• Applied Chemistry for Engineering
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• v.19 no.1
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• pp.17-26
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• 2008

With the effectuation of Kyoto Protocol on the United Nations Framework Convention on the Climate Change, the emission reduction of greenhouse gases became an urgent issue and has been competitively secured among countries as the form of certificates through clean development mechanism (CDM) or joint implementation (JI). Nitrous oxide ($N_2O$) is one of the major greenhouse gases along with carbon dioxide ($CO_2$) and methane ($CH_4$) having warming potential 310 times that of carbon dioxide and chemically very stable in the atmosphere to give a life time of more than 120 years so that it reaches to the stratosphere to act as an ozone depleting substance. $N_2O$ hardly decomposes and thus, besides to the adoption of thermal decomposition at high temperature, selective catalytic reduction methods are usually used at temperatures over $400^{\circ}C$ in which the presence of NOx acts as a major impeding material in the decomposition process. In this article, the sources of various $N_2O$ generation, catalytic reduction processes and the status and trends of emission trade with CDM projects for greenhouse gas reduction are summarized and discussed on a condensed basis.

• Applied Chemistry for Engineering
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• v.31 no.2
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• pp.200-207
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• 2020

In this study, the effect of calcination temperature on the production of RuTi catalyst in NH₃-SCO (selective catalytic oxidation) was investigated. The RuTi catalyst was prepared using the wet impregnation method, and calcined at 400~600 ℃ for 4 h in air condition. The catalysts were named RuTi x00 where x00 means the calcination temperature. According to XRD (X-Ray diffraction), TEM (transmission electron microscope), H₂-TPR (H₂-temperature programmed reduction) analyses, RuTi x00 catalysts displayed that the dispersion of active metal decreased via increasing the calcination temperature. The catalysts with low dispersion showed a decrease in the surface adsorption oxygen species (O_β) and NH₃ adsorption amount via XPS, and NH₃-TPD analyses. Therefore, the RuTi 400 catalyst was well dispersed in the active metal on TiO₂ surface, and also, the NH₃ removal efficiency was excellent.

• Bulletin of the Korean Chemical Society
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• v.33 no.5
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• pp.1643-1646
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• 2012

Three Ni-based catalysts with different clay as support were prepared and tested in the hydrogenation of maleic anhydride, among which Ni/clay1 showed best activity and selectivity. Over Ni/clay1 catalyst prepared by impregnation method, 97.14% conversion of maleic anhydride and 99.55% selectivity to succinic anhydride were obtained at $180^{\circ}C$ under a pressure of 1 MPa. Catalytic activity was greatly influenced by the temperature and weighted hourly space velocity. Catalyst deactivation studies showed that this catalyst have a long life time, the yield of MA still higher than 90% even after a reaction time of 60 h. X-ray diffraction (XRD) and $H_2$ temperature programmed reduction (TPR) were use to investigate the properties of the catalyst. XRD and TPR studies showed that Ni was present as $Ni^{2+}$ on the support, which indicated that there was no elemental nickel ($Ni^0$) and $Ni_2O_3$ in the unreduced samples. The formation of Ni was strong impact on catalytic activity.

• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.79-85
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• 2006

In this study, to increase the mixing between flue gas and reducing agent, new shapes of $NH_3$ ejection nozzles are designed and experimentally and numerically tested. The nozzles have six holes perpendicular to the ambient flue gas flow and the tilting angle between direction of ambient flow and the hole axis is varied. To evaluate the mixing efficiency of the proposed nozzles, numerical and experimental tests are applied to several flow conditions comparing with single hole nozzle, which is commonly used in conventional SCR process. From the results the nozzle with tilted multi-holes has the large region of high turbulent intensity compared with conventional single hole nozzle. This is originated from the high vorticity near the upstream of the jet flow issuing from the hole. The high turbulent intensity and vorticity magnitude lead to enhanced mixing between flue gas and reducing agent. Hence, the most suitable moral ratio between NOx and reducing agent for the catalytic reaction can be obtained on behalf of the intensified scalar mixing within shorter physical mixing length.

• Clean Technology
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• v.26 no.2
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• pp.145-150
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• 2020

