• 한국재료학회지
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• 제2권2호
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• pp.101-109
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• 1992

PET(polyethylene terephthalate)는 섬유 및 다방면의 응용분야에 사용되는 상업용 고분자로 알려져 있다. 본 논문에서는 PET를 개질하기 위해 pentanediol의 이성질체인 1,5-pentanediol(1, 5-PD)과 neopentyl glycol(NPG)를 제3 monomer로 도입시켰다. NPG를 도입시킨 경우에는 결정화 속도가 감소하고, 1,5-PD로 개질된 PET는 1,5-PD가 약 10mo1% 첨가될 때가지 결정화 속도가 서서히 증가하였다. 이러한 결과는 NPG의 branch된 methyl기가 고분자 사슬에 표면으로 확산되면서 결정화하는 것을 방해하기 때문이다.

• 한국환경보건학회지
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• 제23권4호
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• pp.133-138
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• 1997

The technology of removing phosphorous, considered as one of the most important control nutrients causing eutrophication in various water bodies, have been investigated by many researchers. Recently, phosphorous crystallization process is emerging as a new technology for phosphorous removal. In this study, waste oyster shells which can be easily obtained from the ocean, were used as a seed crystal, and their effects of several physical/chemical factors on the phosphorous removal efficiencies were examined by batch tests. Ca$^{2+}$ and pH affected phosphorous crystallization process using waste oyster shells. As alkalinity of wastewater increased, phosphorous removal efficiencies gradually decreased. Phosphorous removal efficiencies were increased, as specific area and contact efficiency per unit area of waste oyster shells were increased. In case of high temperature, phosphorous crystallization process was rapidly advanced and phosphorous removal efficiencies were increased. Dependig on X-ray diffraction analysis, it was showed that generation materials extracted from the surface of waste oyster shells with short reaction time were dominated by $CaHPO_4\cdot 2H_2O$, but progressed to $Ca_5(OH)(PO_4)_3$. The SEM observation reveals that the evident variations were hardly seen, but particle sizes of waste oyster shells were relatively bigger and showed forms of smaller plate than before.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.96.2-96.2
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• 2010

The surface morphology and structural properties of polycrystalline silicon (poly-Si) films made in-situ aluminum induced crystallization at various substrate temperature (300~600) was investigated. Silicon films were deposited by hot-wire chemical vapor deposition (HWCVD), as the catalytic or pyrolytic decomposition of precursor gases SiH4 occurs only on the surface of the heated wire. Aluminum films were deposited by DC magnetron sputtering at room temperature. continuous poly-Si films were achieved at low temperature. from cross-section TEM analyses, It was confirmed that poly-Si above $450^{\circ}C$ was successfully grown on and poly-Si films had (111) preferred orientation. As substrate temperature increases, Si(111)/Si(220) ratio was decreased. The electrical properties of poly-Si film were investigated by Hall effect measurement. Poly-Si film was p-type by Al and resistivity and hall effect mobility was affected by substrate temperature.

• International Journal of Concrete Structures and Materials
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• 제11권2호
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• pp.315-325
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• 2017

The purpose of the paper is to determine the influence of two widely used steel fibers and polypropylene fibers on the sulphate crystallization resistance, freeze-thaw resistance and surface wettability of ultra-high performance concrete (UHPC). Tests were carried out on cubes and cylinders of plain UHPC and fiber reinforced UHPC with varying contents ranging from 0.25 to 1% steel fibers and/or polypropylene fibers. Extensive data from the salt resistance test, frost resistance test, dynamic modulus of elasticity test before and after freezing-thawing, as well as the contact angle test were recorded and analyzed. Fiber hybridization relatively increased the resistance to salt crystallization and freeze-thaw resistance of UHPC in comparison with a single type of fiber in UHPC at the same fiber volume fraction. The experimental results indicate that hybrid fibers can significantly improve the adhesion properties and reduce the wettability of the UHPC surface.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1998년도 한국재료학회 춘계학술발표강연 및 논문개요집
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• pp.114-114
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• 1998

• Journal of Welding and Joining
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• 제18권3호
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• pp.106-113
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• 2000

