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Formation and Progression of Intermetallic phase on Iron Base Alloy PTA weld overlay in Molten Zn Alloys (용융 Zn 합금에서 Fe합금의 PTA 오버레이 용접 금속간 상의 형성과 진행)

  • Zulkarnain, Zulkarnain;Baek, E.R.
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.95-95
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    • 2009
  • Zinc coatings provide the most effective and economical way of protecting steel against corrosion. There are three types of galvanizing lines typically used in production line in galvanizing industries,Galvanize (GI) coating (Zn-0.1-0.3%Al), Galfan coating (Zn-5%Al), Galvalume(GL) coating (45%Zn-Al). In continuous Galvanizing lines, the immersed bath hardware (e.g. bearings, sink, stabilizer, and corrector rolls, and also support roll arms and snout tip) are subjected to corrosion and wear failure. Understanding the reaction of these materials with the molten Zn alloy is becomes scientific and commercial interest. To investigate the reaction with molten Zn alloys, static immersion test performed for 4, 8, 16, and 24 Hr. Two different baths used for the static immersion, which are molten Zn and molten Zn-55%Al. Microstructures characterization of each of the materials and intermetallic layer formed in the reaction zone was performed using optical microscope, SEM and EDS. The thickness of the reaction layer is examined using image analysis to determine the kinetics of the reaction. The phase dominated by two distinct phase which are eutectic carbide and matrix. The morphology of the intermetallic phase formed by molten Zn is discrete phase showing high dissolution of the material, and the intermetallic phase formed by Zn-55wt%Al is continuous. Aluminum reacts readily with the materials compare to Zinc, forming iron aluminide intermetallic layer ($Fe_2Al_5$) at the interface and leaving zinc behind.

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Quantitative Analysis on the Damage of the Austenitic Stainless Steel under the Simultaneous Cavitation Bubble and Solid Particle Collapses (오스테나이트계 304 스테인리스강의 케비테이션 기포 및 고체 입자 동시 충격 손상의 정량적 고찰)

  • Hong, Sung-Mo;Park, Jin-Ju;Lee, Min-Ku;Rhee, Chang-Kyu
    • Korean Journal of Metals and Materials
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    • v.48 no.10
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    • pp.893-900
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    • 2010
  • In the present work, the impact loads and their effects on the surface damage under the simultaneous cavitation bubble and solid particle collapses in the sea water have been quantitatively investigated for the austenitic 304 stainless steel by using a vibratory cavitation test device. To do this, angular $SiO_2$ solid particles with an average size of $150{\mu}m$ were dispersed into the test liquid, and the measured impact amplitudes were converted into the impact loads by a steel ball drop test. The maximum impact load was determined to be 28.2 N in the absence of solid particles, but increased to 33.7 N in the presence of solid particles. In addition, the critical impact loads, $L_{crit}$, required to generate pits with sizes greater than $3{\mu}m$ were measured to be 19.6 N and 16.6 N, respectively, for the cavitation bubble collapse and solid particle collapse. As a result of the cavitation erosion test, the incubation time and erosion rate were 1.2 times lower and 1.5 times higher, respectively, by a solid particle collapse compared to those only by the cavitation bubble collapse, indicating a drastic decrease in a resistance to cavitation erosion by the solid particle collapse.

Magnetite for phosphorus removal in low concentration phosphorus-contained water body

  • Xiang, Heng;Liu, Chaoxiang;Pan, Ruiling;Han, Yun;Cao, Jing
    • Advances in environmental research
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    • v.3 no.2
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    • pp.163-172
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    • 2014
  • Magnetite was chosen as a typical adsorbent to study its phosphate adsorption capacity in water body with low concentration of phosphorus (below $2mg\;PL^{-1}$). Magnetite was collected from Luoyang City, Henan Province, China. In this research, three factors have been studied to describe the adsorption of phosphate on magnetite, which was solution concentration (concentration ranging from 0.1 to $2.5mg\;PL^{-1}$), suspension pH (1 to 13) and temperature (ranging from $10^{\circ}C$ to $40^{\circ}C$). In addition, the modified samples had been characterized with XRD and FE-SEM image. The results show that iron ions contains in magnetite were the main factors of phosphorus removal. The behavior of phosphorus adsorption to substrates could be fitted to both Langmuir and Freundlich isothermal adsorption equations in the low concentration phosphorus water. The theoretical saturated adsorption quantity of magnetite is 0.158 mg/g. pH has great influence on the phosphorus removal of magnetite ore by adsorption. And pH of 3 can receive the best results. While temperature has little effect on it. Magnetite was greatly effective for phosphorus removal in the column experiments, which is a more practical reflection of phosphorous removal combing the adsorption isotherm model and the breakthrough curves. According to the analysis of heavy metals release, the release of heavy metals was very low, they didn't produce the secondary pollution. The mechanism of uptake phosphate is in virtue of chemisorption between phosphate and ferric ion released by magnetite oxidation. The combined investigation of the magnetite showed that it was better substrate for water body with low concentration of phosphorus.

