• Title/Summary/Keyword: SPAN-TWEEN surfactants

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Study on the Absorption Rate of Ascorbic Acid with Span and Tween (Span과 Tween이 Ascorbic Acid의 흡수효율(吸收效率)에 미치는 영향(影響))

  • Kim, Chun-Kyu
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.11 no.4
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    • pp.43-46
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    • 1982
  • The purpose of this paper was to study the effect of surfactants on the absorption and the bioavailability of ascorbic acid in the small intestine of rats and rabbits absorption of ascorbic acid in small intestine of rats was increased with tween 80 and span 80.The blood level of ascorbic acid in rabbits was elevated by combined with low concentration of surfactants but high concentration of surfactants. The bioavailability of ascorbic acid was increased by simultaneous administration of surfactants.

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Combined Effect of Lidocaine Hydrochloride with Some Surfactants ( I ) (유화제(乳化劑)와 Lidocaine.HCl의 병용효과에 관(關)한 연구(硏究)( I ))

  • Kim, Yong-Hyoun;Yeum, Chul-Ho;Choi, Jun-Shik
    • Journal of Pharmaceutical Investigation
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    • v.12 no.2
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    • pp.31-36
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    • 1982
  • The effect of some surfactants, such as tween 40, tween 80, span 80, and triethanolamine, on the absorption of lidocaine was studied using goldfish as a model of absorption kinetics. This model was believed that reciprocal overturn time and death time were the occurrence of biological effect versus drug absorption. The results were as follows; The threshold concentration of lidocaine was significantly reduced by the surfactants. Overturn time and death time of goldfish in the lidocaine solution were reduced by such surfactants as tween 40, tween 80, span 80 and triethanolamine, and more reduced with increasing concentration of surfactants except tween 40 and tween 80. The plots of reciprocal death time versus lidocaine concentration were linear relationship with a positive concentration intercept such as minimum effective concentration (0.2-0.8%). As results it is believed that these surfactants may form complexes with lidocaine or affect the goldfish membrane to make more permeable to lidocaine, which is adsorbed more rapidly.

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Effects of HLB value on oil-in-water emulsions: Droplet size, rheological behavior, zeta-potential, and creaming index

  • Hong, In Kwon;Kim, Su In;Lee, Seung Bum
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.123-131
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    • 2018
  • Using mixed nonionic surfactants Span/Tween, we investigated the effects of HLB value on the O/W emulsion stability and rheological behaviors. In this study, MS-01 (Span 60 & Tween 60) and MS-02 (Span 80 & Tween 80) was used as mixed nonionic surfactants. We considered required HLB value 10.85 and selected corresponding HLB value range 8-13. The droplet size distributions, droplet morphology, rheological properties, zeta-potential and creaming index of the emulsion samples were obtained to understand the mechanism and interaction of droplets in O/W emulsion. The results indicated that optimal HLB number for O/W emulsions was 10.8 and 10.7, while using MS-01 surfactant and MS-02 surfactant respectively. MS-01 (HLB = 10.8) sample and MS-02 (HLB = 10.7) sample showed smallest droplet size and highest zeta-potential value. Rheological properties are measured to understand rheological behaviors of emulsion samples. All emulsion samples showed no phase separation until 30 days storage time at $25^{\circ}C$.

Effect of Nonionic Surfactant Solutions on Wetting and Absorbancy of PET Fabric 1. Mixtures and Dilutions of Span 20 and Tween 20 (비이온계 계면활성제 수용액이 PET직물의 습윤특성에 미치는 영향 제1보 : Span 20과 Tween 20의 혼합계와 희석계)

  • 김천희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.27 no.9_10
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    • pp.1153-1159
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    • 2003
  • The effects of changing aqueous solution properties by nonionic surfactants on wetting behavior and water retention properies of hydrophobic PET (polyethylene terephthalate) fabric were reported. The aqueous solution properties were diversified by mixing and diluting two nonionic surfactants, i.e., sorbitan monolaurate (Span 20) and polyoxyethylene(20) sorbitan monolaurate (Tween 20). The surface wetting properties ($cos{\theta}$) of PET fabric were greatly improved by adding $10^{-1}g/dl$ Tween 20 and further improved by mixing Span 20 to the system. The water retention properties (W) of PET fabric were also greatly increased by addition of $10^{-1}g/dl$ Tween 20. In diluted surfactant systems, the $cos{\theta}'s$ were increased with decreasing surface tension of aqueous liquids. The ratios of aqueous liquid retained in the pore structure to liquid retention capacity (W/H) were also increased with decreasing surface tension, however, W/H values were dramatically increased right after critical micelle concentration (cmc). The existence of micelles was important for the retention of aqueous liquids in the fabric. The critical surface tension of PET fabric used was found to be 28.7dyne/cm.

