• Journal of Korean Society of Environmental Engineers
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• v.22 no.4
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• pp.671-678
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• 2000

Reaction characteristics of simultaneous removal of SOx and NOx have been investigated in a thermogravimetric analyzer and tubular fixed bed reactor using the $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst. Sulfur removal capacity of $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst is largely enhanced above both the temperature of $450^{\circ}C$ and the loading of 6wt% due to the participation of alumina support in a sulfation reaction. The NO reduction efficiency of 8wt% $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst shows the maximum value at $370^{\circ}C$ and then decreases with the increase of reaction temperature due to the oxidation of $NH_3$ gas. The presence of sulfate on the surface of sorbent/catalyst enhances the optimum reaction temperature showing the maximum deNOx efficiency. In the simultaneous removal of SOx and NOx at $250^{\circ}C$. deNOx activity of $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst is rapidly decreased due to the formation of ammonium salts such as $NH_4HSO_4$. In the simultaneous removal reaction of SOx and NOx, the optimum temperature showing the maximum deNOx efficiency increases to $400^{\circ}C$ due to the presence of $SO_2$ gas.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1996.10b
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• pp.81-84
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• 1996

• Clean Technology
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• v.16 no.4
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• pp.254-257
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• 2010

[ $Mg(OH)_2$ ]slurry was prepared by using natural mineral brucite exploited from Liaoning province in China, and its de-SOx efficiency was examined. The effect of difference in particle size distribution of brucite and activation by hydrothermal treatment were investigated. The de-$SO_2$ efficiency of a finely-milled brucite sample below 1000 mesh with narrow particle size distribution was higher than that of the sample below 80 mesh. On the other hand, the de-$SO_2$ efficiency of brucite sample below 80 meshes was significantly improved by the hydrothermal treatment at 363 K tor 3 h.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1995.11a
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• pp.38-41
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• 1995

화석연료의 연소에 의하여 방출되는 SO$_2$ 와 NO 에 의한 대기오염의 심각성은 이미 잘 알려져 있으며 그에 따른 배출규제 또한 강화되고 있다. 최근에는 탈황과 탈질을 동시에 처리하는 동시 탈황탈질 공정의 연구가 진행되고 있다. 동시제거 공정은 주로 흡수제/촉매를 토대로 개발되고 있으며 산화구리가 담지된 알루미나 (CuO/${\gamma}$-A1$_2$O$_3$) 흡수제/촉매는 SOx, NOx 동시제거에 효과적인 물질로 알려져 있다. 담지된 CuO 와 담체 A1$_2$O$_3$는 SO$_2$ 와 $O_2$ 존재하에 반응하여 CuSO$_4$ 와 $Al_2$(SO$_4$)$_3$ 가되며 [1] CuSO$_4$ 와 미반응된 CuO 는 NO 제거를 위한 촉매로서의 역할을 하게 된다 [2].

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.6
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• pp.672-680
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• 2011

Three new granular absorbents were prepared from calcium hydroxide, and applied to an FGD process with internal circulation. The aim of the study was finding the most efficient of the these three applied absorbents for the $SO_2$ removal at high flue gas temperatures. The absorbent is fed to the testing unit at high operation temperature and fluidized inside the FGD system where the sorbent particles react with the $SO_2$ gas. The rate of $SO_2$ decomposition was high in C-type absorbent which had the large surface area. De-SOx characteristics of the current absorbents appeared to be similar to the other conventional agents in this fluidized bed combustor. In particular, the optimum de-SOx condition could be achieved at high mole ratios of Ca to S which can reduce the residual $SO_2$.

• Resources Recycling
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• v.25 no.5
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• pp.44-49
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• 2016

Flue gas desulfurization(FGD) is an effective technique to remove $SO_2$ gases of coal-fired plants. Limestone is usually used as desulfurizing agent. In this study, we use the limestone sludge which is a by-product of steel industry in order to replace desulfurizing agent of FGD process. Physical and chemical characteristics analysis of desulfurizing agent was conducted. Desulfurizing agent using limestone sludge was fabricated by pre-treatment process and, then the agent was used on FGD process. Consequently, the tendency on the $SO_2$ concentration did not appear. And limestone sludge was considered as possible alternative agent for flue gas desulfurization process through absorber control system.