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A Study on Characterization for Low Temperature SCR Reaction by $Mn/TiO_2$ Catalysts with Using a Various Commercial $TiO_2$ Support (다양한 상용 $TiO_2$ 담체를 이용한 $Mn/TiO_2$ 촉매의 저온 SCR 반응 특성 연구)

  • Kwon, Dong Wook;Choi, Hyun Jin;Park, Kwang Hee;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.190-194
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    • 2012
  • 10 wt% Mn supported on various commercial $TiO_2$ catalysts were prepared by wet-impregnation method for the low temperature selective catalytic reduction (SCR) of NO with $NH_3$. A combination of various physico-chemical techniques such as BET, XRD, XPS and TPR were used to characterize these catalysts. MnOx surface densities on MnOx/$TiO_2$ catalyst were related to surface area. As MnOx surface density lowered with high dispersion, the SCR activity for low temperature was increased and the reduction temperature ($MnO_2$ ${\rightarrow}$ $Mn_2O_3$) of surface MnOx was lower. For a high SCR, MnOx could be supported on a high surface area of $TiO_2$ and should be existed a high dispersion of non-crystalline species.

A Study on the Reversible SCR Servo Amplifier (정역전이 가능한 SCR 서보증폭기에 관한 연구)

  • Ahn, B. W.;Park, S. K.
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.31 no.2
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    • pp.190-198
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    • 1995
  • Many industrial servo amplifiers employ power transister as output device. Thyristor converters are not adopted to drive servo motor, although thyristor is superior to power TR in power rating, noise immunity, price, and size. The reason is, thyristor has no ability of self turn - off. Here in this paper line commutation, in which thyristor is turned off naturally since cathode voltage is higher than anode as time goes by, is employed to turn on thyristor with a delicate sequence. We developed thyristor servo amplifier which does not cause any damage on thyristor because it is designed to prevent triggering the two SCRs in the same arm simultaneously. And it was made clearly how to trigger SCR without any power line shorting and also harmonic analysis is carried out with the aid of FFT analyzer and proved that it can be used even severe reactive load. The designed circuit operated as a good DC amplifier in conventinal servomotor and the results can be use as a position control system application.

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A Convergence Study on the Effects of NH3/NOx Ratio and Catalyst Type on the NOx Reduction by Urea-SCR System of Diesel Engine (디젤엔진의 Urea-SCR 시스템에 의한 NH3/NOx 비율 및 촉매 방식이 NOx 저감에 미치는 영향에 관한 융합연구)

  • Yoon, Heung-Soo;Ryu, Yeon-Seung
    • Journal of the Korea Convergence Society
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    • v.10 no.4
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    • pp.131-138
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    • 2019
  • Diesel engines have important advantages over its gasoline counterpart including high thermal efficiency, high fuel economy and low emissions of CO, HC and $CO_2$. However, NOx reducing is more difficult on diesel engines because of the high $O_2$ concentration in the exhaust, marking general three way catalytic converter ineffective. Two method available technologies for continuous NOx reduction onboard diesel engines are Urea-SCR and LNT. The implementation of the Urea-SCR systems in design engines have made it possible for 2.5l and over engines to meet the tightened NOx emission standard of Euro-6. In this study, we investigate the characteristics of NOx reduction with respect to engine speed, load, types of catalyst and the $NH_3$/NOx ratio and present the conditions which maximize NOx reduction. Also we provide detailed experimental data on Urea-SCR which can be used for the preparation for standards beyond Euro-6.

