• 제목/요약/키워드: Semiconductive

검색결과 109건 처리시간 0.025초

카본블랙의 함량에 따른 송전용 반도전 재료의 기계적 특성 및 Smoothness (Mechanical Properties and Smoothness of Semiconductive Shield for Power Transmission by Carbon Black Content)

  • 이경용;양종석;이관우;최용성;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.301-307
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    • 2004
  • To improve mean-life and reliability of power cable in this paper, we have investigated stress-strain and smoothness showing by changing the content of carbon black that is semiconductive additives for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Stress-strain of specimens was measured by TENSOMETER 2000. A speed of measurement was 200[mm/min], ranges of stress and strain were $400(Kgf/cm^2)$ and 600[%]. In addition tests of stress-strain were progressed by aging specimens at air oven. Finally we wished to look for protrusion of specimens by using smoothness tester. According to increasing the content of carbon black from this experimental result, yield stress was increased, while strain was decreased. And stress-strain were decreased some after aging because of oxidation reaction of chemical defect. Lastly surface of specimens smoothed generally.

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전력케이블에서 반도전 재료층의 불순물 측정 및 물성에 관한 연구 (A Study on Impurities Measurement and Physical Properties of Semiconductive Shield at Power Cable)

  • 이경용;양종석;최용성;박대희
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권9호
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    • pp.455-458
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    • 2004
  • In this paper, we investigated impurities content and physical properties showing by changing the content of carbon black that is semiconductive materials for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Impurities content of specimens was measured by ICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometer), and density of specimens were measured by density meter And then specific heat (Cp) was measured by DSC (Differential Scanning Calorimetry). A ranges of measurement temperature were from $0^{\circ}[C]$ to $200^{\circ}[C]$, and heating temperature was $4^{\circ}[C/min]$. Impurities content was highly measured according to increasing the content of carbon black from this experimental result, also density was increased according to these properties. Especially impurities content values of the Al and A2 of existing resins were measured more than 4000[ppm]. Specific heat from the DSC results was decreased according to increasing the content of carbon black. Because ionic impurities of carbon black having Fe, Co, Mn, Al and Zn are rapidly passed kinetic energy increasing the number of times breaking during the unit time with the near particles according to increasing vibration of particles by the applied heat energy.

수열합성법에 의한 반도성 나노 (Ba1-xSbx)TiO3 분말제조 및 PTCR 특성평가 (Preparation and PTCR Characteristics of Semiconductive Nano (Ba1-xSbx)TiO3 Ceramic PowderS by Hydrothermal Process)

  • 최용각;이종현;이혁희;원창환
    • 한국재료학회지
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    • 제12권3호
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    • pp.169-175
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    • 2002
  • Semiconductive nano $(Ba_{1-x}Sb_x)TiO_3$ powders were synthesized by the hydrothermal process and Sb was simultaneously doped in the hydrothermal condition. $(Ba_{1-x}Sb_x)TiO_3$ powders obtained from optimum condition(at 20$0^{\circ}C$ for 3hr) exhibited spherical shape, high purity and nano size. The PTCR characteristics was observed when 0.1 and 0.2 mole% Sb were added and sintered at over 130$0^{\circ}C$ for 1 hour, respectively. And The ceramics exhibit the PTCR characteristics with a resistively jump $ratio($\rho$_{max}/$\rho$_{min})$ of about $10^4$. Also we found that PTCR characteristics were dependent on the microstructure.

Volume Resistivity, Specific Heat and Thermal Conductive Properties of the Semiconductive Shield in Power Cables

  • Lee Kyoung-Yong;Choi Yong-Sung;Park Dae-Hee
    • KIEE International Transactions on Electrophysics and Applications
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    • 제5C권3호
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    • pp.89-96
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    • 2005
  • To improve the mean-life and reliability of power cables, we have investigated the volume resistivity and thermal properties demonstrated by changing the content of carbon black, an additive of the semiconductive shield for underground power transmission. Nine specimens were made of sheet form for measurement. Volume resistivity of the specimens was measured by a volume resistivity meter after 10 minutes in a preheated oven at temperatures of both 25$\pm$1[$^{\circ}C$] and 90$\pm$ 1[$^{\circ}C$]. As well, specific heat (Cp) and thermal conductivity were measured by Nano Flash Diffusivity and DSC (Differential Scanning Calorimetry). The ranges of measurement temperature were from 0[$^{\circ}C$] to 200[$^{\circ}C$], and heating temperature was 4[$^{\circ}C$/min]. From these experimental results, volume resistivity was high according to an increase of the content of carbon black. Specific heat was decreased, while thermal conductivity was increased according to a rise in the content of carbon black. Furthermore, both specific heat and thermal conductivity were increased by heating temperature because the volume of materials was expanded according to a rise in temperature.