Detailed Morphology and Texture of Microlites in Obsidian observed through Electron Microscopy (전자현미경을 이용한 흑요석 내 미세결정의 형태와 조직 관찰)

  • Jwa, Yong-Joo;Hwang, Ga-hyun
    • Journal of the Korean earth science society
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    • v.39 no.6
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    • pp.568-574
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    • 2018
  • Microlite is crystallized under the supercooled condition of volcanic magma. This study reports the morphology and texture of microlites included in the obsidians from the Baekdusan (Mt. Baekdu), Kyushu (Japan), Hokkaido (Japan) and Lipari Island (Italy) by using a scanning electron microscope (SEM). Morphology and texture observed from the back scattered electron (BSE) image could give more detailed information on the microlite crystallization which cannot be acquired from the conventional optical microscope. Ten types of microlites are newly described according to the 14 morphological types of microlites by Clark (1961): Lath, Crenulite, Bacillite, Margarite, Belonites, Trichites, Arculites, Furculite, Scopulites, Scopulitic growth. Detailed description of the ten microlites can be used to interpret the crystallization and paragenetic relations of crystals during the cooling of acidic volcanic magma.

Development of Ceramic Hollow Fiber Membrane Contactor Modules for Carbon Dioxide Separation (이산화탄소 분리용 세라믹 중공사 접촉막 모듈 기술 개발)

  • Lee, Hong Joo;Che, Jin Woong;Park, Jung Hoon
    • Journal of Climate Change Research
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    • v.7 no.3
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    • pp.249-256
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    • 2016
  • Porous $Al_2O_3$ hollow fiber membranes were successfully prepared by dry-wet spinning/sintering method. The SEM image shows that the $Al_2O_3$ hollow fiber membrane consists mostly of sponge pore structure. The contact angle and the breakthrough pressure were $126^{\circ}$ and 1.91 bar, respectively. This results indicate that the $Al_2O_3$ hollow fiber membranes were successfully modified to hydrophobic surface. The hydrophobic modified $Al_2O_3$ hollow fiber membranes were assembled into a membrane contactor system to separate $CO_2$ from a model gas mixture of the flue gas at elevated gas velocity. The $CO_2$ absorption flux was enhanced when the gas velocity increased from $1{\times}10^{-3}$ to $6{\times}10^{-3}$ m/s. Whereas the $CO_2$ absorption flux was decreased with the number of hollow fiber membrane of a module because of the concentration polarization. Furthermore, we developed an lab-scale $Al_2O_3$ hollow fiber membrane contactor modules and their system (i.e., $CO_2$ absorption using the $Al_2O_3$ membrane and monoethanolamine (MEA)) that could dispose of over $0.02Nm^3/h$ mixture gas (15% $CO_2$) with the removal efficiency higher than 95%. The results can be useful in a field of the membrane contactor for $CO_2$ separation, helping to design and extend a equipment.

Flexible Dye-sensitized Solar Cell Using Titanium Gel at Low Temperature (저온 티타늄 겔을 이용한 플렉시블 염료감응형 태양전지)

  • Ji, Seung Hwan;Park, Hyunsu;Kim, Doyeon;Han, Do Hyung;Yun, Hye Won;Kim, Woo-Byoung
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.183-188
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    • 2019
  • Flexible dye-sensitized solar cells using binder free $TiO_2$ paste for low temperature sintering are developed. In this paste a small amount of titanium gel is added to a paste of $TiO_2$ nanoparticle. Analysis of titanium gel paste prepared at $150^{\circ}C$ shows that it has a pure anatase phase in XRD and mesoporous structure in SEM. The formation of the titanium gel 1-2 nm coated layer is confirmed by comparing the TEM image analysis of the titanium gel paste and the pristine paste. This coating layer improves the excited electron transfer and electrical contact between particles. The J-V curves of the organic binder DSSCs fabricated at $150^{\circ}C$ shows a current density of $0.12mA/cm^2$ and an open-circuit voltage of 0.47 V, while the titanium gel DSSCs improves electrical characteristics to $5.04mA/cm^2$ and 0.74 V. As a result, the photoelectric conversion efficiency of the organic binder DSSC prepared at low temperature is as low as 0.02 %, but the titanium gel paste DSSCs has a measured effciency of 2.76 %.