Experimental Study on Mixing Efficiency of Exhaust Gas and Reductant According to SCR Mixer Shape (SCR 믹서형상에 따른 배기가스와 환원제 혼합 효율에 관한 실험적 연구)

  • Choe, Munseok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.74-79
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    • 2021
  • This study examined the mixing efficiency of exhaust gas and urea according to the mixer shape in the SCR system. For the experiment, an SCR simulation system was manufactured, and a uniformity detector was attached to the catalyst location to measure the uniformity. The experiment was conducted by setting the exhaust-gas flow rate, temperature, mixer type, and catalyst distance as variables. The experimental results confirmed the swirl angle analysis, urea number distribution, and uniformity. The swirl angle experiment of Models A and B confirmed that the swirl angle of Model A was formed approximately 7 to 8 degrees higher over the entire RPM range. When there was no mixer in the SCR system, the urea and water were concentrated to one side. Mixer Model A showed an even distribution overall, and Model B showed a slightly concentrated tendency at the beginning but then showed a stable distribution of urea. The mixing efficiency of 90%, which was the uniformity target, could be satisfied in Model A and Model B. In particular, Model A showed excellent results that satisfied 90% efficiency at 10 cm of the catalyst position.

Ammonia flow control for NOx reduction in SCR system of refuse incineration plant (소각로의 NOx 제어용 SCR 시스템의 암모니아 공급량제어)

  • Kim, In-Gyu;Yeo, Tae-Gyeong;Kim, Hwan-Seong;Kim, Sang-Bong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.2
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    • pp.451-457
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    • 1998
  • This paper describes a modelling method for SCR(selective catalystic reduction) system in refuse incineration plant. We consider the SCR system as a single input and single output system. For modelling the SCR system, an auto regressive exogeneous(ARX) modelling method is used. In this case, we should design the white noise input for modelling and put it on the system as an input$(NH_3)$, and take an outlet NOx as an output. From these two relations, we design the ARX model with 45 second delay time and transform to a discrete system with sampling time of 0.5 second. Using the obtained SCR model, we verify that the outlet NOx is deeply related with stoker`s moving in boiler of refuse incineration plant.

Local dynamic buckling of FPSO steel catenary riser by coupled time-domain simulations

  • Eom, T.S.;Kim, M.H.;Bae, Y.H.;Cifuentes, C.
    • Ocean Systems Engineering
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    • v.4 no.3
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    • pp.215-241
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    • 2014
  • Steel catenary riser (SCR) is a popular/economical solution for the oil/gas production in deep and ultra-deep water. The behavioral characteristics of SCR have a high correlation with the motion of floating production facility at its survival and operational environments. When large motions of surface floaters occur, such as FPSO in 100-yr storm case, they can cause unacceptable negative tension on SCR near TDZ (touch down zone) and the corresponding elastic deflection can be large due to local dynamic buckling. The generation, propagation, and decay of the elastic wave are also affected by SCR and seabed soil interaction effects. The temporary local dynamic buckling vanishes with the recovery of tension on SCR with the upheaval motion of surface floater. Unlike larger-scale, an-order-of-magnitude longer period global buckling driven by heat and pressure variations in subsea pipelines, the sub-critical local dynamic buckling of SCR is motion-driven and short cycled, which, however, can lead to permanent structural damage when the resulting stress is greatly amplified beyond the elastic limit. The phenomenon is extensively investigated in this paper by using the vessel-mooring-riser coupled dynamic analysis program. It is found that the moment of large downward heave motion at the farthest-horizontal-offset position is the most dangerous for the local dynamic buckling.

Diesel SCR Development to Meet US Tier2 Bin5 Emission Regulation (북미 Tier2 Bin5 규제 대응을 위한 디젤 SCR 개발)

  • Lee, Kang-Won;Kang, Jung-Whun;Jo, Chung-Hoon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.2
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    • pp.98-104
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    • 2011
  • The introduction of a diesel engine into the passenger car and light duty applications in the United States involves significant technical challenges for the automotive makers. This paper describes the SCR System optimization procedure for such a diesel engine application to meet Tier2 Bin5 emission regulation. A urea SCR system, a representative $NO_x$ reduction after-treatment technique, is applied to a 3.0 liter diesel engine. To achieve the maximum $NO_x$ reduction performance, the exhaust system layout was optimized using series of the computational fluid dynamics and the urea distribution uniformity test. Furthermore a comprehensive simulation model for the key factors influencing $NO_x$ reduction performance was developed and embedded in the Simulink/Matlab environment. This model was then applied to the urea SCR system and played a key role to shorten the time needed for SCR control parameter calibration. The potential of a urea SCR system for reducing diesel $NO_x$ emission is shown for FTP75 and US06 emission standard test cycle.

