• Title/Summary/Keyword: SI7

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CharacteristicProperties of Low-k Thin Film Deposited by Sputtering (스퍼터링에 의한 Low-k 박막의 특성)

  • Oh, Teresa
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.7
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    • pp.3160-3164
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    • 2012
  • To obtain available process at low temperature, SiOC thin film was prepared with various flow rates by using the rf magnetron sputtering, and AZO thin film was also deposited on SiOC film by rf magnetron sputtering system. The optical electrical properties of the SiOC film and SiOC/AZO were analyzed by the uv visible spectrometer and PL spectra. SiOC film on n type Si showed various type emission according to the deposition condition. The SiOC film showed the blue shift with increasing the thickness in PL spectra. AZO/SiOC/Si film had a broad emission characteristic, which is enhanced the efficiency in solar cell.

Thermostability of Monolithic and Reinforced Al-Fe-V-Si Materials

  • He, Yiqiang;Qiao, Bin;Wang, Na;Yang, Jianming;Xu, Zhengkun;Chen, Zhenhua;Chen, Zhigang
    • Advanced Composite Materials
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    • v.18 no.4
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    • pp.339-350
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    • 2009
  • Al-Fe-V-Si alloys reinforced with SiC particles were prepared by multi-layer spray deposition technique. Both microstructures and mechanical properties including hardness and tensile properties development during hot exposure process of Al-8.5Fe-1.3V-1.7Si, Al-8.5Fe-1.3V-1.7Si/15 vol% $SiC_P$ and Al-10.0Fe-1.3V-2Si/15 vol% $SiC_P$ were investigated. The experimental results showed that an amorphous interface of about 3 nm in thickness formed between SiC particles and the matrix. SiC particles injected silicon into the matrix; thus an elevated silicon concentration was found around $\alpha-Al_{12}(Fe,\;V)_3Si$ dispersoids, which subsequently inhibited the coarsening and decomposition of $\alpha-Al_{12}(Fe,\;V)_3Si$ dispersoids and enhanced the thermostability of the alloy matrix. Moreover, the thermostability of microstructure and mechanical properties of Al-10.0Fe-1.3V-2Si/15 vol% $SiC_P$ are of higher quality than those of Al-8.5Fe-1.3V-1.7Si/15 vol% $SiC_P$.

Local Work-function Variation of the Initial Oxidation-Stages of Si(111)-7${\times}$7 (Si(111)-7${\times}$7 표면의 초기산화 단계에서의 국부 일함수 변화)

  • Im, Sam-Ho;Gu, Se-Jeong;Kim, Gi-Jeong;Park, Chan;Seo, Jae-Myeong
    • Journal of the Korean Vacuum Society
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    • v.2 no.2
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    • pp.166-170
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    • 1993
  • In the initial stages of oxidation of Si(111)-7${\times}$7 held at 40K through exposing molecular oxygen, it has been detected average work-function measured by ultraviolet photoelectron spectroscopy (UPS) is about 0.4eV higher than the local work-function of the modified area measured by photoemission for adsorbed Xenon (PAX). This result indicates that the increment of work-function at the initial oxidation stages of Si(111)-7${\times}$7 is mainly due to the moleculary adsorbed oxygen. From the shift of broadened Xe 5p and Xe 3d, it has also been estimated that the work-function of the modified area is 0.6eV higher than that of the clean area.

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Coexistence of quasi-1D ($7{\times}7$) and ($5{\times}5$) phases on vicinal Si(557) surfaces

