• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.08a
• /
• pp.304-304
• /
• 2010

The study on the catalytic oxidation of carbon monoxide (CO) to carbon dioxide ($CO_2$) using the noble metals has long been the interest subject and the recent progress in nanoscience provides the opportunity to develop new model systems of catalysts in this field. Of the noble metal catalysts, we selected ruthenium (Ru) as metal catalyst due to its unusual catalytic behavior. The size of colloid Ru NPs was controlled by the concentration of Ru precursor and the final reduction temperatures. For catalytic activity of CO oxidation, it was found that the trend is dependent on the size of Ru NPs. In order to explain this trend, the surface oxide layer surrounding the metal core has been suggested as the catalytically active species through several studies. In this poster, we show the influence of surface oxide on Ru NPs on the catalytic activity of CO oxidation using chemical treatments including oxidation, reduction and UV-Ozone surface treatment. The changes occurring to UV-Ozone surface treatment will be characterized with XPS and SEM. The catalytic activity before and after the chemical modification were measured. We discuss the trend of catalytic activity in light of the formation of core-shell type oxide on nanoparticles surfaces.

• Steel and Composite Structures
• /
• v.33 no.1
• /
• pp.19-36
• /
• 2019

Cyclic behaviour of composite (steel-concrete) plate shear walls (CPSW) with variable column flexural stiffness is experimentally and numerically investigated. The investigation included design, fabrication and testing of three pairs of one-bay one-storey CPSW specimens. The reference specimen pair was designed in way that its column flexural stiffness corresponds to the value required by the design codes, while within the other two specimen pairs column flexural stiffness was reduced by 18% and 36%, respectively. Specimens were subjected to quasi-static cyclic tests. Obtained results indicate that column flexural stiffness reduction in CPSW does not have negative impact on the overall behaviour allowing for satisfactory performance for up to 4% storey drift ratio while also enabling inelastic buckling of the infill steel plate. Additionally, in comparison to similar steel plate shear wall (SPSW) specimens, column "pull-in" deformations are less pronounced within CPSW specimens. Therefore, the results indicate that prescribed minimal column flexural stiffness value used for CPSW might be conservative, and can additionally be reduced when compared to the prescribed value for SPSWs. Furthermore, finite element (FE) pushover simulations were conducted using shell and solid elements. Such FE models can adequately simulate cyclic behaviour of CPSW and as such could be further used for numerical parametric analyses. It is necessary to mention that the implemented pushover FE models were not able to adequately reproduce column "pull-in" deformation and that further development of FE simulations is required where cyclic loading of the shear walls needs to be simulated.

• Steel and Composite Structures
• /
• v.33 no.1
• /
• pp.111-122
• /
• 2019

This paper presents an experimental work on the post-fire behavior of two kinds of innovative composite stub columns under eccentric compression. The partially precast steel reinforced concrete (PPSRC) column is composed of a precast outer-part cast using steel fiber reinforced reactive powder concrete (RPC) and a cast-in-place inner-part cast using conventional concrete. Based on the PPSRC column, the hollow precast steel reinforced concrete (HPSRC) column has a hollow column core. With the aim to investigate the post-fire performance of these composite columns, six stub column specimens, including three HPSRC stub columns and three PPSRC stub columns, were exposed to the ISO834 standard fire. Then, the cooling specimens and a control specimen unexposed to fire were eccentrically loaded to explore the residual capacity. The test parameters include the section shape, concrete strength of inner-part, eccentricity ratio and heating time. The test results indicated that the precast RPC shell could effectively confine the steel shape and longitudinal reinforcements after fire, and the PPSRC stub columns experienced lower core temperature in fire and exhibited higher post-fire residual strength as compared with the HPSRC stub columns due to the insulating effect of core concrete. The residual capacity increased with the increasing of inner concrete strength and with the decreasing of heating time and load eccentricity. Based on the test results, a FEA model was established to simulate the temperature field of test specimens, and the predicted results agreed well with the test results.

