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기판-타겟간 거리가 선형 대향 타겟 스퍼터 시스템으로 성장시킨 AGZO 전극 특성에 미치는 효과 연구

  • Sin, Hyeon-Su;Seo, Gi-Won;Lee, Ju-Hyeon;Kim, Han-Gi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.533-533
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    • 2013
  • 본 연구에서는 선형 대향 타겟 스퍼터 시스템을 이용하여 hetero sputtering방법으로 증착한Al-Ga-Zn-O (AGZO) 박막의 기판-타겟간 거리(Target-to-Substrate distance)에 따른 전기적, 광학적, 구조적 특성을 분석하였다. 타겟과 기판 사이의 거리 변화(30~120 mm)에 따른 AGZO 박막의 특성 변화를 관찰하기 위하여 일정한 DC 파워 250 W, 공정압력 0.3 mTorr, Ar 20 sccm에서 서로 다른 AZO 타겟과 GZO 타겟을 이용하여 hetero-sputtering 공정을 진행하였다. 최적의 타겟과 기판 사이의 거리를 결정하기 위해 AGZO 박막의 투과도(T)와 면저항($R_{sh}$)을 기반으로 figure of merit ($T^{10}/R_{sh}$)값을 계산하였다. 기판-타겟간 거리는 AGZO 박막의 밀도에 영향을 주는 핵심 인자로 30 mm에서 120 mm로 증가수록 밀도가 낮은 AGZO 박막이 형성되었다. 최적의 타겟과 기판 사이의 거리(30 mm)에서 AGZO 박막은 132 Ohm/sq의 낮은 면저항과 87.2%의 높은 투과도를 나타내었다. 그러나 기판-타겟간 거리가 증가할수록 같은 두께에서 면저항은 급격히 증가함을 발견할 수 있었으며 이러한 특성 변화는 스퍼터되어 기판에 도달하는 입자의 에너지 차이로 설명이 가능하다. 따라서 본 연구에서는 기판-타겟간 거리에 따른 AGZO 박막의 특성 변화를 설명할 수 있는 메커니즘을 다양한 분석을 통해 제시하였다. 또한 적화된 AGZO 투명 전극을 이용해 제작한 GaN-LED의 Damage free sputtering 기술에 대해서 소개한다.

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Blockade of Thromboxane Influences Does Not Affect Renal Blood Flow Deficit in Anesthetized Diabetic Rats (마취된 당뇨 흰쥐의 신혈류량 감소에 관여하는 기전 : 내인성 쓰롬복산계의 무관성)

  • Ha, Hun-Joo;Dunham, Earl W.
    • The Korean Journal of Pharmacology
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    • v.24 no.2
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    • pp.221-232
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    • 1988
  • Studies were conducted to determine whether reduced renal blood flow (RBF) exhibited by rats with uncontrolled, streptozotocin (STZ)-induced diabetes is attributable to diabetes-associated, enhanced renal vasoconstrictor influence of endogenous thromboxane $(TX)A_2$. Rats which were injected with STZ after pretreatment with 3-O-methyl glucose (3OMG), an agent which prevents STZ-induced hyperglycemia, were also studied. Basal values of total RBF (RBF; ml $min^{-1}$ $gKw^{-1}$; electromagnetic flow probe), systemic arterial pressure (BP; mm Hg) and renal vascular resistance (RVR;BP $RBF^{-1})$in pentobarbital-anesthetized rats during a control period were $5.9{\pm}0.3$(P<0.1_{VS}. CR), $115{\pm}3$ and $20.3{\pm}1.0$(P<0.1_{VS}. CR) for STZR (n=15), and $8.4{\pm}0.4$, $123{\pm}3$ and $15.1{\pm}0.8$ for age-matched control rats (CR; n= 15), respectively. Basal values of RBF, BP and RVR in 3OMG pretreated STZR were identical to CR. In preparations shown capable of renal vasodilatation, OKY 1581 (1 mg/kg, i.v. followed by 0.4 mg/kg min infusion) abolished arachidonate-induced $(TX)A_2$ synthesis, but did not alter basal BP, RBF or RVR in either STZR or CR (n=4/group). Similarly, i.r.a. infusion of SQ29548 (100 ng/ml RBF) abolished renal vasoconstriction induced by a TX/prostaglandin endoperoxide mimic, U46619, but had no discern able affect on RVR in either STZR (n=8) or CR (n=8). The data indicates that $TXA_2$ does not participate in the elevated basal RVR of STZR which are associated with the diabetic state.