A Study on the Stabilization of Asphalt Emulsion with Phase Inversion Emulsification Method (반전유화법에 의한 유화아스팔트의 안정성 연구)

  • Heo, Woo-Sung;Lee, Eun-Kyoung;Choi, Sei-Young
    • Elastomers and Composites
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    • v.44 no.2
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    • pp.143-149
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    • 2009
  • In this study, asphalt emulsion was manufactured by phase inversion emulsification method with nonionic surfactants(Span 80, Span 60, Tween 80, and Tween 60), anionic surfactant(SLS) and cationic surfactant(Imidazole) in different feeding ratio to make up for the week points of asphalt. Its stabilization was carefully investigated with respect to droplet size, viscosity, zeta potential, and water-proofing property. When the surfactants mixed with nonionic and anionic surfactant were used into the asphalt, a stabilization of the asphalt emulsion was good. As the amount of the mixed surfactant was increased, the droplet size of asphalt emulsion were decreased, while the viscosity and zeta potential were increased. When the surfactants mixed with nonionic and anionic surfactant were used into the asphalt, a stabilization of asphalt emulsion was good.

Detergency and Soil Redeposition of Wool Fabric in Eco-friendly Drycleaning Solvent(Decamethylcyclopentasiloxane) (친환경 실리콘계 드라이클리닝용제(Decamethylcyclopentasiloxane)에서 모직물의 세척성과 재오염성)

  • Kim, Chun-Hee
    • Textile Coloration and Finishing
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    • v.24 no.2
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    • pp.138-144
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    • 2012
  • Detergency and soil redeposition of wool fabric in 8 nonionic surfactants (Span 20, 40, 60, 80/Tween 20, 40, 60, 80) and 4 solvents (water, petroleum, perchloroethylene(PCE), decamethylcyclopentasiloxane($D_5$)) were studied. Detergency of wool fabric in water was very low with and without surfactants due to the low wetting and difficulty in penetration of water into the fabric. Lipophilic surfactants improved the detergency of wool fabric in petroleum solvent and PCE. The detergency of wool fabric in $D_5$ was similar to that in petroleum solvent without surfactants. When water was solubilized, Span 20 addition to petroleum solvent and PCE increased the detergency of wool fabric. The detergency for $D_5$ was improved with solubilized water, however, it was lowered when the surfactants were added to the system. Therefore, it is important to formulate appropriate detergents which have good solubility and affinity to silicone for $D_5$ charge system. Hydrophilic surfactants were effective for water and lipophilic surfactants were effective for petroleum solvent and PCE in soil redeposition prevention of wool fabric. The soil redeposition prevention effects are not found in $D_5$ with both Span 20 and Tween 20. The same tendency of results in soil redeposition of wool fabric is observed when water is solubilized.

Molecular Area and Interfacial Tension Behavior of Span 20 and Tween series surfactants at water/air interface (Span 20과 Tween계 계면활성제의 물/공기 계면에서의 분자면적과 계면장력 거동)

  • 김천희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.7
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    • pp.1065-1072
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    • 2000
  • The molecular areas and the interfacial tension behavior of ten nonionic surfactants, i.e., Span 20 and Tween 20, 40, 60. 80, 21, 61, 81, 65, & 85 are tested to assay their effects on the wetting and liquid retention properties of hydrophilic and hydrophobic fibrous materials. The molecular areas at water/air interface are derived from Gibbs’adsorption equations. The following conclusions are drawn from the results: 1) Span 20 is efficient in lowering the interfacial tension and effective in adsorption at the water/air interface, resulting in the low interfacial tension at critical micelle concentration (${\gamma}$$_{CMC}$) and a small molecular area($\omega$), 2) when the hydrophiles of the surfactants are constant, $\omega$’s increase as hydrophobe carbon numbers of the surfactants increase, 3) when the hydrophobes are constant, ${\gamma}$$_{CMC}$’s and $\omega$’s increase as the hydrophile ethylene oxide units increase, indicating effectiveness and efficiency is parallel in this case, 4) the ethylene oxide unit length as a hydrophile has greater influence on u than the hydrophobe chain length.han the hydrophobe chain length.gth.