• Computers and Concrete
• /
• v.21 no.6
• /
• pp.717-726
• /
• 2018

Concrete pipelines are the most efficient and safe means for gas and oil transportation over a long distance. The use of nano materials and nono-engineering can be considered for enhancing concrete pipelines properties. the tests show that $SiO_2$ nanoparticles can improve the mechanical behavior of concrete. Moreover, severe hazard for pipelines is seismic ground motion. Over the years, scientists have attempted to understand pipe behavior against earthquake most frequently via numerical modeling and simulation. Therefore, in this paper, the dynamic response of underwater nanocomposite submerged pipeline conveying fluid is studied. The structure is subjected to the dynamic loads caused by earthquake and the governing equations of the system are derived using mathematical model via Classic shell theory and Hamilton's principle. Navier-Stokes equation is employed to calculate the force due to the fluid in the pipe. As well, the effect of external fluid is modeled with an external force. Mori-Tanaka approach is used to estimate the equivalent material properties of the nanocomposite. 1978 Tabas earthquake in Iran is considered for modelling seismic load. The dynamic displacement of the structure is extracted using differential quadrature method (DQM) and Newmark method. The effects of different parameters such as $SiO_2$ nanoparticles volume percent, boundary conditions, thickness to radius ratios, length to radius ratios, internal and external fluid pressure and earthquake intensity are discussed on the seismic response of the structure. From results obtained in this paper, it can be found that the dynamic response of the pipe is increased in the presence of internal and external fluid. Furthermore, the use of $SiO_2$ nanoparticles in concrete pipeline reduces the displacement of the structure during an earthquake.

• Computers and Concrete
• /
• v.24 no.2
• /
• pp.125-135
• /
• 2019

Concrete pipelines are the most efficient and safe means for gas and oil transportation over a long distance. The use of nano materials and nono-engineering can be considered for enhancing concrete pipelines properties. the tests show that SiO2 nanoparticles can improve the mechanical behavior of concrete. Moreover, severe hazard for pipelines is seismic ground motion. Over the years, scientists have attempted to understand pipe behavior against earthquake most frequently via numerical modeling and simulation. Therefore, in this paper, the dynamic response of underwater nanocomposite submerged pipeline conveying fluid is studied. The structure is subjected to the dynamic loads caused by earthquake and the governing equations of the system are derived using mathematical model via Classic shell theory and Hamilton's principle. Navier-Stokes equation is employed to calculate the force due to the fluid in the pipe. As well, the effect of external fluid is modeled with an external force. Mori-Tanaka approach is used to estimate the equivalent material properties of the nanocomposite. 1978 Tabas earthquake in Iran is considered for modelling seismic load. The dynamic displacement of the structure is extracted using differential quadrature method (DQM) and Newmark method. The effects of different parameters such as SiO2 nanoparticles volume percent, boundary conditions, thickness to radius ratios, length to radius ratios, internal and external fluid pressure and earthquake intensity are discussed on the seismic response of the structure. From results obtained in this paper, it can be found that the dynamic response of the pipe is increased in the presence of internal and external fluid. Furthermore, the use of SiO2 nanoparticles in concrete pipeline reduces the displacement of the structure during an earthquake.

• Journal of the Architectural Institute of Korea Structure & Construction
• /
• v.34 no.2
• /
• pp.19-28
• /
• 2018

The progressive collapse resistance performance of a steel structure constructed using the moment frame with the WUF-B connection and the composite slabs was evaluated. GSA 2003 was adapted for the evaluation. Additionally the structural robustness and the sensitivity against the progressive collapse were analyzed. In the numerical analysis, a reduced model comprised of the beam and spring elements for WUF-B connection was adapted. The composite slab was modeled using the composite-shell element. Instead of the time-consuming dynamic analysis for the effect of the sudden column removal, the equivalent energy-based static analysis was effectively applied. The analysis results showed that the structure was the most vulnerable to in the case of the internal column removal, however it satisfied the chord rotation criterion of GSA 2003 due to the contribution of the composite slab which improved the stiffness of structure. In the robustness evaluation, the structural performance showed more than 2.5 times of the requirement according to GSA 2003, and the structural sensitivity analysis indicated the decrease of 33% of the initial structural performance.