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Weight control behavior in women college students and factors influencing behavior (일부 여대생의 체중조절행위와 영향 요인)

  • Yang, Hyun-Young;Byeon, Young-Soon
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.19 no.2
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    • pp.190-200
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    • 2012
  • Purpose: The purpose of this study was to provide basic data for the development of weight control programs to maintain and promote healthy behavior in women college students by identifying their weight control behaviors and factors that influence these behaviors. Method: Data were collected from 300 women student participants and were analyzed using descriptive statistics, t-test, ANOVA, Pearson correlation coefficients, and multiple regression with the SPSS 18.0 program. Result: Weight control behavior showed a significant difference according to participants' gender role identity type. Weight control behaviors were correlated with self-efficacy, body image, objective BMI, and ideal BMI. Factors influencing weight control behavior were self-efficacy (${\beta}$= .449, $p$<.001), secret method for weight loss (${\beta}$= .181, $p$<.001), monthly allowance below 200,000 won (${\beta}$= .156, $p$= .006), weight control support from others (${\beta}$= .124, $p$= .013), eating breakfast (${\beta}$= .119, $p$= .015), and age (${\beta}$= .113, $p$= .023) with R-sq. value of 45.3%. Conclusion: The results of the study indicate that development of interventions for weight control behavior and health education for college women should reflect identified factors influencing weight control behavior and gender role identity.

Ag Grid를 이용한 플렉시블 투명 전극의 투명 안테나 특성 연구

  • Jo, Chung-Gi;Kim, Han-Gi
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.27.2-27.2
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    • 2011
  • 본 연구에서는 저저항/고투과 플렉시블 투명 전극 개발을 위해 금속 그리드가 적용된 투명 전극을 개발하였다. Lift off 공정을 도입하여 플렉시블 PET 기판 위에 Ag grid를 성막하고 이후 연속 공정이 가능한 Roll-to-Roll sputtering system을 이용하여 최적화된 ITO(40nm)/Ag(12nm)/ITO(40nm) 다층 투명 전극을 성막하였다. 제작된 플렉시블 투명 전극의 전기적, 광학적, 구조적 특성 및 기계적/전기적 안정성 평가를 위해 four-point probe measurement, Hall effect measurement, UV/Vis spectrometer, scanning electron microscopy 및 bending tester를 이용하여 각각의 특성을 분석하였다. Ag grid가 적용된 ITO/Ag/ITO 투명 전극에서 Ag의 배선 간격이 0.75 mm일 때 0.18 ohm/sq. 의 낮은 면 저항과 가시광선 영역에서 80% 이상의 높은 투과율을 나타내었으며, 이러한 저저항 및 고투과율 특성으로 인해 최적화된 배선 간격 0.75 mm에서 $538.11{\times}10^{-3}\;ohm^{-1}$의 매우 높은 figure of merit ($T^{10}/R_{sh}$) 값을 확보할 수 있었다. 기계적 응력에 따른 전기적 안정성 특성 분석 결과 5,000회 이상의 bending cycle 에서도 초기 저항 값과 유사한 전기적 특성을 나타냄으로써 Ag grid가 적용된 ITO/Ag/ITO 플렉시블 투명 전극의 기계적 응력에 따른 전기적 안정성을 확인할 수 있었다. Ag grid가 적용된 ITO/Ag/ITO 투명 전극의 투명 안테나 적용 가능성을 타진하기 위해 low band 및 high band 영역에서의 안테나 효율을 측정하였으며, 모든 영역에서 상용화된 copper 안테나와 유사한 효율을 나타내었다. Ag grid를 이용한 플렉시블 투명 전극의 저저항/고투과율 특성은 플렉시블 광전소자의 투명 안테나로의 적용 가능성을 나타낸다.

