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Isolation of an Unusual Aloenin-acetal from Aloe

  • Woo, Won-Sick;Shin, Kuk-Hyun;Chung, Ha-Sook;Lee, Jung-Mi;Shim, Chang-Sub
    • Korean Journal of Pharmacognosy
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    • v.25 no.4 s.99
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    • pp.307-310
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    • 1994
  • A hitherto unknown substance was isolated from the commercial sample of Aloe arborescens, which was shown to be the 4',6'-O-ethylidene-aloenin, most likely an artifact caused by hot-air drying procedure for the product preparation.

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Magnetoresistance in Hybrid Type YBCO-NiO/NiFe/Cu/NiFe Film Structure

  • Lee, S.S;Rhee, J.R;Hwang, D.G;Rhie, K
    • Journal of Magnetics
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    • v.6 no.3
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    • pp.83-85
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    • 2001
  • The magnetoresistance properties of NiO/NiFe/Cu/NiFe spin valve film deposited on MgO(100) substrate with YBa$_2$$Cu_3O_7$(YBCO) film were investigated at room temperature and at 77 K. The magnetoresistance (MR) curves of the hybrid superconductor-magnetoresistor film structure showed an exchange coupling field of 300 Oe and an inverse magnetoresistance ratio of -6.5%. The magnetization configurations of the two magnetic layers in the NiO spin valve were antiparallel due to an increment in the conduction electron flow to superconductor YBCO film. This sample showed an inverse MR ratio.

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열처리 조건에 따른 Rubrene 박막의 결정 특성 변화 연구

  • Yun, Yeong-Un;Kim, Song-Hui;Lee, Han-Ju;Kim, Tae-Dong;Lee, Gi-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.124-124
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    • 2009
  • We observed the changes of crystal structure of Rubrene (5,6,11,12-tetraphenylnaphthacene) polycrystal thin films at various in situ substrate temperature and process by scanning electron microscope(SEM), x-ray diffraction (XRD) and near-field microwave microprobe (NFMM). Amorphous rubrene thin film was initially obtained on 200 nm thick $SiO_2/Si$ substrate at 35 $^{\circ}C$ in a vacuum evaporation but in situ long time postannealing at the temperature 80 $^{\circ}C$ transformed the amorphous phase into crystalline. Four heating conditions are followed : (a) preheating (b) annealing (c) preheating, annealing (d) preheating, cooling(35 $^{\circ}C$), annealing. We have obtained the largest polycrystal disk in sample (c). But the highest crytallity and conductivity of the rubrene thin films were obtained in sample (d).

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백두산 화산군 환경과 동굴 암석의 년대측정 및 성분분석

  • 김경훈
    • Journal of the Speleological Society of Korea
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    • v.34 no.35
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    • pp.32-42
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    • 1993
  • The Paektu-san mountains are geographically situated in the Korea strait to the north of the main peninsula, coordinated between the longitudes of W(127$^{\circ}$15'~128$^{\circ}$00')and E(128$^{\circ}$15'~129$^{\circ}$00'), and between the latitudes of S(41$^{\circ}$15'~42$^{\circ}$00') and N(42$^{\circ}$10'~42$^{\circ}$40'). The volcanic group of the Paektu-san mountains can be devided into 2 main kinds of volcanos by the method investigation, The ashes are mainly made of tremolite, trachte, basalt and pumice, or, a little quartz, labradorite and volcanic glass. These sorts, ratios and forms of the rocks are respectively similar. The Haeven lake is surrounded by 19 peaks. The central volcanic cone is a secant cone in shape, with an altitude of the 1800m to 2749,2m (Chang-kun-bong), an average diameter of 10km, and a shape of an ellipse seen high from the plane. They say there were several eruptions in 1668, 1700 and 1702 A. D. The crystal structure of the rock sample collected at the cave of Mt. Paektu-san is monoclinic. The quantitative analysis of the rock samples in the cave is done by using XRF this time. The chemical compositions by XRF fundamamental parameter analysis is : SiO$_2$: 50.72Wt%, TiO = 2.422Wt%, $Al_2$O$_3$= 17.65Wt%, Fe$_2$O$_3$= 9.371Wt%, CaO = 8.711Wt%, MgO = 4.l19Wt%, MnO = 0.l15Wt%, $K_2$O = 1.369Wt%, Na$_2$O : 3.028Wt% and P$_2$O$_{5}$ = 0.365Wt%. The K-Ar age of the rock sample is also determined to be 0.16Ma. This paper describes some problems experienced in dating young volcanic rocks, and then discusses chemical compositions, X-ray fluorescence analyses and the age of the formation of a lava tunnel such as in Mt. Paektu-san.n.

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Influence of subsequent-annealing on the oxide layer of AZ91 Mg alloy prepared by plasma electrolytic oxidation (PEO 코팅 처리된 AZ91 합금의 산화층에 미치는 후-열처리의 영향)

  • Kim, Y.M.;Ko, Y.G.;Shin, D.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.429-432
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    • 2009
  • The influence of the subsequent-annealing (SA) treatment on plasma electrolytic oxidation (PEO)-treated Mg-based alloy was investigated and the dependence of the dehydration reaction on the SA temperature was also studied. For this purpose, a series of the SA treatments were carried out on the coated samples at two different temperatures, i.e. 423 and 523 K for 10 h. In contrast to the sample without SA treatment, the sample annealed at 523 K exhibited a significant difference in term of surface morphology since the MgO content in the oxide layer increased with increasing SA temperature. With increasing SA temperature, the dehydration of $Mg(OH)_2$ led to the increase in the relative amount of the MgO, which was a hard phase. From the nano-indentation results, the applied loads of the samples were seen to increase as SA temperature increased. However, the corrosion resistance of the sample annealed at 423 K was higher than that of the samples annealed at 523 K.

