• 한국전기전자재료학회논문지
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• 제26권9호
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• pp.701-706
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• 2013

We have focused on the conversion efficiency of CIGS thin film solar cell prepared by co-evaporation method as well as the optimization of process condition. The total thickness of back electrode was fixed at 1 ${\mu}m$ and the structural, electric and optical properties of CIGS thin film were investigated by varying the thickness of Mo:Na bottom layer from 0 to 500 nm. From the experimental results, the content of Na was appeared as 0.28 atomic percent when the thickness of Mo:Na layer was 300 nm with compactly densified plate-shape surface morphology. From the XRD measurements, (112) plane was the strongest preferential orientation together with secondary (220) and (204) planes affecting to the crystallization. The lowest roughness and resistivity were 2.67 nm and 3.9 ${\Omega}{\cdot}cm$, respectively. In addition, very high carrier density and hole mobility were recorded. From the optimization of Mo:Na layer, we have achieved the conversion efficiency of 9.59 percent.

• 한국결정성장학회지
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• 제9권4호
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• pp.371-376
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• 1999

A large NaX type zeolite crystal of a uniform particle size of 20$\mu\textrm{m}$ are grown with various {{{{{H}_{2}O}}}} content by hydrothermal reaction and added seed crystal (2~3$\mu\textrm{m}$) to reactant solution as a function of different adding seed levels from 3 to 15%. The result that increased purity of NaX zeolite above 95% and homogeneity of crystal size by increasing adding seed levels, also decreased crystallization time. It was explained that adding seed to synthesis solution leaded out increase of surface area for physical contact reaction and directed growth of seed crystal, so more rapid consumption of reaction gel as increase seeding levels.

• Transactions on Electrical and Electronic Materials
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• 제9권1호
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• pp.12-15
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• 2008

Hafnium oxynitride films have been deposited onto a silicon substrate by means of radio frequency (RF) reactive sputtering using a hafnium dioxide $(HfO_2)$ target with a variety of nitrogen! argon $(N_2/Ar)$ gas flow ratios. Auger electron spectroscopy (AES)results confirm that $N_2$ was successfully incorporated into the HfON films. An increase in the $N_2/Ar$ gas flow ratio resulted in metal oxynitride formation. The films prepared with a $N_2/Ar$ flow ratio of 20/20 sccm show (222), (530), and (611) directions of $HfO_2N_2$, and the (-111), (311) directions of $HfO_2$. From X-ray reflectometry measurements, it can be concluded that with $N_2$ incorporated into the HfON films, the film density increases. The density increases from 9.8 to $10.1g/cm^3$. XRR also reveals that the surface roughness is related to the $N_2/Ar$ flow ratio.

• 대한디지털의료영상학회논문지
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• 제12권2호
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• pp.145-150
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• 2010

Thick films of carbon fiber were prepared by a heating element of plan shape made in Darin co., We have investigated surface morphology of the specimen depending on heat-treatment temperatures. Scanning electron microscope(SEM) image of carbon fiber thick films of the specimen heat treated shows a grain growth at $1200^{\circ}C$ and becomes a poly-crystallization at $1350^{\circ}C$. The variation of resistivity at the thermally annealed specimen above $600^{\circ}C$ depends on type of the substrates. It may be due to a variation of film thickness and a difference of interfacial phenomena. A heating element of features was affected significantly by skin blood and quantity of heat of the body physiological function. After radiation of farinfrared for plate heating element, the function of biometric physiological is considered of skin blood flow and calorie which greatly affects on individuals. Electromagnetic wave was not influence on the body.

• 상하수도학회지
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• 제27권6호
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• pp.751-759
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• 2013

This study is carried out to get the basic design parameters for phospate removal facilites from wastewater by Tobermolite. The phosphate removal by the apatite formation on the surface was affected by several important factors, temperature, ions present in wastewater stream, contact time, recirculation rate, and etc. In case of the temperature, with the increase of temperature, the apatite formation was accelerated. When temperature increased from $15^{\circ}C$ to $35^{\circ}C$, removal efficiency of phosphate increased from 83 % to 93 %. An increase of calcium and fluoride ion content increase the apatite formation, however, bicarbonate and magnesium ion inhibited the crystallization of apatite. As expected, when the recirculation rate was increased from 1 Q to 3 Q, at EBCT (Empty Bed Contact Time) 60min enhanced removal efficiency was observed. The more the recirculation rate increased, the more the removal efficiency increased. According to the results of column experiment using an actual wastewater with low and high phosphate concentration (5 mg/L and 50 mg/L-P), the removal efficiency was 77 % at EBCT of 45 min, and 80 % at 60 min. It was suggested that optimum EBCT was 45 min.