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Opto-electrical properties of solution based carbon nanotube electrode (용액코팅된 탄소나노튜브 전극의 광전기적 성질)

  • Woo, Jong-Seok;Kim, Sun-Young;Han, Joong-Tark;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.394-394
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    • 2007
  • Transparent conductive films can serve as a critical component in displays, solar cells, lasers, optical communication devices, and solid state lighting. Carbon nanotube (CNT) based transparent conductive films are fabricated on glass and polymer substrates. CNTs typically exist in form of quasi-crystalline bundles or highly entangled bundles containing tens of individual nanotubes. To achieve full potential, CNTs must be dispersed in a solvent or other organic media. CNTs are acid treated with nitric acid then the stable dispersion of CNTs in polar solvent such as alcohols, DMF, etc. is achieved by sonication. The solubility of CNTs correlates well with the area ratio of the D and G bands from Raman spectrum. Thin films are formed from well dispersed CNT solutions using spray coating method. CNT thin films exhibit a sheet resistance ($R_s$) of nearby $10^3\;{\Omega}/sq$ with a transmittance of around 80% on the visible light range, which is attributed by excellent dispersion and interaction among CNTs, solvents and polymeric binders.

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Carbon Nanotube (CNT) based Transparent Conductive Films for Display Applications (탄소나노튜브 기반 투명전도성 필름 및 이의 응용)

  • Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.77-77
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    • 2007
  • The development of next generation displays such as flexible display is a major challenge. Most materials and processes in current flat panel display industry cannot be transferred to flexible substrates. Typically, indium tin oxide (ITO) thin films are brittle and need to be deposited at high temperature to achieve an optimal opto-electrical property, therefore ITO films cannot be used as a flexible electrode. Up to date, many alternative materials to ITO have been proposed such as conductive polymers, nanometals, solution deposited transparent conductive oxide(TCO) and carbon nanotubes(CNTs). CNT based transparent conductive films are fabricated on glass and polymer substrates. CNT thin films exhibit a sheet resistance ($R_s$) of nearby $10^3\;{\Omega}/sq$ with a transmittance of around 80% on the visible light range, which is attributed by excellent dispersion and interaction among CNTs, solvents and polymeric binders. This talk will present the current studies, opto-electrical properties, design criteria and its applications for CNT-based transparent conductive films.

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Synergistic Effect of Azadirachta Indica Extract and Iodide Ions on the Corrosion Inhibition of Aluminium in Acid Media (Azadirachta Indica엑스와 요드화이온이 산성매체에서 Al 부식방지에 대한 Synergistic 효과)

  • Arab, S.T.;Al-Turkustani, A.M.;Al-Dhahiri, R.H.
    • Journal of the Korean Chemical Society
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    • v.52 no.3
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    • pp.281-294
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    • 2008
  • synergistic action caused by iodide ions on the corrosion inhibition of aluminium (Al) in 0.5 M HCl in the presence of Azadirachta Indica (AZI) plant extract has been investigated using potintiodynamic polarization and impedance techniques. It is found that AZI extract inhibits the corrosion of aluminium in 0.5 M HCl. The inhibition efficiency increases with the increase in AZI extract concentration, until 24% v/v of AZI extract, then Inh.% is decreased with father increase in AZI extract concentration. The adsorption of this extract in the studied concentration is found to obey Frewendlish adsorption isotherm. The addition of iodide ions enhances the inhibition efficiency to a considerable extent. The increase in Inh.% values in presence of fixed concentration of iodide ions indicates that AZI extract forms an insoluble complex at lower AZI extract concentrations by undergoing a joint adsorption. But at higher concentrations of AZI extract, competitive adsorption is found between iodide ions and the formed complex leading to less Inh.%.The Inh.% decreased in presence of iodide ions with AZI extract than in presence of AZI extract alone at all studied iodide concentrations. The synergism parameter Sq is defined and calculated from surface coverage values. This parameter in the case of AZI extract is found to be more than unity, indicating that the enhanced inhibition efficiency caused by the addition of iodide ions.

Effects of Squalene on the Mice Hepatotoxicity Induced by Lead Acetate (납으로 유발된 생쥐 간장 독성에 대한 스쿠알렌의 효과)

  • Kim, Jong-Se
    • Applied Microscopy
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    • v.33 no.3
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    • pp.205-214
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    • 2003
  • To investigate the effect of the squalene against the lead toxicity. A healthy male of ICR mice were used for experiment. The SOD was observed after the intraperitoneal injection in mice. The ultrastructural changes of the liver were observed after the intraperitoneal injection in mice. The experimental groups were divided into two groups. Group A was control group that squalene was not treated after intraperitoneal injection of lead acetate. Group B was squalene treatment group that squalene solution was injected after intraperitoneal injection of lead acetate. All groups were used to 10 mice. The results were as follow: SOD activity in the liver, Group A was lower than in normal. But, Group B was higher than in Group A (P<0.05). In the histological observation, Group A were showed that the inner cavity of mitochondria swellen and development of cristae weakened. Swelling of lamellae of rough endoplasmic reticulum (rER) was showed. It was concluded that the SQ will be effective for the recovery of hepatic cell at lead intoxication.