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Neutron irradiation impact on structural and electrical properties of polycrystalline Al2O3

  • Sunil Kumar;Sejal Shah;S. Vala;M. Abhangi;A. Chakraborty
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.402-409
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    • 2024
  • High energy neutron irradiations impact on structural and electrical properties of alumina are studied with particular emphasis on real time in-situ radiation induced conductivity measurement in low flux region. Polycrystalline Al2O3 samples are subjected to high energy neutrons produced from D-T neutron generator and Am-Be neutron source. 14 MeV neutrons from D-T generator are chosen to study the role of fast neutron irradiation in the structural modification of samples. Real time in-situ electrical measurement is performed to investigate the change in insulation resistance of Al2O3 due to radiation induced conductivity at low flux regime. During neutron irradiation, a significant transient decrease in insulation resistance is observed which recovers relative higher value just after neutron exposure is switched off. XRD results of 14 MeV neutron irradiated samples suggest annealing effect. Impact of relatively low energy neutrons on the structural properties is also studied using Am-Be neutrons. In this case, clustering is observed on the sample surface after prolonged neutron exposure. The structural characterizations of pristine and irradiated Al2O3 samples are performed using XRD, SEM, and EDX. The results from these characterizations are analysed and interpreted in the manuscript.

Synthesis of CoFe2O4 Magnetic Nanoparticles by Thermal Decomposition

  • Soundararajan, D.;Kim, Ki Hyeon
    • Journal of Magnetics
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    • v.19 no.1
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    • pp.5-9
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    • 2014
  • The amine functionalized $CoFe_2O_4$ nanoparticles were prepared by thermal decomposition method at reflux temperatures $160^{\circ}C$ and $172^{\circ}C$. The obtained $CoFe_2O_4$ nanoparticles at $160^{\circ}C$ reflux temperature show aggregation free poly-dispersed nanoparticles in 4-15 nm range. In an elevated reflux temperature of $172^{\circ}C$, $CoFe_2O_4$ show aggregated poly-dispersed nanoparticles in the size range of 20-46 nm. The saturation magnetization value at 300 K exhibited 51 emu/g at reflux temperature of $160^{\circ}C$. However, the sample synthesized at an elevated temperature of $172^{\circ}C$ has shown a coercive field value of 560 Oe with saturation magnetization of 68 emu/g.

Dynamic Pyroelectric Properties and Their Frequency Dependences of $LiTaO_3$ crystal ($LiTaO_3$crystal Dynamic 초전 특성과 그 주파수 의존성)

  • 이원재;윤영섭
    • Proceedings of the IEEK Conference
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    • 1998.10a
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    • pp.605-608
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    • 1998
  • In this paper, we have investigated the pyroelectric characteristics of the $20\mu\textrm{m}-thick$ $LiTaO_3$ single crystal with black coating by using the nondestructive dynamic method. The $LiTaO_3shows$ the maximum pyroelectric coefficient (${\gamma}$) of $1.56$\times$10-8C/\textrm{cm}^2K$ at 40Hz and the responsivity (Rv) is 488V/W at 2Hz. The noise equivalent power (NEP) is obtained as 3.95$\times$10-10W/√Hz at 40Hz. The detectivity (D*) is obtained divided by the sample area and estimated to be 5.6$\times$108cm√Hz/W at 40Hz. These results, shows that the $LiTaO_3$ single crystals are the best candidates to pyroelectric IR sensors.

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A Study on Development of EM Wave Absorber Using TiO2 for Automotive Radar in Cars

  • Choi, Chang-Mook;Kim, Dong-Il
    • Journal of electromagnetic engineering and science
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    • v.8 no.3
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    • pp.110-113
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    • 2008
  • In this paper, we designed and fabricated an electromagnetic(EM) wave absorber for automotive radar in cars using $TiO_2$ as a dielectric material and chlorinated polyethylene(CPE) as a binder. First of all, we confirmed that the optimum composition ratio of $TiO_2$ was about 70 wt.%. The complex relative permittivity of a sample containing $TiO_2$: CPE=70:30 wt.% was calculated from S-parameter. The EM wave absorption abilities were simulated for the EM wave absorbers of different thickness using the calculated relative permittivity, and the EM wave absorber was manufactured based on the simulated design. A comparison of simulated and measured results is in good agreement. Measurement shows that a 1.85 mm thick absorber has absorption ability higher than 20 dB in the frequency range of $76{\sim}77$ GHz for automotive radars.

Synthesis and Characterization of Superparamagnetic Fe3O4@SiO2 Nanoparticles

  • Kulkarni, Sachnin A.;Sawadh, P.S.;Palei, Prakash K.
    • Journal of the Korean Chemical Society
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    • v.58 no.1
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    • pp.100-104
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    • 2014
  • Magnetite nanoparticles were prepared by co-precipitation method and then silica was coated onto the surface of $Fe_3O_4$ by hydrolysis of TEOS. The silica coated magnetite nanoparticles were characterized for its structural, microstructural, optical, vibrational and magnetic properties by X-ray diffraction analysis, Scanning electron microscopy, UV-visible spectroscopy, Infrared spectroscopy and Vibration sample magnetometer, respectively. XRD study confirmed the presence of $SiO_2$ on the surface of magnetite nanoparticles. SEM study indicated that with increase in TEOS content the particles become bigger and mono-disperse. It was also found that the silica coating prevents magnetic particles from aggregation and imparts excellent stability.