• 제목/요약/키워드: Sampling Tube

검색결과 140건 처리시간 0.02초

산적 액체 화물 작업중 배출되는 VOCs 분석방법 및 오염 측정 연구 (A study on the Analysis Method and Pollution Measure of existed VOCs during the Bulk Liquid Cargo Operation at Vessels)

  • 정광현;이인호
    • 해양환경안전학회:학술대회논문집
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    • 해양환경안전학회 2007년도 춘계학술발표회
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    • pp.21-26
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    • 2007
  • [ ${\ulcorner}$ ]1978년 의정서 및 1997년 의정서에 의하여 개정된 선박으로부터의 오염방지를 위한 1973년 국제협약${\lrcorner}$의 부속서 VI ${\ulcorner}$선박으로부터의 대기오염방지를 위한 규칙${\lrcorner}$이 발효 (2005.5.19) 함에 따라 동 내용의 수용을 위한 개정 (2005.12.29, 공포, 2006. 6.29. 시행)이 되었음에도 유중기배출제어장치의 설치가 되어있지 않았거나 설치되어 있어도 사용하지 않는 유류 터미널이 대부분이다. 본 연구의 목적은 다양하고 체계화되지 않은 VOCs 의 시료채취 및 분석방법을 고찰하고 산적 액체 위험물작업중에 배출되는 VOCs의 현 실태를 파악하여 VOCs 에 대한 보다 체계화된 접근을 시도해보고자 하였다. VOCs 에 대한 시료채취방법 중 Tedlar bag 은 화학반응 및 흡착현상에 의한 농도감소현상이, 용매추출을 이용한 방법은 추출시의 실험오차요인이, 흡착관은 흡착시 파과에 의한 오차요인이 분석의 신뢰도를 떨어뜨리는 원인으로 작용하고 있으며 Canister를 이용한 방법은 상기 방법의 단점을 보완한 가장 안정한 방법으로 파악된다. 선박에서 산적 액체 화물 작업중 배출된 유해성대기오염물질의 분석자료와 오염물질에 관한 VOCs 배출 연구분석자료는 충분하지 않다. 그러므로, 향후 선박 작업중에 배출되는 VOCs 관리에 대한 지속적인 Monitoring이 필요하다고 사료되며 선원들의 건강상 안전을 위해서라도 이 분야에 대한 연구가 활발히 진행되었으면 한다.

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ACF 흡착관 개발을 위한 파괴특성에 관한 연구 (A study on breakthrough characteristics of activated carbon fiber by development of sorbent tube)

  • 원정일;김기환
    • 환경위생공학
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    • 제20권1호
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    • pp.40-54
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    • 2005
  • This dissertation aims to develop adsorption tubes for measuring organic solvents in the working environment, by comparing and analyzing breakthrough condition and adsorption capacity with ACF. 1. In breakthrough characteristics, the raising velocity of breakthrough curve is increasing according to assault concentration, but $50\%$ breakthrough time is decreasing. As breakthrough curve of calculated data using this agrees with the one of experimental data both of them can be used on determining sampling time of adsorption tubes. It is predicted by theoretical that $10\%$ breakthrough time is increasing in the case of increasing filled adsorbent amount. 2. $10\%$ breakthrough time is regularly decreasing as much as assault concentration is increasing. As a result, we can predict the life of adsorbent within the range of the low concentration, and adsorption amount that ACF can sample during $10\%$ breakthrough time is increasing as much as assault concentration is increasing.

A Comparison of Nicotine Diffusive Sampler and XAD-4 Tube for Determination of Nicotine in ETS

  • Kim, Hyo-Cherl;Paik, Nam-Won;Kim, Kyoung-Ran;Kim, Kyoung-Su;Lee, Kyoung-Suk;Cho, Kyung-Ah
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2005년도 국제학술대회
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    • pp.371-372
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    • 2005
  • Active sampler has been widely used to measure nicotine concentration in air. The experiments were conducted to compare the active sampler method with diffusive sampler in exposure chamber and smoking areas, respectively. The result of these tests that indicated that passive sampler can be used instead of active sampler in ETS, because coefficient of determination was 0.9292 between active and passive sampling in smoking area

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청각장애아동과 건청아동의 성도면적 추정 성능 (Performance of Vocal Tract Area Estimation from Deaf and Normal Children's Speech)

  • 김세환;김남;권오욱
    • 대한음성학회지:말소리
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    • 제56호
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    • pp.159-172
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    • 2005
  • This paper analyzes the vocal tract area estimation algorithm used as a part of a speech analysis program to help deaf children correct their pronunciations by comparing their vocal tract shape with normal children's. Assuming that a vocal tract is a concatenation of cylinder tubes with a different cross section, we compute the relative vocal tract area of each tube using the reflection coefficients obtained from linear predictive coding. Then, we obtain the absolute vocal tract area by computing the height of lip opening with a formula modified for children's speech. Using the speech data for five Korean vowels (/a/, /e/, /i/, /o/, and /u/), we investigate the effects of the sampling frequency, frame size, and model order on the estimated vocal tract shape. We compare the vocal tract shapes obtained from deaf and normal children's speech.

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고속분사를 이용한 소형 축열식 복사관 버너시스템의 성능평가 (Performance Estimation of Small Regenerative Radiant Tube Burner System using High Velocity Discharge)

  • 조한창;조길원;이용국
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.242-247
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    • 2004
  • An Experimental study was conducted on spray combustion using dual swirlers at different outlet angle; co-swirl and counter-swirl. To understand the characteristics of turbulent spray combustion of dual swirl flow (DSF), the axial helical annular vaned swirlers with various swirl ratios and combination of angle and direction were designed. and temperature measurements of a rapidly thermocouple insertion and measurements of soot volume fraction and microrstructure using thermophoretic sampling particle diagnostic (TSPD) as TEM were carried out. The NOx, $CO_2$, $O_2$, etc. was analyzed using emission gas analyzer. The results show that flame stability were maintained under very lean condition. for both co-swirl and counter-swirl case. And though Counter-swirl case kept the higher temperature region compared to co-swirl case, Counter-swirl combustion represented less NOx emission and soot formation than co-swirl case.

