Determination of Methyl Bromide Used for the Preservation of Cultural Materials from Insects

  • Published : 2002.11.01

Abstract

A thermal desorption-gas chromatography/mass spectrometric method was developed for the determination of methyl bromide in fumes formed during preservation of cultural materials from insects. Methyl bromide in lunes was collected by drawing 10ι of air through the adsorbent tube filled with a solid adsorbent (Chromosorb). The air samples were analyzed by using a special thermal desorption device and GC/MS determination. The recovery of methyl bromide by air sampling was 88% and the detection limit of the assay was 0.1 pptv based upon assayed air of 10ι. The method was applied to the determination of fumed methyl bromide used for the preservation of papers in a library. The mean concentration of methyl bromide determined in a library was 280.2 $\pm$ 25.4 pptv.

Keywords

References

  1. Bell, C.H., Crop Protection, 19, 563-569(2000) https://doi.org/10.1016/S0261-2194(00)00073-9
  2. Hayes, W.J. Jr and Laws, E.R. Jr. : Handbook of pesticide tocicology. Vol 2, Classes of Pesticides. Academic Press, New York, 1991
  3. Gamliel, A., Grinstein, A. and Katan, J. : Improved technologies to reduce emission of methyl bromide from fimigated soil. 25(Suppl.), 21-30
  4. United Nations Environment Programme (UNEP) : Report of the methyl bromide technical options committee. UNEP, Nairobi, Kenya, 1994
  5. Khalil, M.A.K., Rasmussen, R.A. and Gunawar-dena, R.J. : Geophys. Res., 98, 2887(1993) https://doi.org/10.1029/92JD02598
  6. Singh, H.B. and Kanakidou, M. : Geophys. Res. Lett., 20, 133, 1993 https://doi.org/10.1029/92GL02634
  7. Butler, J.H. : Nature., 377, 717, 1995 https://doi.org/10.1038/377717a0
  8. Yagi, K., Williams, J. Yang, N.Y. and Cicerone. R.J. : Science, 267, 1979, 1995 https://doi.org/10.1126/science.267.5206.1979
  9. Yang,, R.S.H. Witt, K.L., Alden, C.J. and Cock-erham, L.G. : Rev. Environ. Contarn. Toxicol. 142, 65, 1995
  10. Pletsa, V., Steenwinkel, M.-J. S.T., van Delft, J.H.M., Baan, R.A. and Kyrtopoulos, S.A. : Cancer Letters., 135, 21-27, 1999 https://doi.org/10.1016/S0304-3835(98)00262-6
  11. Alge, E. Adams, N.G. and Smith, D. : J. Phys. B. 17, 3827-3833, 1984 https://doi.org/10.1088/0022-3700/17/18/019
  12. Bassford, M.R., Simonds, R.G. and Nickless, G. : Anal. Chem., 70, 958-965, 1998 https://doi.org/10.1021/ac970861z
  13. Hughes, R.A., Knighton, W.B. and Grimsrud, E.P. : J. Chromatogr. A., 852, 535-543, 1999 https://doi.org/10.1016/S0021-9673(99)00649-4
  14. Schauffler, S.M., Altas, E.L., Flocke, F., Lueb, R.A., Stroud, V. and Travnicek, W. : Geophys. Res. Lett., 25, 317-320, 1998 https://doi.org/10.1029/98GL00040
  15. Wingenter, O.W., Wang, C.J., Blake, D.R. and Rowland, F.S. : Geophys. Res. Lett., 25, 2797-2800, 1998 https://doi.org/10.1029/98GL02179
  16. Cicerone, R.J., Heidt, L.E. and Pollock, W.H. : J. Geophys. Res., 93, 3745-3749, 1998 https://doi.org/10.1029/JD093iD04p03745