Nitrous oxide (N₂O) is one of the six greenhouse gases, and it is essential to reduce N₂O by showing a global warming potential (GWP) equivalent to 310 times that of carbon dioxide (CO₂). Selective catalytic reduction (SCR) is a technology that converts ammonia into harmless N₂ and H₂O by using ammonia as a reducing agent to remove NOx, one of the air pollutants; the process also produces high denitrification efficiency. In this study, the Fe-BEA catalyst was steam-treated at 100 ℃ for 2 h before Fe ion exchange in the fixed bed reactor in order to investigate the effect of the steam-treated Fe-BEA catalyst on the NH₃-SCR reaction. NH₃-SCR reaction test of synthesized catalysts was performed at WHSV = 180 h^-1, 370 to 400 ℃ in the fixed bed reactor. The Fe-BEA(100) catalyst steam-treated at 100 ℃ showed a somewhat higher activity than the Fe-BEA catalyst at 370 to 390 ℃. The catalysts were characterized by BET, ICP, NH₃-TPD, H₂-TPR, and ²⁷Al MAS NMR in order to determine the cause affecting NH₃-SCR activity. The H₂-TPR result confirmed that the Fe-BEA(100) catalyst had a higher reduction of isolated Fe³⁺ than the Fe-BEA catalyst, and that the steam treatment increased the amount of isolated Fe³⁺ as an active species, thus increasing the activity.

• Journal of Environmental Science International
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• v.22 no.11
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• pp.1481-1498
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• 2013

The SCR (selective catalytic reduction) system is highly-effective technique for NOx reduction from exhaust gases. In this study, the effects of the direction and size of nozzle and the ammonia injection concentration on the performance of SCR system are analyzed by using the computational fluid dynamics method. When the nozzle is arranged in zigzaged direction which is normal to exhausted gas flow, it is shown that the uniformity of gas flow and the NH3/NO molar ratio is improved remarkably. With the change of the ammonia injection concentration from 0.2 vol%(wet) to 1.0 vol%(wet), the uniformity of gas flow shows a good results. As the size of nozzle diameter changes from 6 mm to 12 mm, the uniformity of gas flow is maintained well. It is shown that the uniformity of the $NH_3/NO$ molar ratio becomes better with decreasing the ammonia injection concentration and the size of nozzle diameter.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.22 no.2
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• pp.451-457
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• 1998

This paper describes a modelling method for SCR(selective catalystic reduction) system in refuse incineration plant. We consider the SCR system as a single input and single output system. For modelling the SCR system, an auto regressive exogeneous(ARX) modelling method is used. In this case, we should design the white noise input for modelling and put it on the system as an input$(NH_3)$, and take an outlet NOx as an output. From these two relations, we design the ARX model with 45 second delay time and transform to a discrete system with sampling time of 0.5 second. Using the obtained SCR model, we verify that the outlet NOx is deeply related with stoker`s moving in boiler of refuse incineration plant.

• Journal of Institute of Convergence Technology
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• v.7 no.1
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• pp.15-18
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• 2017

As emission gas regulation of deisel vehicles is strengthened to Euro-6, It becomes difficult to deal with NOx regulated value mainly by EGR without additional after-treatment system. In addition, RDE(Real Driving Emissions) test will be introduced after september 2017. Therefore, It is essential to develop the after-treatment of diesel vehicles which reduce NOx emissions. It is possible to use DOC, DPF, LNT or DOC, DPF and SCR as a after-treatment system for reducing NOx. However, It is expected that the SCR will be applied widely because LNT alone does not have sufficient NOx purification efficiency. In this study, It tried to analyze the efficiency of reducing NOx emissions during the mode test by attaching a NOx sensor to test vehicle. As a result, It was confirmed that NOx emissions was significantly reduce through the after-treatment system from engine. And the NOx reduction efficiency of SCR was about 4.5 times better than DOC, DPF.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.18 no.8
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• pp.816-822
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• 2008

This study presents the design modification for SCR muffler of a commercial vehicle. Its main objective is the reduction of radiated noise at SCR muffler. For this study, the research of five steps were achieved by experimental and CAE analysis. First step is the measurement of radiated noise using impact-acoustic test. Second step is the source identification using experimental modal analysis. The cause of radiated noise source is confirmed by the resonance of end plates at SCR muffler. Third step confirms the possibility of resonance avoidance using SDM analysis applied the mass control. Fourth step is the suggestion of design modification which is the change of mode shape by CAE analysis. Last step is the verification of design modification using SYSNOISE analysis. Finally, the prototype product applied the countermeasure of resonance evasion was manufactured and the reduction of radiated noise at SCR muffler was confirmed by pass-by noise test.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.06a
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• pp.521-527
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• 2005

The effects of an urae injection at the exhaust pipe for a 4-cylinder DI(Direct Injection) diesel engine are investigated experimentally. The urea quantity was controlled by NOx quantity and MAF(Manifold Air Flow). The urea injection must be precisely metered and then I used the urea syringe pump. I have tested 4 kinds of items that were with the EGR base engine and without the EGR engine. Then I tested each urea-SCR(Selective Catalytic Reduction) system. As the results, I can caculate the SUF(Stoichiometric Urea Flow) and visualize the NOx results by variation of engine speed and engine load. Also, I can make the NOx map. Therfore, I knew that NOx reduction effects of the urea-SCR system without the EGR engine were better than the with EGR base engine except of low load and low speed.