• Title/Summary/Keyword: SR-20

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Resistive Switching Behavior of Cr-Doped SrZrO3 Perovskite Thin Films by Oxygen Pressure Change (산소 분압의 변화에 따른 Cr-Doped SrZrO3 페로브스카이트 박막의 저항변화 특성)

  • Yang, Min-Kyu;Park, Jae-Wan;Lee, Jeon-Kook
    • Korean Journal of Materials Research
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    • v.20 no.5
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    • pp.257-261
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    • 2010
  • A non-volatile resistive random access memory (RRAM) device with a Cr-doped $SrZrO_3/SrRuO_3$ bottom electrode heterostructure was fabricated on $SrTiO_3$ substrates using pulsed laser deposition. During the deposition process, the substrate temperature was $650^{\circ}C$ and the variable ambient oxygen pressure had a range of 50-250 mTorr. The sensitive dependences of the film structure on the processing oxygen pressure are important in controlling the bistable resistive switching of the Cr-doped $SrZrO_3$ film. Therefore, oxygen pressure plays a crucial role in determining electrical properties and film growth characteristics such as various microstructural defects and crystallization. Inside, the microstructure and crystallinity of the Cr-doped $SrZrO_3$ film by oxygen pressure were strong effects on the set, reset switching voltage of the Cr-doped $SrZrO_3$. The bistable switching is related to the defects and controls their number and structure. Therefore, the relation of defects generated and resistive switching behavior by oxygen pressure change will be discussed. We found that deposition conditions and ambient oxygen pressure highly affect the switching behavior. It is suggested that the interface between the top electrode and Cr-doped $SrZrO_3$ perovskite plays an important role in the resistive switching behavior. From I-V characteristics, a typical ON state resistance of $100-200\;{\Omega}$ and a typical OFF state resistance of $1-2\;k{\Omega}$, were observed. These transition metal-doped perovskite thin films can be used for memory device applications due to their high ON/OFF ratio, simple device structure, and non-volatility.

Ion Exchange Phenomena of $Cs^{+1},\;Sr^{+2},\;and\;Th^{+4}$ on Ion Exchange Resin in Loading and Elution Process ($Cs^{+1},\;Sr^{+2}$$Th^{+4}$가 동시에 이온교환수지에 흡착 및 탈착시의 이온교환현상)

  • Park, Chong-M.;Walter, Meyer
    • Journal of Radiation Protection and Research
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    • v.11 no.2
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    • pp.104-113
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    • 1986
  • The ion exchange behaviour of the $Cs^{+1},\;Sr^{+2},\;and\;Th^{+4}$ in the system of $Cs^{+1},\;Sr^{+2},\;Th^{+4},\;and\;7Cl^{-}-H^{+}$ from Dowex HCR-W2, was examined in the loading and elution processes. $Th^{+4}$ was slowly adsorbed through the entire contact time between resin and solution and $Cs^{+1}\;and\;Sr^{2+}$ were adsorbed fast for the first few minutes of contact time. Because of the strong affinity of $Th^{+4}$, the longer contact time was allowed, the less amount of $Cs^{+1}\;and\;Sr^{2+}$ was adsorbed on the resin. The peak concentration of the resin phase $Cs^{+1}$ in the solution concentration of $Cs^{+1}:Sr^{+2}:Th^{+4}$ in the ratio of 2 : 2 : 1 in normality with total normality of 0.1N was produced at about 4 minutes of contact time and the peak time for $Sr^{+2}$ was 20 minutes. The loaded ions were eluted using hydrochloric acid. The loaded $Cs^{+1}$ was eluted at the low eluent concentration of less than 0.1N with less than 5% contamination of $Sr^{+2}$. The loaded $Th^{+4}$ was eluted at the high eluent concentration of greater than 1N. The best eluent concentration for eluting $Th^{+4}$ was 4N.

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Screening of SrO-B2O3-P2O5 Ternary System by Combinatorial Chemistry and QSAR (조합화학과 QSAR를 이용한 SrO-B2O3-P2O5 3원계 청색형광체 개발)

  • Yoo, Jeong-Gon;Back, Jong-Ho;Cho, Sang-Ho;Sohn, Kee-Sun
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.391-398
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    • 2005
  • It is known that $BaMgAl_{10}O_{17}:Eu^{2+}(BAM)$ phosphors currently used have a serious thermal degradation problem. We screened $SrO-B_2O_3-P_2O_5$ system by a solution combinatorial chemistry technique in an attempt to search for a thermally stable blue phosphor for PDPs. A Quantitative Structure Activity Relationship (QSAR) was also obtained using an artificial neural network trained by the result fiom the combinatorial screening. As a result, we proposed a promising composition range in the $SrO-B_2O_3-P_2O_5$ ternary library. These compositions crystallized into a single major phase, $Sr_6BP_5O_{20}:Eu^{2+}$. The structure of $Sr_6BP_5O_{20}:Eu^{2+}$ was clearly determined by ab initio calculation. The luminescent efficiency of $Sr_6BP_5O_{20}:Eu^{2+}$ was 2.8 times of BAM at Vacuum Ultra Violet (VUV) excitation. The thermal stability was also good but the CIE color chromaticity was slightly poor.