Characterizing the Thermal Stability of TiSi2 Film by Using the Statistical Experimental Method (통계적 실험 방법을 이용한 티타늄실리사이드의 열적안정성 연구)

  • Cheong, Seong-Hwee;Song, Oh-Sung
    • Korean Journal of Materials Research
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    • v.13 no.3
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    • pp.200-204
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    • 2003
  • A statistical experiment method was employed to investigate the window of the thermal stability of $TiSi_2$films which are popular for Ti-salicide and ohmic layers. The statistical experimental results showed that the first order term of $TiSi_2$thickness and annealing temperature was acceptable as a function of $\Delta$resistivity by 95% reliability criteria, and R-sq value implying a fit accuracy of the model also showed a high value of 93.80%. We found that $\Delta$resistivity of the $TiSi_2$film annealed at $700^{\circ}C$ for 1 hr changed from 3.35 to $0.379\mu$$\Omega$$\cdot$cm with increasing thickness from 185 to $703\AA$, and TEX>$\Delta$resistivity of the $TiSi_2$film with a fixed thickness of 444 $\AA$ changed from 0.074 to 17.12 $\mu$$\Omega$$\cdot$cm with increasing temperature increase from 600 to $800^{\circ}C$. From these results, we report that the process conditions of$ 692^{\circ}C$-1 hr, $715^{\circ}C$-1 hr, and 73$0^{\circ}C$-1 hr for $TiSi_2$($400 \AA$) are stable by the criteria of 1, 2, and 3 $\mu$$\Omega$$\cdot$cm of $\Delta$resistivity, respectively.

Mass-Spectral Identification of an Extracellular Protease from Bacillus subtilis KCCM 10257, a Producer of Antibacterial Peptide Subtilein

  • SONG HYUK-HWAN;GIL MI-JUNG;LEE CHAN
    • Journal of Microbiology and Biotechnology
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    • v.15 no.5
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    • pp.1054-1059
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    • 2005
  • An extracellular protease was identified from Bacillus subtilis KCCM 10257 by N-terminal sequencing and mass spectral analysis. The molecular mass of the extracellular protease was estimated to be 28 kDa by SDS-PAGE. Sequencing of the N-terminal of the protease revealed the sequence of A(G,S,R)QXVPYG(A)V(P,L)SQ. The N-terminal sequence exhibited close similarity to the sequence of other proteases from Bacillus sp. A mass list of the monoisotopic peaks in the MALDI-TOF spectrum was searched after peptide fragmentation of the protease. Six peptide sequences exhibiting monoisotopic masses of 1,276.61, 1,513.67, 1,652.81, 1,661.83, 1,252.61, and 1,033.46 were observed from the fragmented protease. These monisotopic masses corresponded to the lytic enzyme L27 from Bacillus subtilis 168, and the Mowse score was found to be 75. A doubly charged Top product (MS) at a m/z of 517.3 exhibiting a molecular mass of 1034.6 was further analyzed by de novo sequencing using a PE Sciex QSTAR Hybrid Quadropole-TOF (MS/MS) mass spectrometer. MS/MS spectra of the Top product (MS) at a m/z of 517.3 obtained from the fragmented peptide mixture of protease with Q-star contained the b-ion series of 114.2, 171.2, 286.2, 357.2, 504.2, 667.4, 830.1, and 887.1 and y-ion series of 147.5, 204.2, 367.2, 530.3, 677.4, 748.4, 863.4, and 920.5. The sequence of analyzed peptide ion was identified as LGDAFYYG from the b- and y-ion series by de novo sequencing and corresponded to the results from the MALDI-TOF spectrum. From these results the extracellular protease from Bacillus subtilis KCCM 10257 was successfully identified with the lytic enzyme L27 from Bacillus subtilis 168.