• Title/Summary/Keyword: Selective reduction process

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A Study on Characteristic of NO Reduction by High Level O2Gas in Selective Non-Catalystic Reaction (High Level O2배가스중 NO 저감에 대한 선택적비촉매환원 반응특성에 관한 연구)

  • 이강우;정종현;오광중
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.577-582
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    • 2002
  • Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

A development of diesel engine De-NOx system using the selective catalytic reduction method (선택적 촉매 환원법을 이용한 디젤엔진의 De-NOx 시스템 개발에 관한 연구)

  • 정경열;김재윤;오상훈;박정일;류길수
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2001.05a
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    • pp.187-191
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    • 2001
  • In the paper, an approach to the development of the selective catalytic reduction process of NOx is presented. The reduction process can be efficiently controlled using a conventional combination of feed-forward and feed-back control structures. The aim of this paper is to test and verify an approach to the SCR process which is based on an industrial pilot plant of combustion and nitric oxide formation. The systems are based on measurements of a NOx removal ratio and the fuel flow rate, and NH$_3$slip which are usually available as a part of de-NOx control system.

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Selective Graphene Oxide Reduction Utilizing Photon Energy (광에너지를 활용한 선택적 산화그래핀의 환원)

  • Shin, Jae-Soo;Choi, Eunmi
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.4
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    • pp.16-20
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    • 2018
  • Graphene is attracting attention due to its outstanding properties as line material for next-generation semiconductor. Graphene pattern technology is essential to apply graphene line. Selective graphene oxide reduction as one of graphene pattern method does not require a substrate thereby a high flexibility device can be applied. Particularly, the method using photon energy has advantages of short process time and environment friendly. In this review, we introduce the photocatalytic method and the photo-thermal energy conversion method using photon energy in the selective reduction process of graphene oxides.

New Selective Tungsten Deposition Process by the alternating Cyclic Hydrogen Reduction of $WF_6$ using LPCVD (LPCVD을 사용하여 $WF_6$의 교번적 수소환원 반응에 의한 새로운 선택적 텅스텐 박막 증착)

  • ;Arnold Reisman;Christopher Berry
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.39 no.7
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    • pp.692-701
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    • 1990
  • New selective tungsyen deposition deposition on silicon process is described which makes use of a previously unreported, alternating cyclic,

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Reduction of Nitrogen Oxides with Diesel Oil In Pilot Scale SCR(Selective Catalytic Reduction) Process (파일럿규모의 선택적촉매환원장치에서 디젤유를 이용한 질소산화물 제거)

  • Lee, In-Young;Yoo, Kyong-Ok
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.1977-1983
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    • 2000
  • SCR(selective catalytic reduction) pilot plant for reduction of the nitrogen oxides using diesel oil as a reductant was installed at the NG(natural gas) fired combined cycle and the activity of Pt(0.3%)/Zeolite catalyst was studied in real flue gas condition according to the amount of reductant. reaction temperature and space velocity. NOx conversion gradually increased with increasing the diesel oil concentration up to C/N ratio 5.5(C/N ratio: the ratio of the number of carbon atom to the number of NOx molecules included in the flue gas). Increasing the reaction temperature. NOx conversion increased and reached a maximum conversion of 50% at $190^{\circ}C$. NOx conversion did not changed with increasing the space velocity up to 18,500/hr and then gradually decreased. These results reveal the potential for diesel oil as a reductant for de-NOx SCR process.

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Trend of Nitrogen Oxide Reduction Technologies in Cement Industry (시멘트 산업에서의 질소산화물 저감 기술 동향)

  • Seo, JunHyung;Kim, YoungJin;Cho, KyeHong;Cho, JinSang;Han, KyungHo;Yoon, DoYoung
    • Resources Recycling
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    • v.29 no.6
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    • pp.114-124
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    • 2020
  • In the cement industry, NOx emission is recognized as an important problem, and NOx reduction technologies can be divided into process change, staged combustion, low NOx burner, selective non-catalytic reduction and selective catalytic reduction method. The operation of the selective non-catalytic reduction method, which is the most used in the cement industry, is expected to make it difficult to meet the emission standards to be strengthened in the future, and it is necessary to improve equipment such as SCR and secure technologies. Recently, we are developing technologies for simultaneous application of SNCR and SCR, dust and denitrification filter technology, and removal technology using NO oxidation.

A development of reactor design software for De-NOx system using the selective catalytic reduction method (선택적 촉매 환원법을 이용한 De-NOx 시스템의 반응로 설계 전산프로그램 개발)

  • 정경열;오상훈;동은석;이수태;류길수
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.187-191
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    • 2002
  • The exhaust gas from electric power stations, incinerators and industrial boilers contains considerable amount of harmful nitric oxide which causes air pollution. Selective catalytic reduction system with ammonia as a reductant(NH$_{3}$ SCR) have been applied to remove NOx since 1970. it is widely accepted that the NH$_{3}$ SCR process is the best method for the removal of NOx. In this paper the design of SCR reactor based on the NOx displacement is considered and the design program of SCR reactor is developed. The newly developed design program for de-NOx system maybe used in practice.