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First record of the Cleantioides rotundata (Malacostraca: Isopoda: Holognathidae) from South Korea

  • Song, Ji-Hun;Min, Gi-Sik
    • Journal of Species Research
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    • 제5권3호
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    • pp.309-312
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    • 2016
  • Cleantioides rotundata (Kussakin, 1982) is reported for the first time in South Korea. Specimens of C. rotundata were collected with a small hand net from the intertidal zone of Opo-ri, Yeongdeok-gun in South Korea. This species makes tubes using seagrass debris at our sampling location and distinguished by the following characteristics: pleotelson long, length almost 1.6 times as long as width; dorsum of distal one third with deeply bilobed depression on plane. In this paper, we provide descriptions of diagnostic characteristics and illustrations of morphology of C. rotundata. Additionally, a key to the Korean species of the genus Cleantioides is provided and the partial sequences of the mitochondrial cytochrome c oxidase subunit 1 (CO1) are provided as molecular characteristics.

Determination of Methyl Bromide Used for the Preservation of Cultural Materials from Insects

  • Lee, Gil-Seung;Shin, Ueon-Sang;Shin, Ho-Sang
    • 한국환경보건학회지
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    • 제28권4호
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    • pp.27-30
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    • 2002
  • A thermal desorption-gas chromatography/mass spectrometric method was developed for the determination of methyl bromide in fumes formed during preservation of cultural materials from insects. Methyl bromide in lunes was collected by drawing 10ι of air through the adsorbent tube filled with a solid adsorbent (Chromosorb). The air samples were analyzed by using a special thermal desorption device and GC/MS determination. The recovery of methyl bromide by air sampling was 88% and the detection limit of the assay was 0.1 pptv based upon assayed air of 10ι. The method was applied to the determination of fumed methyl bromide used for the preservation of papers in a library. The mean concentration of methyl bromide determined in a library was 280.2 $\pm$ 25.4 pptv.

공기 중 휘발성 유기화합물의 측정을 위한 열탈착-분석시스템의 구성 및 평가 (Composition and Evaluation of the Thermal Desorption-Gas Chromatographic System for the Measurement of Volatile Organic Compounds in Air)

  • 이수형;송희남;김희갑
    • Environmental Analysis Health and Toxicology
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    • 제17권1호
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    • pp.63-71
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    • 2002
  • The thermal desorption-gas chromatographic (TD-GC) system has been constructed for the measurement of volatile organic compounds. The thermal desortion unit is composed of four major parts: 1) the control part; 2) the thermal desorption part; 3) the focusing part; and 4) the injection part. The peltier element was introduced to the focusing part for the temperature of the focusing tube to reach-35$^{\circ}C$. The system was tested for the linearity of the calibration curves and reproducibility of instrumental analyses using some disinfection by-products (DBPs) and BTXs (benzene, toluene and p-xylene). The coefficients of determination (r$^2$) for all the calibration curves made were higher than 0.998, and the coefficients of variation (CV) for triplicate measurements were all within 10%. The system also has been tested for field applicability. The analysis of field samples showed that there was no breakthrough problem in the sampling system and that the system could be applied to field measurements.

확산포집-이온크로마토그래프법을 이용한 대기중 SOx의 자동정량 (Automated Determination of SOx in Air by Diffusion Scrubber-lon Chromatography)

  • 이용근;이동수;백선영
    • 한국대기환경학회지
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    • 제11권4호
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    • pp.307-313
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    • 1995
  • An automatic method is developed for the determination of SOx in atmosphere. The method involves SOx sampling in diffusion scrubber followed by ion chromatographic analysis. Filtered air is withdrawn at 1.8.ell./min through a diffusion scrubber of which inner tube is made of PTFE(Gore-tex) membrane tubing. 1mM $H_{2}$ $O_{2}$ is used as absorbing solution so that SOx is oxidized to S $O_{4}$$^{2-}$. The scrubbered solution is automatically injected into ion chromatograhpy eith conductivity detection for sulphate determination. Replacement of commonly used polyproplene membrane with PTFE gives several merits such as easy preparation of diffusion scrubber, better collection efficiency. No measurable memory effect is experienced, and this isin contrast to previous work for ammonia. Detection limit of this method defined by three times standard deviation is 0.56ppbv. The precision is 0.4% RSD at SOx concentration of 7.3ppbv Results for Seoulatmosphere ate presented.

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청각장애아 및 건청아 음성으로부터 성도 면적 추정 (Vocal Tract Area Estimation from Deaf and Normal Children's Speech)

  • 김세환;권오욱
    • 대한음성학회:학술대회논문집
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    • 대한음성학회 2005년도 추계 학술대회 발표논문집
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    • pp.51-54
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    • 2005
  • This paper analyzes the vocal tract area estimation algorithm used as a part of a speech analysis program to help deaf children correct their pronunciations by comparing their vocal tract shape with normal children's. Assuming that a vocal tract is a concatenation of cylinder tubes with a different cross section, we compute the relative vocal tract area of each tube using the reflection coefficients obtained from linear predictive coding. Then, obtain the absolute vocal tract area by computing the height of lip opening with a formula modified for children's speech. Using the speech data for five Korean vowels (/a/, /e/, /i/, /o/, and /u/), we investigate the effects of the sampling frequency, frame size, and model order. We compare vocal tract shapes obtained from deaf and normal children's speech.

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