• 한국염색가공학회지
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• 제24권1호
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• pp.91-96
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• 2012

The physical properties of recycled polyester yarns according to recycling methods were investigated. Virgin polyester draw texturized yarn(DTY), material-recycled(MR) polyester DTY and chemical-recycled(CR) polyester DTY were prepared. Surface morphology, thermal property, micro-structure and mechanical property of recycled polyester yarns were estimated. SEM-EDS analysis showed that the CR PET yarn had better crimp and more stable structure than MR PET yarn. Tm of the MR PET yarn was higher than that of the CR PET yarn. The intensity of the crystallization peak of the CR PET yarn was a little higher than that of the MR PET yarn. Tensile strength of the MR PET yarn was slightly higher than that of the CR PET yarn. Breaking elongation of the CR PET yarn was slightly higher than that of the MR PET yarn.

• 열처리공학회지
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• 제23권4호
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• pp.205-209
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• 2010

Transparent and conductive AZO films were deposited on the glass by using radio frequency (RF) magnetron sputtering with intense electron radiation, simultaneously. After deposition, the effect of electron radiation energy on the optical and electrical properties of AZO was investigated. In XRD measurements, the films irradiated with intense electron beam show the larger grain size than that of the films prepared without electron radiation. Sheet resistance was also dependent on the electron radiation energy, while the optical transmittance in visible wavelength region was not affected seriously by electron radiation. X-.ray diffraction, UV-Vis spectrophotometer and four point probes were used to observe the crystallization, optical transmittance and sheet resistance, respectively.

• 한국세라믹학회지
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• 제26권6호
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• pp.811-819
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• 1989

There have been many studies on the biological phenomena of Bioglasses, which nay be used as implant materials in human body. However, not many works on the Bioglass compositions have been reported. In the present study, the effect of Al2O3 substitution for SiO2 in Bioglass of Na2O-CaO-P2O5-SiO2 system on its structure and properties was examined. Infrared and Raman spectroscopic studies for the glass structural analysis, differential thermal analysis and X-ray diffraction analysis for crystallization of the glass were perfomed. Several physical properties, such as thermal expansion coefficient, softening point, microhardness and reaction phenomena, were also measured. The major crystalline phase, after heat treatment of the glasses, was Na2Ca2(SiO2)3 and the crystal was transformed into other phase with increased substitution of Al2O3. The added Al2O3 reduced non-bridging oxygen in glass structure and thermal expansion coefficient, but increased glass density, sofening point and microhardness. When the glasses are reacted in Tris-buffer solution, the substituted Al2O3 inhibited the formation of hydroxyapatite on the Bioglas surface, and no hydroxyapatite was formed for the sample which contained more than 6wt.% of Al2O3 even if they were reacted for 600 hours.

• 보존과학연구
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• 통권33호
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• pp.57-67
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• 2012

의성 탑리리 오층석탑은 박리박락, 입상분해, 표면변색 등 물리적 및 화학적 훼손이 발생하여 석탑의 표면이 심하게 훼손되어 있으며, 특히 주요 훼손영역에서는 염에 의한 백화현상이 발생하고 있다. 석탑에서 발생한 염의 SEM-EDS 분석 및 X-선 회절분석 결과, 대표적인 염은 석고로 나타났으며, 일부 영역에서 타라나카이트도 확인되었다. 석탑과 동일한 암석을 선택하여 염풍화 실험을 실시한 결과, 암석의 표면은 염 결정 성장과 함께 염에 의한 백화현상이 발생하였으며 내부는 미세균열 및 공극을 따라 염 수용액이 이동하고 결정화되면서 풍화(박리박락, 입상분해)되는 것으로 나타났다.

• 폴리머
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• 제39권2호
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• pp.200-209
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• 2015

In this study, the influence of dilauroyl peroxide on mechanical and thermal properties of different polypropylene (PP) matrices was investigated. Polypropylene matrices, different molecular weight isotactic PP containing 0.01, 0.02, 0.04, 0.06, 0.08, and 0.1 wt% of dilauroyl peroxide (DLP) were prepared by using a single-screw extruder. The effect of the visbreaking agent (DLP) on mechanical, physical, thermal and morphological properties of different molecular weight PP had been studied. Mechanical properties (tensile strength at break point, at yield and elongation at break point), melt flow index (MFI), scanning electron microscope (SEM) and differential scanning calorimetric (DSC) analyses of these matrices were examined. Melting ($T_m$) and crystallization ($T_c$) temperatures, crystallinity ratio (%) and enthalpies were determined. The microstructure of isotactic polypropylene matrix was investigated by scanning electron microscopy (SEM). From SEM analysis, it was observed that the surface disorder increased by the increasing amount of DLP. As a result of DSC analyses, the crystallinity ratio of the PP matrices has varied between 1.64-7.27%. Mechanical properties of the matrices have been improved. Particularly, the mechanical tests of PP have given interesting results when compounded with 0.06-0.08 wt% dilauroyl peroxide (DLP). Mechanical properties and thermal decomposition processes were all changed by increasing the amount of DLP in the matrix structure.