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$TiO_2$ 기반 가시광 응답형 광촉매의 수소 생산

  • Choe, Jin-Yeong;Park, Won-Ung;Jeon, Jun-Hong;Mun, Seon-U;Im, Sang-Ho;Han, Seung-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.394-394
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    • 2011
  • 급속한 산업의 발달은 심각한 환경오염 및 에너지 문제를 가져왔다. 이를 해결하기 위하여 무한한 에너지원인 태양에너지를 원천으로 하는 친환경 정화소재로서의 광촉매(photocatalyst)를 통하여 인류의 에너지를 확보하는 것에 대한 관심이 급격하게 증가하고 있는 추세이다. 현재 광촉매로 가장 많이 사용되는 $TiO_2$의 경우 뛰어난 광활성과 저렴한 가격, 광 안정성, 화학적 안정성을 가짐에도 불구하고, 3.2 eV라는 상대적으로 넓은 band gap을 가지기 때문에 약 386 nm보다 짧은 파장을 갖는 자외선만 흡수할 수 있다. 이로 인한 가시광 응답성의 부재를 해결하기 위해 수십년간 많은 연구가 진행되어 왔다. 따라서 본 연구에서는 ICP assisted pulsed DC reactive magnetron sputtering을 이용하여 $TiO_2$를 기반으로 하면서 가시광영역의 빛을 흡수하여 높은 효율을 얻을 수 있도록 Nitrogen doping, Low band gap semi-conductor sensitization 등의 방법을 사용하여 광촉매를 제작하였다. 시료의 chemical state와 crystallinity를 확인하기 위하여 X-ray photoelectron spectroscopy와 X-ray diffraction method를 이용하여 분석을 수행하였으며, 이러한 공정을 통해 제작된 $TiO_2$기반 광촉매의 가시광 응답성을 확인하기 위하여 UV/Vis 스펙트럼을 측정하였다. 또한 물 분해 장치(water splitting device)를 제작하여 수소와 산소 생성시 흐르는 전류를 측정하여 광특성을 평가하였다.

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The EFFECTS OF DENTAL LASER ON PULP FIBROBLAST IN VITRO (치과용 레이저 조사가 배양 치수 섬유모세포에 미치는 영향에 관한 연구)

  • Jeong, Hye-Jeon;Min, Byung-Soon
    • Restorative Dentistry and Endodontics
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    • v.22 no.2
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    • pp.519-535
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    • 1997
  • The responses of human pulp fibroblastic cells to Ga-As Semi-Conductor-Dens-Bio Laser (Frequency: 5 Hz~10,000 Hz Model: SD-101A RCA, U.SA)) were examined in vitro using pulp fibroblastic cells obtained from the pulp tissue of human tooth. The mitogenic effect of soft laser was assessed by measuring the MTT assay. The morphologic effect for soft laser showed under the scanning and transmission electron microscopy. The results as follows; 1. The mitogenic response of the soft laser was not observed until 4th time of radiation, while the mitogenic response at 4th time increased mitogenic effect by as much as 1.7 fold compared to the control value. 2. The mitogenic response of the soft laser on pulp fibroblast differ from the mitogenic response on other fibroblasts. 3. In scanning electron microscopic study, The microvilli of cell surface increased gradually with width and length after laser radiation, it demonstrate that development of microvilli have close connection with differentiation of cells. 4. Under the transmission electron microscope, The laser-treated cells maintained their elongated shape and a high degree of cellular polarization. The large cell body containing a well developed Golgi complex, a large number of profiles of rough endoplasmic reticulum, and great numbers of mitochondria. 5. The laser-treated cells maintained the long straight bundles of closely apposed microfilaments or individual filaments forming a cross-linked network. These findings suggest that the laser may have important roles in promotion of pulp healing and consequently may be useful for clinical application in pulp regenerative procedures.

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Microvibration Control of High Technology Facilities Subjected to Train-induced Excitation using Smart Base Isolation (열차진동하중을 받는 첨단시설물의 스마트 면진시스템을 이용한 미진동제어)

  • Kim, Hyun-Su;Kang, Joo-Won;Kim, Young-Sik
    • Journal of Korean Association for Spatial Structures
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    • v.12 no.2
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    • pp.99-108
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    • 2012
  • Microvibration problem of high-technology facilities, such as semi-conductor plants and TFT-LCD plants, has been considered as important factors that affects the performance of products and thus it is regarded as important in facilities with high precision equipments. In this paper, various base isolation control systems are used to investigate their microvibration control performance. To this end, train-induced ground acceleration is used for time history analysis and three-story example building structure is employed. Microvibration control performance of passive and smart base isolation systems have been investigated in this study. Based on numerical simulation results, it has been verified that smart base isolation system can control microvibration of a high-technology facility subjected to train-induced excitation.