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Detergency and Liquid Wetting/Retention Properties of Soiled Polyester/Cotton(65/35) Cloth in Nonionic Surfactant Solutions (비이온계 계면활성제 수용액에서 Polyester/Cotton(65/35) 오염포의 습윤특성과 세척성)

  • Kim, Chun-Hee
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.140-145
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    • 2011
  • The effects of nonionic surfactant solutions of 0.1g/dL on detergency and liquid wetting/retention properties of soiled polyester/cotton(65/35) cloth were studied. Soiled polyester/cotton(65/35) cloth (EMPA 104) and 10 different nonionic surfactants (Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, 85) were used in the study. The water retention and liquid retention capacity values of soiled cloth were decreased compared with those of unsoiled cloth. The wetting and water retention of soiled cloth improved with addition of surfactants, whereas water retention ratio(W/H) values didnot change markedly. Generally surfactants with low surface tension and high HLB (Hydrophile-lipophile balance) were more effective in improving the wetting/retention properties of soiled cloth. Nonionic surfactants having high ethylene oxide contents of 20 moles; i.e., Tween 20, 40, 60 & 80, showed better detergency than low ethylene oxide contents of 4 moles; i.e., Tween 21, 61 & 81. As HLB values of surfactants and $cos{\theta}$ of the soiled cloth increase, the detergency values of soiled cloth increased.

Detergency and Water Wetting/Retention Properties of Soiled Cotton Cloths in Nonionic Surfactant Solutions (비이온계 계면활성제 수용액에서 면 오염포의 습윤특성과 세척성)

  • Kim, Chun-Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.3 s.162
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    • pp.433-439
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    • 2007
  • The effects of nonionic surfactants on detergency and water wetting/retention properties of soiled cotton cloths were reported. Two different soiled cloths were used. soiled cotton cloth 1 was made in the lab. with carbon black, tripalmitin, n-dodecane & palmitic acid on Korea Apparel Testing & Research Institute(KATRI) cotton testcloth and soiled cotton cloth 2(EMPA 101) was purchased from Testfabrics, Inc., USA. The following nonionic surfactants; l.e., Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, & 85, were used in the study. The water retention ratio(W/H) values of soiled cotton cloths were decreased, whereas the water contact angle values of soiled cloth were not changed markedly compared with those of unsoiled testcloths. The wetting and water retention of soiled cotton cloth 1 was improved with addition of nonoinic surfactants. The surfactants which have more hydrophilic characterictics or unsaturated hydrophobe tails were effective in improving wetting and water retention properties of soiled cotton cloth 1. The water contact angle values of soiled cotton cloths were extremely low with Span 20, presumably due to the high adsorption density or the surfactant. The detergency of soiled cloths were low in Span 20 and high in Tween 20, 40, 60 & 80 0.1g/dl surfactant solutions. Nonionic surfactants having higher ethylene oxide contents resulted in better detergency. In the range studied, the wetting and water retention of soiled cotton cloths did not show any particular relation to the detergency, whereas the surfactant characteristics, especially HLB values, influenced the detergency of soiled cotton cloths.

Synergistic Effects of UV Absorbance of Nanoemulsions Formed with Organic UV filters and Wax (유기자외선차단제와 왁스를 함유한 나노에멀젼의 자외선 흡광도의 상승효과)

  • Cho, Wan Goo;Cha, Young Kweon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.41 no.1
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    • pp.57-62
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    • 2015
  • In this study, we investigated the effect on the increase of UV absorbance using a o/w nanoemulsion containing a blend of surfactants (Tween 80 and Span 80), an organic sunscreen, and wax. The particle size of nanoemulsion produced by PIC (Phase Inversion Composition), in Tween 80/Span 80 system containing candelilla wax was below 50 nm. As the concentration of Tween 80/Span 80/candelilla wax/organic UV filter was fixed at 4.5/0.5/3.0/2.0 wt%, and various organic sunscreens were added to the system, stable nanoemulsion was produced by Parsol MCX and Escalol 587, respectively. In addition, in the same system, when the ratio of Parsol MCX and candelilla wax was less than 2.0, a stable nanoemulsion was obtained. UV absorbance showed a high synergistic effect when Parsol MCX was used with candelilla wax.