The transient analysis for choosing the optimal SCR ratings of AC3 utilization category testing equipment used for electrical durability test for magnetic switch (IEC60947-4에 따른 전자개폐기 전기적 수명시험설비의 과도현상을 고려한 SCR최적 정격선정에 대한 연구)

  • Ryu Haeng Soo;Kim Kab Dong;Han Gyu Hwan
    • Proceedings of the KIEE Conference
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    • summer
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    • pp.354-356
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    • 2004
  • This paper is the transient analysis for choosing the optimal SCR ratings of AC3 utilization category testing equipment(AC3 TE) used for electrical durability test for magnetic switch according to IEC60947-4 Annex B by utilizing EMTP -ATPDraw. Magnetic contactor closes and opens the motor load with ON/OFF switch of electronic contactor. It is also used for protecting and controlling the load. Magnetic contactor detects the over-current flow in the load with a over-current relay and disconnects the load by opening its control power. The key cost of AC3 TE is the SCR ratings. The more decreases SCR ratings, the more decreased the cost is, but it is impossible to ensure the reliability. On the other hand, the more increases SCR ratings, the more increased the cost is. Thereupon, in this paper after the testing circuit is simulated by using EMTP-ATPDraw the SCR ratings will be applied in order to guarantee the testing reliability of PT&T(Power Testing and Technology institute in LG Industrial Systems Co.,Ltd.).

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A Study on SCR-Based ESD Protection Circuit with PMOS (PMOS가 삽입된 SCR 기반의 ESD 보호 회로에 관한 연구)

  • Kwak, Jae-Chang
    • Journal of IKEEE
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    • v.23 no.4
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    • pp.1309-1313
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    • 2019
  • In this paper, the electrical characteristics of Gate grounded NMOS(GGNMOS), Lateral insulated gate bipolar transistor(LIGBT), Silicon Controlled Rectifier(SCR), and Proposed ESD protection device were compared and analyzed. First, the trigger voltage and holding voltage were verified by simulating the I-V characteristic curve for each device. After that, the robustness was confirmed by HBM 4k simulation for each device. As a result of HBM 4k simulation, the maximum temperature of the proposed ESD protection device is lower than that of GGNMOS and GGLIGBT and SCR, which means that the robustness is improved, which means that the ESD protection device is excellent in terms of reliability.

Investigation of NOx Reduction Ratio on SCR System for a Marine Diesel Engine (선박디젤기관용 SCR 시스템의 NOx 저감율에 관한 연구)

  • 최재성;조권회;이재현;이진욱;김정곤;양희성;고준호;박기용;장성환
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.7
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    • pp.832-838
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    • 2003
  • IMO NOx levels are generally possible to meet by means of primary on-engine measures. Nevertheless further significant follow-on reductions are likely to require a secondary after-treatment technique. SCR system is currently the only available technology proven at full scale to meet the 90% NOx reduction levels. Accordingly, maybe the use of an SCR system on board ship provides the solution to minimize this primary pollutant without increasing fuel consumption. In order to develop a practical SCR system for marine application on board ship, a primary SCR system using urea was made. The SCR system was set up on the ship. employed a two-stroke diesel engine as a main propulsion. which is a training ship in KMU (Korea Maritime Univ.). The purpose of this paper is to report the results about the basic effects of the above system parameters which is investigated from practical application through its trial use. The degree of NOx removal depends on some parameters. such as the amount of urea solution added, space velocity. reaction gas temperature and activity of catalyst. The preliminary results from trial run are presented.