Use of Adaptive Meshes in Simulation of Combustion Phenomena

  • Yi, Sang-Chul;Koo, Sang-Man
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06b
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    • pp.285-309
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    • 1996
  • Non oxide ceramics such as nitrides of transition metals have shown significant potential for future economic impact, in diverse applications in ceramic, aerospace and electronic industries, as refractory products, abrasives and cutting tools, aircraft components, and semi-conductor substrates amid others. Combustion synthesis has become an attractive alternative to the conventional furnace technology to produce these materials cheaply, faster and at a higher level of purity. However he process os highly exothermic and manifests complex dynamics due to its strongly non-linear nature. In order to develop an understanding of this process and to study the effect of operational parameters on the final outcome, numerical modeling is necessary, which would generated essential knowledge to help scale-up the process. the model is based on a system of parabolic-hyperbolic partial differential equations representing the heat, mass and momentum conservation relations. The model also takes into account structural change due to sintering and volumetric expansion, and their effect on the transport properties of the system. The solutions of these equations exhibit steep moving spatial gradients in the form of reaction fronts, propagating in space with variable velocity, which gives rise to varying time scales. To cope with the possibility of extremely abrupt changes in the values of the solution over very short distances, adaptive mesh techniques can be applied to resolve the high activity regions by ordering grid points in appropriate places. To avoid a control volume formulation of the solution of partial differential equations, a simple orthogonal, adaptive-mesh technique is employed. This involves separate adaptation in the x and y directions. Through simple analysis and numerical examples, the adaptive mesh is shown to give significant increase in accuracy in the computations.

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Design and Manufacturing of Clean Room Garments Required at Ultra Clean Environment - Based on comparative analysis of Particle Release- (고청정 작업환경에 적합한 방진복 디자인 개발 -파티클 발생량을 중심으로-)

  • 박상희;송명견
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.6
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    • pp.1037-1045
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    • 2001
  • This research is done to design and manufacture prototype clean room garments to improve the product yield of the clean room processing. To assist the research, other papers and references on the same subject were collected for analysis. Also the researcher made interviews with the workers at the clean room. The prototype garments made for this project was compared against the commercially available clean room garments used in the industry. A set of test was conducted to measure particle release from the garments. The prototype clean room garments was manufactured after having considered all the aspects stated above, and tested for the level of particle release. The test subjects performed 4 different movements(marching, arms stretch, squat and rise, and jogging) while wearing the prototype garments and commercially available clean room garments. Particle counts produced by each movement were measured. The data collected was statistically analyzed. The followings are the result of the test. 1) Overall, the prototype garments yielded less particle release.(p<0.001) 2) It showed greatest difference of particle counts for jogging(p<0.001) and squat and rise(p<0.001). In the arms stretch test. the prototype garments was also more effective in controling the particle, however, in the marching test. no significant difference was detected. 3) The prototype garments had less particle release in upper(p<0.001), middle(p< 0.001), and lower level(p<0.01) than the commercially available clean room garments. Manufacturing a new fabric for the clean room processing is important, but this research proves that the design of the clean room garments also determines the efficiency garments in the particle control. Therefore the same fabric can perform differently according to how it is designed. Improving the design will also improve the 7article control and reduce the cost of research. Eventually, the manufacturers will increase the product yield.

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Preparation of Vanadium Dioxide by Hydrogen Reduction of Vanadium Pentoxide and its Thermochromic Properties (오산화바나듐의 수소 환원에 의한 이산화바나듐의 제조 및 열변색 특성)

  • Choi, Seung Hoon;Lee, Chun Boo
    • Resources Recycling
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    • v.26 no.5
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    • pp.61-66
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    • 2017
  • Vanadium Dioxide has been investigated for use as a "spectrally-selective" window coating to block infrared transmission and reduce the loss of building interior heat through windows. The preparation of thermochromic $VO_2$ powder by the reductive reaction with hydrogen was studied. The reductive reaction method has many advantages of easy and mass production of $VO_2$ powder according to controlled reaction without semi-conductor equipments like sputter and beam evaporator. The reaction temperature, time, concentration of reductive gas, post-annealing condition and W addition as dopant would affect the characterization of $VO_2$ powder and its thermochromism. Many applications for electrical device and energy-saving technologies is expected.