Effect of chemical doping on heterostructured Fe-based superconductor Sr2VO3FeAs

  • Ok, Jong Mok;Na, Se Woong;Kim, Jun Sung
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.1
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    • pp.28-31
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    • 2018
  • Phase diagrams of electron- and hole-doped $Sr_2VO_3FeAs$ are investigated using Co and Mn substitution at Fe site. Metallic nature survives only for Co (electron) doping, not for Mn (hole) doping. The conductivity of $Sr_2VO_3(Fe,M)As$ (M=Mn,Co) is sensitive to the structural modification of FeAs microstructure rather than carrier doping. This finding implies that the FeAs layer plays a dominant role on the charge conduction, thus the $SrVO_3$ layers should be considered as an insulating block. Also, we found that the superconductivity is rapidly suppressed by both dopants. This result is different from the conventional behavior that superconductivity is induced by doping in the most of Fe pnictides. Our finding strongly supports the uniqueness of $Sr_2VO_3FeAs$ among the Fe pnictide superconductors.

Development of EM Wave Absorbers for GHz Frequency (GHz 대역용 전파흡수체의 개발)

  • 문상현;신승재;김동일;송재만;최정현;김기만
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2004.04a
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    • pp.17-22
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    • 2004
  • We prepared EM wave absorbers by using recycled Ba and Sr ferrites for GHz frequency, and investigated the effects of carbon additions, thickness and preparation temperatures on their EM wave absorption properties. We clarified that it is very important to consider carbon amounts in Ba and Sr ferrites and preparation temperature for Ba and Sr ferrite EM wave absorbers with high quality. In this study, the developed a EM Wave absorber satisfying over 20 dB.

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Synthesis and Photo Luminescent Characteristics of SrAl2O4:Eu2+,Dy3+ Phosphor using Polymer Matrix (폴리머 매트릭스를 전구체로 사용한 SrAl2O4:Eu2+,Dy3+ 축광성 형광체의 합성 및 형광 특성)

  • Kim, Soo-Jong;Kwon, Hyuk-Sil
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.8
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    • pp.671-679
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    • 2007
  • [ $SrAl_2O_4:Eu^{2+},\;Dy^{3+}$ ] phosphor was synthesized using the impregnation method, and its photoluminescence and long-afterglow properties were investigated, A mixture of $Sr(NO_3)_2,\;Al(NO_3)_2\;9H_2O,\;EuCl_3\;6H_2O,\;DyCl_3\;6H_2O,\;NdCl_3\;6H_2O$ salts were dissolved in distilled water and impregnating into the polymer precursor. After drying, the impregnated mixture was heat treated at $900-1400^{\circ}C$ for 2h in a $N_2-H_2$ reduction atmosphere. The microstructure and crystal structure of the $SrAl_2O_4:Eu^{2+},\;Dy^{3+}$ powders were examined by scanning electron microscopy and X-ray diffraction, respectively. The photoluminescence spectra showed an excitation band along over wide wavelength of 250-450nm, and a broaden emission with a maxima peak at 360nm. In addition, the spectra also showed a good long after glow that decayed over a 1000sec period after 10 min excitation illumination.

Photoluminescence and Long-phosphorescent Characteristics of SrAl2O4:Eu2+,Dy3+ Phosphor by Glycine-nitrate Combustion Method (글리신-질산염 연소법으로 합성된 SrAl2O4:Eu2+,Dy3+ 형광체의 발광 및 장잔광 특성)

  • Lee, Young-Ki;Kim, Jung-Yeul;Lee, You-Kee
    • Korean Journal of Materials Research
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    • v.20 no.7
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    • pp.364-369
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    • 2010
  • A $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor powder with stuffed tridymite structure was synthesized by glycine-nitrate combustion method. The luminescence, formation process and microstructure of the phosphor powder were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). The XRD patterns show that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was an amorphous phase. However, a crystalline $SrAl_2O_4 $ phase was formed by calcining at $1200^{\circ}C$ for 4h. From the SEM analysis, also, it was found that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was in irregular porous particles of about 50 ${\mu}m$, while the calcined phosphor was aggregated in spherical particles with radius of about 0.5 ${\mu}m$. The emission spectrum of as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor did not appear, due to the amorphous phase. However, the emission spectrum of the calcined phosphor was observed at 520 nm (2.384eV); it showed green emission peaking, in the range of 450~650 nm. The excitation spectrum of the $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor exhibits a maximum peak intensity at 360 nm (3.44eV) in the range of 250~480 nm. After the removal of the pulse Xe-lamp excitation (360 nm), also, the decay time for the emission spectrum was very slow, which shows the excellent longphosphorescent property of the phosphor, although the decay time decreased exponentially.

Numerical Simulation on the Effects of Air Staging for Pulverized Coal Combustion in a Tangential-firing Boiler (접선연소식 보일러에서 미분탄 연소 시 공기 배분의 영향에 대한 전산해석연구)

  • Kang, Kieseop;Ryu, Changkook
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.548-555
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    • 2017
  • This study investigated the influence of air staging on combustion and NOx emission in a tangential-firing boiler at a 560 MWe capacity. For air staging, the stoichiometric ratio (SR) for the burner zone was varied from 0.995 to 0.94 while the overall value was fixed at 1.2. The temperature and heat flux in the burner zone and upper furnace corresponded to the distribution of SR, while the total boiler efficiency remained similar. The NOx emission at the furnace exit was reduced by up to 20% when the SR in the burner zone decreased to 0.94. However, the amount of unburned carbon and slagging propensity was not noticeably influenced by the changes in the SR of the burner zone. Therefore, it was favorable to lower the SR of the burner zone for reduction of NOx emission.