  • Kim, Min-Kook;Oh, Dong-Hwa;Baik, Jae-Yoon;Jeon, Cheol-Ho;Park, Chong-Yun;Ahn, Joung-Real
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.361-361
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    • 2010
  • The separated quasi-one-dimensional ($7{\times}7$) and ($5{\times}5$) phases on vicinal Si(557) surfaces were successfully realized by changing the crystallographic orientation and thermal treatment conditions. A small change in the crystallographic orientation of the Si(557) surface stabilized the quasi-one-dimensional ($5{\times}5$) phase of a (111) facet on vicinal Si(557) surfaces and made it coexist with a quasi-one-dimensional ($7{\times}7$) phase after an optimal thermal treatment, whereas only the quasi-one-dimensional ($7{\times}7$) phase was stable on the Si(557) surface. Interestingly, this causes the (111) terraces with different widths (L) to prefer only one of the $5{\times}5$ (L=12) and $7{\times}7$ (L=9) phases resulting in long-range order of both phases along the step edge direction, which was observed by scanning tunneling microscopy (STM) and was supported by first principle calculations. In contrast, the quasi-one-dimensional ($5{\times}5$ and ($7{\times}7$) phases were arranged randomly across the step edge direction. The change of surface morphology of vicinal Si(557) surfaces will be discussed with STM images and theoretical calculations by changing crystallographic cutting angles and thermal treatment conditions.

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Synthesis and Luminescent Characterization of Eu2+/Dy3+-Doped Sr2MgSi2O7 Powders (Eu2+/Dy3+ 이온이 도핑된 Sr2MgSi2O7 분말 합성 및 발광 특성)

  • Park, Jaehan;Kim, Young Jin
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.658-662
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    • 2014
  • $Eu^{2+}/Dy^{3+}$-doped $Sr_2MgSi_2O_7$ powders were synthesized using a solid-state reaction method with flux ($NH_4Cl$). The broad photoluminescence (PL) excitation spectra of $Sr_2MgSi_2O_7:Eu^{2+}$ were assigned to the $4f^7-4f^65d$ transition of the $Eu^{2+}$ ions, showing strong intensities in the range of 375 to 425 nm. A single emission band was observed at 470 nm, which was the result of two overlapping subbands at 468 and 507 nm owing to Eu(I) and Eu(II) sites. The strongest emission intensity of $Sr_2MgSi_2O_7:Eu^{2+}$ was obtained at the Eu concentration of 3 mol%. This concentration quenching mechanism was attributable to dipole-dipole interaction. The $Ba^{2+}$ substitution for $Sr^{2+}$ caused a blue-shift of the emission band; this behavior was discussed by considering the differences in ionic size and covalence between $Ba^{2+}$ and $Sr^{2+}$. The effects of the Eu/Dy ratios on the phosphorescence of $Sr_2MgSi_2O_7:Eu^{2+}/Dy^{3+}$ were investigated by measuring the decay time; the longest afterglow was obtained for $0.01Eu^{2+}/0.03Dy^{3+}$.

A Study on the Development for the Vehicle Engine Mountion Bracket Using Squeeze Casting (스퀴즈 캐스팅 제조법에 의한 자동차 엔진 마운틴 브래킷 개발에 관한 연구)

  • Kim, S.H.
    • Journal of Power System Engineering
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    • v.7 no.4
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    • pp.44-48
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C)alloy fabricated by squeeze casting process for development of Engine Mountain Bracket. The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy revealed 2985MPa. It was found that Al-7.0Si-0.4Mg alloy have good aging hardening effect results are presented to show the validity of the control method.

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Differences in Cold Rolling Workability and Mechanical Properties between Al-Mg-Si and Al-Mg-Zn System Alloys with Cold Rolling (냉간압연가공에 따른 Al-5.5Mg-2.9Si계와 Al-7Mg-0.9Zn계 합금의 압연가공성 및 기계적 특성 차이)

  • Yang, Ji-Hun;Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.26 no.11
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    • pp.628-634
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    • 2016
  • The cold rolling workability and mechanical properties of two new alloys, designed and cast Al-5.5Mg-2.9Si and Al-7Mg-0.9Zn alloys, were investigated in detail. The two alloy sheets of 4 mm thickness, 30 mm width and 100 mm length were reduced to a thickness of 1 mm by multi-pass rolling at ambient temperature. The rolling workability was better for the Al-7Mg-0.9Zn alloy than for the Al-5.5Mg-2.9Si alloy; in case of the former alloy, edge cracks began to occur at 50% rolling reduction, and their number and length increased with rolling reduction; however, in the latter alloy, the sheets did not have any cracks even at higher rolling reduction. The mechanical properties of tensile strength and elongation were also better in the Al-7Mg-0.9Zn alloy than in Al-5.5Mg-2.9Si alloy. Work hardening ability after cold rolling was also higher in the Al-7Mg-0.9Zn alloy than in the Al-5.5Mg-2.9Si alloy. At the same time, the texture development was very similar for both alloys; typical rolling texture developed in both alloys. These differences in the two alloys can primarily be explained by the existence of precipitates of $Mg_2Si$. It is concluded that the Al-7Mg-0.9Zn alloy is better than the Al-5.5Mg-2.9Si alloy in terms of mechanical properties.