A Multi-point I/O module development that utilize PC's LAN card and Switching (PC의 랜카드와 스위칭 허브를 활용한 다접점 I/O 모듈 개발)

  • Kim, Tae-Min;Jeon, Yoon-Han;Shin, Gun-Soon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.12 no.11
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    • pp.2022-2030
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    • 2008
  • System such as FA and breakup TC is applied by real time and need to manage. This paper studies data processing skill that can divide TC and data of much quantity with collection by real time. Modularize to several system, and use of computer communication network that interlink computers that can achieve control function of each systems to network is spreading. Develop that can take advantage of Ideonet communication method and transmit signal of channel because do multiplex all. Do data that have semi-conductor equipment or many input of LCD equipment and output node multiplex, and several units real time Ideonet communication that control is available use that all input of point of contact and output module develop.

Inspection System for Tracing Defects of Optical Film Using Contact Image Sensor (Contrast 향상 필름 평가를 위한 실시간 검사장치 개발)

  • Rhee, Hyug-Gyo;Jeon, Byeong-Hyug;Lee, Hoi-Yun;Lee, Yun-Woo
    • Korean Journal of Optics and Photonics
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    • v.19 no.4
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    • pp.310-314
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    • 2008
  • The light from the exterior considerably deteriorates the performance of displays including PDP (plasma display panel). Thus semi-conductor industries have developed a special optical film that can block or absorb the exterior light. In this paper, we propose a new inspection system for tracing the defects of the film. Our system is able to inspect a $1.5\;m\;{\times}\;1\;m$ area for 10 sec with $127\;{\mu}m\;{\times}\;50{\mu}m$ spatial resolution.

Standardization of Rare Earth Elements in ISO TC 298 and Korea's Standardization Strategy (ISO TC 298에서의 희토류 분야 표준화 현황과 우리나라의 전략 및 과제)

  • Eom, Nu Si A;Abbas, Sardar Farhat;Aneeq, Haq Muhammad;Zarar, Rasheed Mohammad;Lee, Mi Hye;Kim, Bum Sung;Kim, Taek-Soo;Lee, Bin
    • Journal of Powder Materials
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    • v.26 no.3
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    • pp.251-257
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    • 2019
  • Since the ISO decided to deal with rare-earth elements at the $298^{th}$ Technical Committee (TC) in 2015, Korea has participated in four plenary meetings and proposed four standards as of June 2019. The status of ISO TC 298, the standards covered by the TC, and the standardization strategies of Korea are summarized. Korean delegations are actively engaged in WG2, which deals with recycling, proposing four standards for fostering the rare-earth recycling industry. However, the participation of domestic experts is still low compared with the increase in the number of working groups and the number of standards in TC 298. The aim of this article is to summarize the current status of ISO international standards related to rare-earth elements, to encourage relevant experts to participate in standardization, and to develop international standards that accurately reflect the realities of the industry.

Application of Layered Perovskites Substituted with Co and Ti as Electrodes in SOFCs (Co 및 Ti가 치환된 Layered perovskite의 SOFC 전극에 대한 적용성 연구)

  • Kim, Chan Gyu;Shin, Tae Ho;Nam, Jung Hyun;Kim, Jung Hyun
    • New & Renewable Energy
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    • v.18 no.2
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    • pp.40-49
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    • 2022
  • In this study, the phase and electrochemical properties of Co and Ti substituted layered perovskites SmBaCo2-xTixO5+d (x=0.5, 0.7, 1.0, 1.1, 1.3, and 1.5) were analyzed, and their application as electrodes in solid oxide fuel cells (SOFCs) were evaluated. After calcination at 1300℃ for 6 h, a single phase was observed for two compositions of the SmBaCo2-xTixO5+d oxide system, SmBaCoTiO5+d (x=1.0) and SmBaCo0.9Ti1.1O5+d (x=1.1). However, the phases of SmBaCoTiO5+d (SBCTO) and SmTiO3 coexisted for compositions with x≥1.3 (Ti content). In contrast, for compositions of x≤0.7, the SmBaCo2O5+d phase was observed instead of the SmTiO3 phase. To evaluate the applicability of these materials as SOFC electrodes, the electrical conductivities were measured under various atmospheres (air, N2, and H2). SBCTO exhibited stable semi-conductor electrical conductivity behavior in an air and N2 atmosphere. However, SBCTO showed insulator behavior at temperatures above 600℃ in a H2 atmosphere. Therefore, SBCTO may only be used as cathode materials. Moreover, SBCTO had an area specific resistance (ASR) value of 0.140 Ω·cm2 at 750℃.