• 제목/요약/키워드: Semi-Empirical Methods

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이론적 수치계산 모델(TUV)과 Eppley radiometer를 이용한 $J_{NO_2}$의 산정에 관한 비교연구 (A study on comparison of two methods for determination of $J_{NO_2}$ between theoretical and semi-empirical radiometric method)

  • 김세웅;이강웅;김경렬
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 1999년도 추계학술대회 논문집
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    • pp.428-429
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    • 1999
  • 잘 알려져 있듯 광화학 오존 생성의 첫 단계는 N $O_2$가 자외선을 받아 NO와 O로 해리되는 과정이다. N $O_2$ + h$\upsilon$ $\longrightarrow$ NO + O 일반적으로 이러한 광해리 반응을 정량화하기 위하여 아래의 식과 같이 광해리 상수, $J_{NO2}$를 정의한다.(중략)략)

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Impact of Public Information Arrivals on Cryptocurrency Market: A Case of Twitter Posts on Ripple

  • Gunay, Samet
    • East Asian Economic Review
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    • 제23권2호
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    • pp.149-168
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    • 2019
  • Public information arrivals and their immediate incorporation in asset price is a key component of semi-strong form of the Efficient Market Hypothesis. In this study, we explore the impact of public information arrivals on cryptocurrency market via Twitter posts. The empirical analysis was conducted through various methods including Kapetanios unit root test, Maki cointegration analysis and Markov regime switching regression analysis. Results indicate that while in bull market positive public information arrivals have a positive influence on Ripple's value; in bear market, however, even if the company releases good news, it does not divert out the Ripple from downward trend.

공간데이터 크리깅 적용을 위한 공간상관함수 추정 (Estimation of Spatial Coherency Functions for Kriging of Spatial Data)

  • 배태석
    • 한국측량학회지
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    • 제34권1호
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    • pp.91-98
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    • 2016
  • 지구통계학적인 공간분석의 대표적인 방법인 크리깅(kriging)을 적용하기 위해서는 두 관측점 사이의 거리에 기반한 상관성을 나타내는 공간상관함수의 추정이 우선적으로 이루어져야 한다. 본 연구에서는 다양한 크리깅에 적용할 수 있는 대표적인 상관함수인 semi-variogram, homeogram, covariance function에 대하여 국가지오이드 모델을 기반으로 추정하였다. 경위도 각각 2°의 대상지역 내 통합기준점의 지오이드고를 이용하였으며, 선형모델을 이용하여 공간적인 편향성을 제거하였다. 전체 100개의 샘플 포인트에 대해서 중복되지 않은 두 점 간의 거리를 기준으로 구간을 나누고, 각 함수에 대한 경험적인 값을 계산하였다. 공간상관함수의 경험적인 값은 각각 두 개의 모델에 최소제곱조정 방법으로 피팅한 결과 semi-variogram의 wave 모델 적합도가 가장 높았으며, homeogram과 covariance function은 exponential 모델이 상대적으로 좋은 피팅 결과를 보였다. 본 연구에서 결정한 공간상관함수는 추후 다양한 크리깅 방법을 통해 임의 지점에서의 예측값에 대한 정확도 검증과 이에 대한 평균제곱예측오차(Mean Squared Prediction Error, MSPE)를 계산함으로써 각 함수의 활용성에 대한 추가적인 연구가 수행되어야 한다.

쇄빙선 및 쇄빙상선에 대한 빙저항 추정식과 실측자료의 비교 분석 (A Comparative Study of Ice Resistance Estimation Equations with Measured Data for Icebreakers and Ice-Strengthened Cargo Vessels)

  • 최경식;이우람;이진경
    • 대한조선학회논문집
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    • 제43권2호
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    • pp.147-155
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    • 2006
  • Ice resistance estimation equations based on model tests and full-scale sea trial data from many previous research articles are studied. Measured ice resistance data and its empirical/semi-empirical estimation equations are summarized in common format and are compared with each other, considering three ship categories, i.e, icebreakers, tug/supply vessels, ice-strengthened cargo vessels. The most suitable estimation methods or prediction equations are recommended based on this ice resistance data analysis.

Electronic Structures of a Macrocyclic Fulleropyrrolidine

  • 황선구;이종명;전일철
    • Bulletin of the Korean Chemical Society
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    • 제17권12호
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    • pp.1112-1117
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    • 1996
  • The electronic structures of twenty-seven isomers of a macrocyclic fulleropyrrolidine are investigated with semi-empirical extended Huckel (EH) molecular orbital method. The geometry of each isomer is determined by the molecular mechanics and dynamics methods based on UFF (universal force field) empirical force field. The calculated geometries, such as the carbon-carbon distances of the fullerene moiety, are in good agreement with those of related fullerene derivatives. The EH calculation shows that the formation of macrocyclic pyrrolidine ring on fullerene moiety results in the reduction of the HOMO-LUMO energy gap. From the graphical analysis of the DOS (density of states), PDOS (projected DOS), and MOOP (molecular orbital overlap population) curves, we can find that this reduction is due to splitting of the HOMO of fullerene moiety, which results from the symmetry-breaking and the distortion of the buckminsterfullerene framework from its ideal icosahedral structure.

