and Y. Yampol'skii, "Polymeric Gas separation Membranes", CRC Press. London (1990).
20 R. E. Kesting and A. K. Fritzsche, "Polymeric Gas Separation Membranes", John Wiley & Sons., New York (1993).
21 S. A. Stern, "Polymers for gas separations: the next decade", J. Membr. Sci., 94, 1 (1994).   DOI   ScienceOn
22 W. M. Lee, "Selection of barrier materials from molecular structure", epolym. Eng. sci., 20, 65 (1980).   DOI
23 J. A. Moor and D. R. Robello, "Curable, thermally stable poly(enaminonitriles)", Macromolecules, 22, 1084 (1989).   DOI   ScienceOn
24 K. Matsumoto and P. Xu, "Gas permeation properties of hexafluoro aromatic polyimides", J. Appl. Polym. Sci., 47, 1961 (1993).   DOI
25 K. Haraya and S. T. Hwang, "Permeation of oxygen, argon and nitrogen through polymer membranes", J. Membr. Sci., 71, 13 (1992).   DOI   ScienceOn
26 M. R. Coleman and W. J. Koros, "Isomeric polyimides based on fluorinated dianhydrides and diamines for gas separation applications", J. Membr. Sci., 50, 285 (1990).   DOI   ScienceOn