지중 전력케이블용 반도전재료의 이온성 불순물에 따른 흡습 및 열적특성 (Absorption and Thermal Properties According to Ionic Impurities of Semiconductive Materials for Underground Power Cable)

  • 이경용;최용성;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집 방전 플라즈마 유기절연재료 초전도 자성체연구회
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    • pp.133-137
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    • 2004
  • In this paper, we investigated impurities content, absorption properties, and thermal properties showing by changing the content of carbon black which is semiconductive materials for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Impurities content of specimens and absorption properties were measured by ICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometer) and Karl Fisher. And high temperature, heat degradation initiation temperature, and heat weight loss were measured by TGA (Thermogravimetric Analysis). The dimension of measurement temperature was 0$[^{\circ}]$ to 800$[^{\circ}]$, and rising temperature was 10$[^{\circ}/min]$. Impurities content was highly measured according to increasing the content of carbon black from this experimental result also absorption amount was increased according to these properties. Specially, impurities content values of the A1 and A2 of existing resins were measured more than 4000[ppm]. Heat degradation initiation temperature from the TGA results was decreased according to increasing the content of carbon black. All over, heat stabilities were EEA>EBA>pEVA. That is, heat stabilities of EVA containing the weak VA(vinyl acetate) against heat was measured the lowest.

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전력케이블용 가교 폴리에칠렌과 반도재료의 전기적 특성 (Electrical Characteristics of XLPE/Semicinductor Sheet for Power Cables)

  • 백광현;이경용;이관우;최용성;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집 방전 플라즈마 유기절연재료 초전도 자성체연구회
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    • pp.142-145
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    • 2004
  • In this paper, we researched the dielectric properties and voltage dependence on slice XLPE sheet from 22[kV] and 154[kV] power cable. studied effect for impurities and water for semiconductive shied through a dielectric properties experiment to estimate performance of insulating material in power cable. Capacitance and $tan{\delta}$ of 22[kV], 154[kV] were 52/42 pF and $7.4{\times}10^{-4}$, $2.1510^{-4}$, respectively. In these results, the trend was increased with the increase of temperature. The $tan{\delta}$ of XLPE/semiconductive layer and XLPE/water/semiconductive layer were increased as compared with that of XLPE. dielectric properties reliability of $tan{\delta}$ was small.

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DMA를 사용한 전력케이블 내 반도전층 재료의 탄성율 및 에너지 손실 측정 (Modulus and Fractural Side Measurement of Semiconductive Shield (Materials) in Power Cable Using the DMA)

  • 앙종석;이경용;최용성;남종철;박동하;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.213-214
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    • 2005
  • To measure modulus and damping of semiconductive materials in power cable, we have investigated the modulus and damping of semiconductive materials showed by changing the content of carbon black. Then they were produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[$kg/cm^2$]. The content of conduct ive carbon black was the vailable, and their contents were 20, 30 and 40[wt%], respectively. The modulus and $Tan\delta$ experiments were measured by DMA 2980. Ranges of measurement temperature from -50[$^{\circ}C$] to 100[$^{\circ}C$] and measurement frequency is 1[Hz]. The modulus of specimens was increased according to a increment of a carbon black content. And modulus was rapidly decreased at the glass transition temperature. The $Tan\delta$ of specimens was decreased according to a increment of a carbon black content.

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반도전 재료의 화학적 특성 (Chemical Properties of Semiconductive Shield)

  • 안종현;김향곤
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 추계학술대회 논문집 전기설비전문위원
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    • pp.203-206
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    • 2008
  • To improve mean-life and reliability of power cable in this study, we have investigated chemical properties showing by changing the content of carbon black that is semiconductive additives for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Chemical properties of specimens was measured by FT-ATR (Fourier Transform Attenuated Total Reflectance). The condition of specimens was a solid sheet. We could observe functional group (C=O, carbonyl group) of specimens through FT-ATR. From these experimental result, the concentration of functional group (C=O) was high according to increasing the content of carbon black. We could know EEA was excellent more than other specimens from above experimental results.

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Karl Fischer를 통한 전력케이블용 반도전 Composite 특성 연구 (A Study on the Property of Semiconductive Shield Composite through Karl Fischer Method in Power Cable)

  • 양훈;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 Techno-Fair 및 합동춘계학술대회 논문집 전기물성,응용부문
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    • pp.187-188
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    • 2008
  • In this paper, we have investigated water content of semiconductive shield materials for power cables, EEA(Ethylene Ethyl Acrylate) is used polymer matrix. And filler is used CNT(Carbon Nanotube) and CB(Carbon Black). EEA, CNT and CB is favor moisture. In case of EEA, it has polyolefin resin that strong polarity combination. To research water content, experimental method used KF(Karl Fischer). KF method is Electrochemical titration based on chemical reaction. As a result, specification by KEPCO(Korea Electric Power Corporation) is lower than 800ppm. CNT and CB ratio of 80 versus 20 is best specimen that had lowest moisture content. It seem likely to increase crosslinking rate, CNT between CB.

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