Strength assessment of RC deep beams and corbels

  • Adrija, D.;Geevar, Indu;Menon, Devdas;Prasad, Meher
    • Structural Engineering and Mechanics
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    • 제77권2호
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    • pp.273-291
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    • 2021
  • The strut-and-tie method (STM) has been widely accepted and used as a rational approach for the design of disturbed regions ('D' regions) of reinforced concrete members such as in corbels and deep beams, where traditional flexure theory does not apply. This paper evaluates the applicability of the equilibrium based STM in strength predictions of deep beams (with rectangular and circular cross-section) and corbels using the available experiments in literature. STM is found to give fairly good results for corbel and deep beams. The failure modes of these deep members are also studied, and an optimum amount of distribution reinforcement is suggested to eliminate the premature diagonal splitting failure. A comparison with existing empirical and semi empirical methods also show that STM gives more reliable results. The nonlinear finite element analysis (NLFEA) of 50 deep beams and 20 corbels could capture the complete behaviour of deep members including crack pattern, failure load and failure load accurately.

Pyrazole 유도체들의 Tautomer들에 대한 Ab Initio와 Semi-Empirical 계산 (Ab Initio and Semi-Empirical Calculations of the Tautomers of Pyrazole Derivatives)

  • 이홍기;임선화;정성경;강성권
    • 대한화학회지
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    • 제39권3호
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    • pp.150-156
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    • 1995
  • Pyrazole 유도체들인 1,2,4-triazolidine-3,5-dione(1)과 1,3,4-oxa(or thia) diazolidine-2,5-dione(2,3)의 lactam-lactim tautomer들을 ab initio, AM1 그리고 PM3 방법으로 연구하였다. 세 가지 방법에서 모두 1 화합물의 가장 안정한 형태는 dilactam인 1a이고 다음으로 lactam-lactim인 2b로 결정되었댜. 계산방법에 따라 1a와 1b의 에너지 차이는 4.1~12.6kcal/mol로 계산되었다. 1a에 대한 ab initio 구조는 X-ray 구조와 잘 일치하고 있다. 2 화합물의 안정도는 2a>2b>2c인 반면 황원자를 포함하고 있는 3 화합물 tautomer들간의 안정도 순서는 계산방법에 의존된다. 3-21G에서는 3a가 3b보다 4.9kcal/mol 안정한 반면 AM1은 3b가 2.71kcal/mol 안정한 결과를 얻었다.

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Pseudo plastic zone analysis of steel frame structures comprising non-compact sections

  • Avery, P.;Mahendran, M.
    • Structural Engineering and Mechanics
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    • 제10권4호
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    • pp.371-392
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    • 2000
  • Application of "advanced analysis" methods suitable for non-linear analysis and design of steel frame structures permits direct and accurate determination of ultimate system strengths, without resort to simplified elastic methods of analysis and semi-empirical specification equations. However, the application of advanced analysis methods has previously been restricted to steel frames comprising only compact sections that are not influenced by the effects of local buckling. A concentrated plasticity method suitable for practical advanced analysis of steel frame structures comprising non-compact sections is presented in this paper. The pseudo plastic zone method implicitly accounts for the effects of gradual cross-sectional yielding, longitudinal spread of plasticity, initial geometric imperfections, residual stresses, and local buckling. The accuracy and precision of the method for the analysis of steel frames comprising non-compact sections is established by comparison with a comprehensive range of analytical benchmark frame solutions. The pseudo plastic zone method is shown to be more accurate and precise than the conventional individual member design methods based on elastic analysis and specification equations.

기어미션용 실증적 기어치형수정에 관한 연구 (Study on Empirical Gear Profile Micro-modifications for Gear Transmission)

  • 장기;왕주겐;류성기
    • 한국기계가공학회지
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    • 제16권3호
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    • pp.54-62
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    • 2017
  • When gears mesh, shock and noise are produced as results of tooth error and tooth deformation under load. Transmission error (TE) is the most important cause of gear noise and vibration because TEs affect the changes of the force and the speed of gears. Gear tooth modification research plays a positive role in reducing TE and improving the design level and transmission performance of transmission systems. In high-precision manufacturing gear, gear tooth modification is also commonly used to reduce noise in practical applications. In order to study the accuracy of gear transmission, some empirical gear profile micro-modifications are introduced, and a helical gear pair is modeled and analyzed in RomaxDesigner software to investigate the utility of these modification methods. Some of these will be selected as experimental proposals for gear pairs, and these manufactured gears will be tested and compared in a semi-anechoic room later. The final purpose of this study is to find reasonable and convenient empirical formulae to facilitate improved gear production.

구동방법에 따른 TFT-LCD 화소 특성 시뮬레이션 (Simulations of TFT-LCD Pixel Characteristics with Different Driving Methods)

  • 흥성진;최종선;이신두
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 C
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    • pp.1603-1605
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    • 2002
  • TFT-LCD is widely used for flat panel display. The large-size TFT-LCD panel requires a high speed driving and various driving methods because of signal delay, which is responsible for the shading effects. In this work, the floating and double driving methods are applied to Pixel Design Array Simulation Tool(PDAST) and the pixel characteristics of TFT-LCD array is simulated. Also, we have implemented the semi-empirical TFT model to PDAST, which makes to obtain a more accurate pixel characteristics.

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