• Structural Engineering and Mechanics
• /
• v.85 no.1
• /
• pp.105-118
• /
• 2023

The present work is an attempt to develop a simple and accurate finite element formulation for the assessment of thermal shock/thermally induced vibrations in pretwisted and tapered functionally graded material thin (FGM) blades obtained from Voigt and local representative volume elements (LRVE) homogenization models, based on neutral surface approach. The neutral surface of the FGM blade does not coincide with its mid-surface. A finite element model (FEM) is developed using first-order shear deformation theory (FSDT) and the FGM turbine blade is modelled according to the shallow shell theory. The top and the bottom layers of the FGM blade are made of pure ceramic and pure metal, respectively and temperature-dependent material properties are functionally graded in the thickness direction, the position of the neutral surface also depends on the temperature. The material properties are estimated according to two different homogenization models viz., Voigt or LRVE. The top layer of the FGM blade is subjected to high temperature and the bottom surface is either thermally insulated or kept at room temperature. The solution of the nonlinear profile of the temperature in the thickness direction is obtained from the Fourier law of heat conduction in the unsteady state. The results obtained from the present FEM are compared with the benchmark examples. Next, the effect of angle of twist, intensity of thermal shock, variable chord and span and volume fraction index on the transient response due to thermal shock obtained from the two homogenization models viz., Voigt and LRVE scheme is investigated. It is shown that there can be a significant difference in the transient response calculated by the two homogenization models for a particular set of material and geometric parameters.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.26 no.3A
• /
• pp.523-532
• /
• 2006

It is thought that the suggestion of efficient and rational design guideline based on the behavior evaluation of bridge structure system the included cross beam is necessary for the construction efficiency of two-I girder steel bridges. Therefore, in this study, the effects of influence parameters are investigated by the behavior analyses of the bridges, in which the influence parameters are location, spacing and rigidity of the cross beam. For this study, the existed two-I girder steel bridges firstly were selected with the model of case study and the FE analyses for some case models were performed to estimate the action of the cross beam in the bridge. From the analyses, it was estimated that if it consider local stress and load distribution of a floor system, shell and solid elements are compatible to modeling of the cross beams. Also, the efficient design guideline for the cross beam of two-I girder steel bridge was suggested from parameter studies used location, spacing and rigidity of the cross beam.

• Animal Bioscience
• /
• v.37 no.6
• /
• pp.1065-1076
• /
• 2024

Objective: This study aimed to assess the effects of dietary mulberry leaves on the growth, production performance, gut microbiota, and immunological parameters of poultry and livestock. Methods: The PubMed, Embase, and Scopus databases were systematically analyzed to identify pertinent studies up to December 2022. The effects of mulberry leaf diet was assessed using the weighted mean difference, and the 95% confidence interval was calculated using a random-effects model. Results: In total, 18 studies that sampled 2,335 poultry and livestock were selected for analysis. Mulberry leaves improved the average daily gain and reduced the feed/meat ratio in finishing pigs, and the average daily gain and average daily feed intake in chicken. In production performance, mulberry leaves lowered the half carcass weight, slaughter rate, and loin eye area in pigs, and the slaughter rate in chickens. Regarding meat quality in pigs, mulberry leaves reduced the cooked meat percentage, shear force, crude protein, and crude ash, and increased the 24 h pH and water content. In chickens, it increased the drip loss, shear force, 45 min and 24 h pH, crude protein, and crude ash. Mulberry leaves also affect the abundances of gut microbiota, including Bacteroides, Prevotella, Megamonas, Escherichia-Shigella, Butyricicoccus, unclassified Ruminococcaceae, Bifidobacterium, Lactobacillus, and Escherichia coli in poultry and livestock. Mulberry leaves at different doses were associated with changes in antioxidant capacity in chickens, and immune organ indexes in pigs. With respect to egg quality, mulberry leaves at different doses improved the shell strength, yolk color, eggshell thickness, and eggshell weight. However, moderate doses diminished the egg yolk ratio and the egg yolk moisture content. Conclusion: In general, dietary mulberry leaves improved the growth, production performance, and immunological parameters in poultry and livestock, although the effects varied at different doses.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.37 no.2
• /
• pp.133-141
• /
• 2024

Considering fluid-structure-soil interactions, a finite-element model for a liquid-storage tank is presented and the nonlinear earthquake response analysis is formulated. The tank structure is modeled considering shell elements with geometric and material nonlinearities. The fluid is represented by acoustic elements and combined with the structure using interface elements. To consider the soil-structure interactions, the near- and far-field regions of soil are modeled with solid elements and perfectly matched discrete layers, respectively. This approach is applied to the seismic fragility analysis of a 200,000 kL liquid-storage tank. The fragility curve is observed to be influenced by the amplification and filtering of rock outcrop motions at the site when the soil-structure interactions are considered.