Single crystallization behavior ad high temperature tensile properties of TLP bonded joints of Ni-base single crystal superalloy, CMSX-2 were investigated using MBF-80 and F-24 insert metals. CMSX-2 was bonded at 1523~1548K for 1.5~1.8ks in vacuum. The (100) orientation of bonded specimen was aligned perpendicular to the joint interface. Crystallographic orientation analyzed points over the bonded region possessed the almost same orientation across the joint interface and misorientation $\Delta^{\theta}$ was negligibly small in as-bonded and post-bond heat-treated situations. It was confirmed that single crystallization could be readily achieved during TLP bonding. The tensile strengths of all joints at elevated temperatures were equal to or greater than those of base metal the range of testing temperature between 923K and 1173K. The elongation and reduction of area in values were almost the same as those of base metal. SEM observation of the fracture surfaces of joints after tensile test revealed that the fracture surface indicated the similar morphologies each other, and that the fracture of joints occurred in the base metal in any cases.

• 한국표면공학회지
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• 제41권6호
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• pp.301-307
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• 2008

In this paper, nanocrystallization of CuNiTiZr bulk metallic glass (BMG) subjecting to a kinetic spraying, dependent on impact velocity, was investigated by numerical and experimental approaches. The crystallization fraction and nucleation activation energy of initial feedstock and as-deposited coating were estimated by DSC and Kissinger method, respectively. The results of numerical modeling and experiment showed that the crystalline fraction and nucleation activation energy in BMG coatings were depended on kinetic energy of incident particle. Upon impact, the conversion of particle kinetic energy leads to not only decreasing free energy barrier but also increasing the driving force for an amorphous to crystalline phase transformation. The nanocrystallization of BMGs is associated with the strain energy delivered by a plastic deformation with a high strain rate.

• 한국치위생학회지
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• 제19권1호
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• pp.151-159
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• 2019

Objective: This study aimed to investigate the relation between rinsing time and the change in enamel surface after fluoride application on the enamel surface. Methods: We recruited two sample groups with different mouth rinsing times. While one group rinsed the teeth immediately after applying acidulated phosphate fluoride (APF) gel, the other group rinsed the teeth 30 minutes after APF gel application. In each group, we performed the following four-step experiment: (i) apply APF gel on the teeth, (ii) rinse the teeth, (iii) immerse the teeth in orange juice, and (iv) measure enamel surface microhardness and scan enamel surfaces. Results: The group that rinsed 30 minutes after treatment exhibited greater microhardness than the group that rinsed immediately after fluoride treatment. The former also showed smooth and regular crystallization, whereas the latter showed rough and damaged crystallization and irregular surfaces. Conclusions: Based on these observations, we conclude that delaying the rinsing time improves the dental caries preventive effect of fluoride.

• Advances in nano research
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• 제10권3호
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• pp.211-219
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• 2021

The evaluation of the corrosion resistance of titanium with a TiO2 nanotubes top layer was carried out (TiO2 NT). These nanostructures were evolved into anatase nanoparticles without heat treatment in an aqueous medium, which is a novel phenomenon. This work analyzes the layer between the nanotube bottom and the substrate, which is thin and still susceptible to corrosion. The bottom of TiO2 nanotubes having Fluor resulting from the synthesis process changed between amorphous to crystalline anatase with a crystallite size of about 4 nm, which influenced the corrosion rates. Four kinds of samples were evaluated. A) NT by Ti anodizing; B) NTSB for Ti plates, either modifying its surface or anodizing the modified surface; C) NT-480 for anodized Ti and heat-treated (480℃) for reaching the anatase phase; D) NTSB-480 for Ti plates, first, modifying its surface using sandblast, after that, anodizing the modified surface, and finally, heat-treated to 480℃ to compare with samples having induced crystallization and passivation. Four electrochemical techniques were used to evaluate the corrosion rates. The surfaces having TiO2 nanotubes with a sandblast pre-treatment had the highest resistance to corrosion.

• 한국세라믹학회지
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• 제22권2호
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• pp.44-50
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• 1985

The crystallization behavior of $K_2O-SiO_2$ glasses with added $TiO_2$ and the effect of $TiO_2$ on internal nuleation at temperature in the range of 875 to 121$0^{\circ}C$ have been investigated by means of X-ray diffractometry optical microscopy and scanning electron microscopy. The crystalline phase of these glasses identified by X-ray diffractometry is cristbalite. The scanning electron microspcopy reveals a two-phase layer of dendritic crystals and intersitial melt which grow from the surface at a constant rate, The observed crystallization rates are consistent with a diffusion-controlled mechanism. An equation relating viscosity and undercooling to growth rate is presented.