Effect of $\alpha-SiC $seed on microstructure and fracture toughness of pressureless-sintered $\beta-SiC$ ($\alpha-SiC $seed의 첨가가 상압소결된 $\beta-SiC$의 미세구조와 파괴인성에 미치는 영향)

  • Young-Wook Kim;Won-Joong Kim;Kyeong-Sik Cho;Heon -Jin Choi
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.18-26
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    • 1997
  • $\beta-SiC $powder with or without the addition of 1 wt% of $\alpha-SiC$ particles (seeds) was pressureless-sintered at $1950^{\circ}C$ for 0.5, 2 and 4 h using $Y_3Al_5O_{12}$ (yttrium aluminum garnet, YAG) as a sintering aid. The introduction of $\alpha-SiC$ seeds into $\beta-SiC$ accelerated :he grain growth of elongated large grains during sintering, resulting in the coarser microstructure. The fracture toughnesses of materials with $\alpha$-SiC seeds and without $\alpha-SiC$ seeds sintered for 4 h were 7.5 and 6.1 $MPa\cdot \textrm m^{1/2}$, respectively. Higher fracture toughness of the material with seeds was due to the enhanced bridging by elongated grains, resulting from coarser microstructure.

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Construction of RHEED Apparatus and Study on K, Cs/Si)(111) System (RHEED 장치의 제작과 K, Cs/Si(111)계에 관한 연구)

  • 이경원;안기석;강건아;박종윤;이순보
    • Journal of the Korean Vacuum Society
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    • v.1 no.1
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    • pp.43-49
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    • 1992
  • RHEED apparatus which is one of the systems of surface structure analysis has been constructed.Electron beam is focused by means of magnetic lens, and the beam divergence is about $1{\times}10^{-3}$ rad. The Acceleration voltage of this RHEED apparatus is continuously variable from 0 to 20 kV. K and Cs-adsorbed structureson Si(111)$7{\times}7$ surface at room and high temperatures($200{\times}700^{\circ}C$) have been investigated by RHEED. It is observed that the K and Cs-adsorbed Si(111)surface structures at saturation coverage are Si(111)$7{\tiems}7-K$ and Si(111)$1{\tiems}1-Cs$ at room temperature, respectively. When the specimen temperature was elevated during evaporation,the $3{\times}1$ structure appears in the range of temperature between $300^{\circ}C$ and $550^{\circ}C$, and the $1{\tiems}1$ structure appears above $550^{\circ}C$ in K/Si(111)system. Also, in Cs/Si(111) system the $\sqrt{3}{\times}\sqrt{3}$ structure appears at $300^{\circ}C$, and the $\sqrt{3}{\times}\sqrt{3}+3{\times}1$ structure appears between $350^{\circ}C$ and $400^{\circ}C$.

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Effect of Pd addition on nickel silicide : ab initio calculation (Nickel silicide에 대한 Pd 첨가 효과 : ab initio 계산)

  • Kim, Dae-Hee;Seo, Hwa-Il;Kim, Yeong-Cheol
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.1
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    • pp.7-10
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    • 2008
  • Effect of Pd addition on crystal structures of two nickel silicides, NiSi and $NiSi_2$, is investigated by using an ab initio calculation. A Pd atom substitutes a Ni and Si site, respectively, to evaluate the preferable site between them. Pd prefers Ni site to Si site in NiSi, while it prefers Si site to Ni site in $NiSi_2$. The calculated total energy also indicates that the Pd substitution to Si site stabilizes the $NiSi_2$ structure. This calculated data matches well with the experimental data obtained from Atom probe.

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