• Bulletin of the Korean Chemical Society
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• v.34 no.9
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• pp.2697-2701
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• 2013

The solvolysis rate constants of piperonyloyl chloride (1) in 27 different solvents are well correlated with the extended Grunwald-Winstein equation, using the $N_T$ solvent nucleophilicity scale, $Y_{Cl}$ solvent ionizing scale, and I aromatic ring parameter with sensitivity values of $0.30{\pm}0.05$, $0.71{\pm}0.02$, and $0.60{\pm}0.04$ for l, m, and h, respectively. The solvent kinetic isotope effect values (SKIE, $k_{MeOH}/k_{MeOD}$ and $k_{50%MeOD-50%D2O}$) of 1.16 and 1.12 were also in accord with the values for the $S_N1$ mechanism and/or the dissociative $S_N2$ mechanism. The product selectivity values (S) for solvolysis of 1 in alcohol/water mixtures were in the range of 0.5 to 1.9, which is also consistent with the proposed unimolecular ionization mechanism.

• Journal of Korea Soil Environment Society
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• v.1 no.2
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• pp.43-50
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• 1996

The adsorption charateristics of lead(II) ions on Aspergillus niger and Rhizopus arrhizus were investigated. Adsorption amount of A. niger and R. arrhizus was about 95 mg/g and 25 mg/g, respectively. These biomass was approached to adsorption equilibrium within reaction time of 1hr because of their high reactivity. The uptake of lead ion by A. niger was less sensitivity than it by R. arrhizus on the inhibition effect of alkali metals and the decreasing ratio of uptake of lead ion of A. niger and R. arrhizus by inhibition effect of alkali metals was 37% and 50%, respectively. In pre-treatment on these biomass, NaOH treatment was contributed high adsorption capacity to these biomass. Then, adsorption amount of A. niger and R. allhizus was increased about 25 mg/g and 10 mg/g, respectively. In isotherm for the adsorption of lead ion based on Freundlich equation, 1/n value of A. niger and R. ar고izus was calculated the range of 0.28-0.56 and 0.44-0.67, respectively.

• Journal of the Korean Chemical Society
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• v.61 no.1
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• pp.25-28
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• 2017

Solvolyses with the reaction center being the sulfur of 4-(chlorosulfonyl)biphenyl ($C_6H_5C_6H_4SO_2Cl$, 1) was studied under solvolytic conditions and the extended Grunwald-Winstein equation was applied. The thirty five kinds of solvents gave a reasonable extended Grunwald-Winstein plot with a correlation coefficient (R) of 0.940. The sensitivity values (l = 0.60 and m = 0.47) of 1 were smaller than those obtained for benzenesulfonyl chloride ($C_6H_5SO_2Cl$, 2; l = 1.10 and m = 0.61) proposed to undergo dissociative $S_N2$ mechanism. These l and m values for the solvolyses of 1 can be considered to support a $S_N2$ pathway with some ionization reaction. The activation parameters, ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$, were determined and they are also in line with values expected for a bimolecular reaction. The kinetic solvent isotope effect (KSIE) of 1.26 is also in accord with a bimolecular mechanism, probably assisted by general-base catalysis.

• Nuclear Engineering and Technology
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• v.48 no.1
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• pp.43-54
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• 2016

In the present paper, development of the three-dimensional (3D) computational code based on Galerkin finite element method (GFEM) for solving the multigroup forward/adjoint diffusion equation in both rectangular and hexagonal geometries is reported. Linear approximation of shape functions in the GFEM with unstructured tetrahedron elements is used in the calculation. Both criticality and fixed source calculations may be performed using the developed GFEM-3D computational code. An acceptable level of accuracy at a low computational cost is the main advantage of applying the unstructured tetrahedron elements. The unstructured tetrahedron elements generated with Gambit software are used in the GFEM-3D computational code through a developed interface. The forward/adjoint multiplication factor, forward/adjoint flux distribution, and power distribution in the reactor core are calculated using the power iteration method. Criticality calculations are benchmarked against the valid solution of the neutron diffusion equation for International Atomic Energy Agency (IAEA)-3D and Water-Water Energetic Reactor (VVER)-1000 reactor cores. In addition, validation of the calculations against the $P_1$ approximation of the transport theory is investigated in relation to the liquid metal fast breeder reactor benchmark problem. The neutron fixed source calculations are benchmarked through a comparison with the results obtained from similar computational codes. Finally, an analysis of the sensitivity of calculations to the number of elements is performed.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.6 no.3
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• pp.234-244
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• 1994

Longshore currents driven by monochromatic waves have been described using 2-equation $textsc{k}$-ι turbulence transport model. When using $textsc{k}$-ι closure both profiles of eddy viscosity and current velocity are found to be satisfactory. Several terms of ι equation are related to various variables concerned with turbulence mechanism. New form of turbulence frequency used in ι equation is suggested in the present approach, and non-dimensional parameters are evaluated by comparing the computational results with the laboratory measurements. Various values of a large range are applied to the non-dimensional parameters for the sensitivity test and in order to improve the predictability common values of constants are deduced, which produce similarly good computational results for the well-controlled laboratory measurements.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2004.11a
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• pp.721-726
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• 2004