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Computational Fluid Dynamics(CFD) Simulation and in situ Experimental Validation for the Urea-Based Selective Non-Catalytic Reduction(SNCR) Process in a Municipal Incinerator (생활폐기물 소각장 2차 연소로에서 요소용액을 이용한 선택적무촉매환원 공정에 대한 전산유체역학 모사 및 현장 검증)

  • Kang, Tae-Ho;Nguyen, Thanh D.B.;Lim, Young-Il;Kim, Seong-Joon;Eom, Won-Hyeon;Yoo, Kyung-Seun
    • Korean Chemical Engineering Research
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    • v.47 no.5
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    • pp.630-638
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    • 2009
  • A computational fluid dynamics(CFD) model is developed and validated with on-site experiments for a urea-based SNCR(selective non-catalytic reduction) process to reduce the nitrogen oxides($NO_x$) in a municipal incinerator. The three-dimensional turbulent reacting flow CFD model having a seven global reaction mechanism under the condition of low CO concentration and 12% excess air and droplet evaporation is used for fluid dynamics simulation of the SNCR process installed in the incinerator. In this SNCR process, urea solution and atomizing air were injected into the secondary combustor, using one front nozzle and two side nozzles. The exit temperature($980^{\circ}C$) of simulation has the same value as in situ experiment one. The $NO_x$ reduction efficiencies of 57% and 59% are obtained from the experiment and CFD simulation, respectively at NSR=1.8(normalized stoichiometric ratio) for the equal flow rate ratio from the three nozzles. It is observed in the CFD simulations with varying the flowrate ratio of the three nozzles that the injection of a two times larger front nozzle flowrate than the side nozzle flowrate produces 8% higher $NO_x$ reduction efficiency than the injection of the equal ratio flowrate in each nozzle.

A Study on NOx Removal Efficiency using SNCR Process in the Industrial Waste Incineration Plant (산업폐기물 소각로에서 SNCR공정에 의한 NOx 제거효율에 관한 연구)

  • Ryu Hae-Yeol;Kim Min-Choul;Jung Jong-Hyeon;Lee Gang-Woo;Chung Jin-Do
    • Journal of Environmental Health Sciences
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    • v.31 no.4 s.85
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    • pp.332-339
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    • 2005
  • The environmental regulations in the world has been reinforced and many nations has devoted themselves to the development of cost-effective technology. Selective catalyst reduction(SCR) and selective non-catalyst reduction (SNCR) processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. One of these typical technologies for reduction of do-NOx is SNCR process has increased continuously because of the low cost for building and maintenance. Nevertheless the researches on the application to real scale plant by the reductant like Urea are rarely studied. In this paper, an experimental investigations were performed on the SNCR process in the industrial waste incineration plant. With no reducing agent, the concentration of NOx stayed in around 180 ppm $(O_2\;12\%)$ with the exhausting temperature of $950^{\circ}C$ and changed within the range of 20 ppm to remain relatively consistent. When $10\;wt\%)$ of a solution was added, the efficiency of denitrification reached above $61.4\%$ with the NSR of 2.0 and the exhausting temperature of $950^{\circ}C.$ When the concentration of the urea solution was set to $10\;wt\%$ and the sprinkling to four nozzles, the reaction temperature was reduced to about $50~100^{\circ}C$ with a mixture of $10\;wt\%\;CH_3OH\;and\;5wt\%\;Na_2CO_3$ in $40\;wt\%$ of the solution. The NOx removal efficiency increased to $78.4\%,$ achieving a broader and expansive range of reaction temperatures than the addition of an unmixed pure solution.

Experience of Decision Making about Selective Fetal Reduction among Women Who Conceived through Assisted Reproductive Techniques (보조생식술을 받은 여성의 선택적 태아감소술에 대한 의사결정 경험)

  • Jang, HyeYoung;Chung, ChaeWeon
    • Journal of Korean Clinical Nursing Research
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    • v.24 no.1
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    • pp.44-55
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    • 2018
  • Purpose: This study aimed to explore and understand the experience of decision making among women undergoing or forgoing selective fetal reduction who have higher-order multiple pregnancies through assisted reproductive techniques. Methods: A qualitative study was conducted from August 1, to October 30, 2013. Eight participants were interviewed and the interviews were audio-recorded and transcribed verbatim. Six persons participated in in-depth interviews in person and two participated over the telephone. A thematic analysis was conducted. Results: Four themes were identified and carefully named: Confusion after higher-order multiple pregnancy; Obstacles to choice: Uncertain safety; Weighing between reality and ideality and; Influences of medical professionals. Conclusion: The results demonstrated a wide range of factors considered by women when making decisions about selective fetal reduction, and mothers' feelings of conflict and distress in the decision-making process. The results suggest that it is important for nurses to provide emotional support and consolation, in addition to sufficient information. These findings will help nurses improve their counseling techniques by understanding the situation of infertile couples.