A simplified method for the computation of first second and higher order derivatives of eigenvalues and eigenvectors derivatives associated with repeated eigenvalues is presented. Adjacent eigenvectors and orthonormal conditions are used to compose an algebraic equation whose order is (n+m)x(n+m), where n is the number of coordinates and m is the number of multiplicity of the repeated eigenvalues. The algebraic equation developed can be used to compute derivatives of both eigenvalues and eigenvectors simultaneously. Since the coefficient matrix in the proposed algebraic equation is non-singular, symmetric and based on N-space it is numerically stable and very efficient compared to previous methods. This method can be consistently applied to structural systems with structural design parameters and mechanical systems with lumped design parameters. To verify the effectiveness of the proposed method, the finite element model of the cantilever beam is considered.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.28 no.1
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• pp.1-10
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• 2004

This paper presents a navigation garde capacitive microaccelerometer, whose low-noise high-resolution detection capability is achieved by a new electrode design based on a high-amplitude anti-phase sense voltage. We reduce the mechanical noise of the microaccelerometer to the level of 5.5$\mu\textrm{g}$/(equation omitted) by increasing the proof-mass based on deep RIE process of an SOI wafer. We reduce the electrical noise as low as 0.6$\mu\textrm{g}$/(equation omitted) by using an anti-phase high-amplitude square-wave sense voltage of 19V. The nonlinearity problem caused by the high-amplitude sense voltage is solved by a new electrode design of branched finger type. Combined use of the branched finger electrode and high-amplitude sense voltage generates self force-balancing effects, resulting in an 140％ increase of the bandwidth from 726㎐ to 1,734㎐. For a fixed sense voltage of 10V, the total noise is measured as 2.6$\mu\textrm{g}$/(equation omitted) at the air pressure of 3.9torr, which is the 51％ of the total noise of 5.1$\mu\textrm{g}$/(equation omitted) at the atmospheric pressure. From the excitation test using 1g, 10㎐ sinusoidal acceleration, the signal-to-noise ratio of the fabricated microaccelerometer is measured as 105㏈, which is equivalent to the noise level of 5.7$\mu\textrm{g}$/(equation omitted). The sensitivity and linearity of the branched finger capacitive microaccelerometer are measured as 0.638V/g and 0.044％, respectively.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.5
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• pp.1409-1420
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• 2014

In this work, we have carried out a sensitivity analysis of hydrogeologic parameters such as reaction factor and drainable pore space in groundwater table fluctuation model and have found characteristics of parameter distribution according to the altitude. We found that drainable pore space which is hydrogeologic parameter of aquifer didn't show any trend with altitude while reaction factor which is groundwater flow characteristic showed clear trend with altitude. To find a sensitivity of parameters, we compared RMSE of estimated groundwater recharges by using the mean value and linear relationship of parameters. As results, the linear equation derived for entire watersheds could be applied to estimate parameters for ungauged watershed. Furthermore, the features of parameter distribution can be used to predict hydrogeologic parameter in ungauged watersheds and it is expected that those features could be used for a basic data for groundwater modeling.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.17 no.2 s.105
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• pp.158-164
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• 2006

In this paper, we proposed a new algorithm of the inverse scattering for the reconstruction of unknown dielectric scatterers using the finite-difference time-domain method and the design sensitivity analysis. We introduced the design sensitivity analysis based on the gradient information for the fast convergence of the reconstruction. By introducing the adjoint variable method for the efficient calculation, we derived the adjoint variable equation. As an optimal algorithm, we used the steepest descent method and reconstructed the dielectric targets using the iterative estimation. To verify our algorithm, we will show the numerical examples for the two-dimensional $TM^2$ cases.

• Macromolecular Research
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• v.17 no.12
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• pp.1025-1031
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• 2009

Several kinds of biodegradable hydrogels were prepared via in situ photopolymerization of Pluronic F127/poly($\varepsilon$-caprolactone) macromer and acrylic acid (AA) comonomer in aqueous medium. The swelling kinetics measurements showed that the resultant hydrogels exhibited both thermo- and pH-sensitive behaviors, and that this stimuli-responsiveness underwent a fast reversible process. With increasing pH of the local buffer solutions, the pH sensitivity of the hydrogels was increased, while the temperature sensitivity was decreased. In vitro hydrolytic degradation in the buffer solution (pH 7.4, $37^{\circ}C$), the degradation rate of the hydrogels was greatly improved due to the introduction of the AA comonomer. The in vitro release profiles of bovine serum albumin (BSA) in-situ embedded into the hydrogels were also investigated: the release mechanism of BSA based on the Peppas equation was followed Case II diffusion. Such biodegradable dual-sensitive hydrogel materials may have more advantages as a potentially interesting platform for smart drug delivery carriers and tissue engineering scaffolds.