Fabrication and Characterization of Silver Copper(I) Oxide Nanoparticles for a Conductive Paste (은이 코팅된 Copper(I) Oxide 나노 입자 및 도전성 페이스트의 제조 특성)

  • Park, Seung Woo;Son, Jae Hong;Sim, Sang Bo;Choi, Yeon Bin;Bae, Dong Sik
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.37-42
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    • 2019
  • This study investigates Ag coated $Cu_2O$ nanoparticles that are produced with a changing molar ratio of Ag and $Cu_2O$. The results of XRD analysis reveal that each nanoparticle has a diffraction pattern peculiar to Ag and $Cu_2O$ determination, and SEM image analysis confirms that Ag is partially coated on the surface of $Cu_2O$ nanoparticles. The conductive paste with Ag coated $Cu_2O$ nanoparticles approaches the specific resistance of $6.4{\Omega}{\cdot}cm$ for silver paste(SP) as $(Ag)/(Cu_2O)$ the molar ratio increases. The paste(containing 70 % content and average a 100 nm particle size for the silver nanoparticles) for commercial use for mounting with a fine line width of $100{\mu}m$ or less has a surface resistance of 5 to $20{\mu}{\Omega}{\cdot}cm$, while in this research an Ag coated $Cu_2O$ paste has a larger surface resistance, which is disadvantageous. Its performance deteriorates as a material required for application of a fine line width electrode for a touch panel. A touch panel module that utilizes a nano imprinting technique of $10{\mu}m$ or less is expected to be used as an electrode material for electric and electronic parts where large precision(mounting with fine line width) is not required.

A study on carbon composite fabrication using injection/compression molding and insert-over molding (사출/압축 공정과 인서트 오버몰딩을 이용한 탄소복합소재 성형에 대한 연구)

  • Jeong, Eui-Chul;Yoon, Kyung-hwan;Hong, Seok-Kwan;Lee, Sang-Yong;Lee, Sung-Hee
    • Design & Manufacturing
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    • v.14 no.4
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    • pp.11-16
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    • 2020
  • In this study, forming of carbon composite parts was performed using an injection/compression molding process. An impregnation of matrix is determined by ability of wet and flow rate between the matrix and reinforcement. The flow rate of matrix passing through the reinforcements is a function of permeability of reinforcement, a viscosity of matrix and pressure gradient on molding, and the viscosity of the matrix depends on the mold temperature, molding pressure and shear strain of matrix. Therefore, compression molding experiment was conducted using a heating mold in order to confirm the possibility of matrix impregnation. The impregnation of the matrix through the porosities between the woven yarns was confirmed by the cross-sectional SEM image of compression molded parts. An injection molding process was also performed at a short cycle time, high molding pressure and low mold temperature than those of compression experiment conditions. Deterioration of impregnation on the surface of molded parts were caused by these injection conditions and it could be the reason of decreasing the maximum tensile strength. In order to improve impregnation of matrix on the surface, injection/compression molding and insert-over molding were applied. As a result of applying injection/compression molding and insert-over molding, it was shown that the improvement of impregnation on the surface and the maximum tensile strength was increased about 2.8 times than the virgin matrix.

Design and Empirical Study of an Online Education Platform Based on B2B2C, Focusing on the Perspective of Art Education

  • Hou, Shaopeng;Ahn, Jongchang
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.16 no.2
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    • pp.726-741
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    • 2022
  • The purpose of this study is to provide instructive theoretical models for art (music) education institutions especially when unpredictable risks, such as pandemics, occur again. Based on the customer behavior theory of the business-to-business-to-customer (B2B2C) platform, and in combination with the technology acceptance model (TAM) and expectation confirmation model (ECM), this study proposes an online education model from the perspective of art education. The framework is based on the three decision-making processes of the customer, and includes the product owner, content owner, and customer area. This paper highlights the factors that influence customers in making decisions when art education institutions are product owners. Regression analysis was introduced to study the factors influencing the expectation confirmation, and the overall fitting testing and six hypotheses testing of 385 effective samples were performed using the structural equation modeling (SEM). The results show that the course-design and after-service positively influenced the expectation confirmation, and the domain image positively influenced the continuance behavior. Negative emotions skipped the mediator (expectation confirmation) and directly exerted a significant negative impact on customers' willingness to continue system usage (continuance behavior). In addition, expectation confirmation positively influenced continuance behavior. The paths of detailed items comprising course-design, after-service, and negative emotion were also analyzed and discussed. In this path analysis, ordinary art learners did not believe that AI partners can play a very good auxiliary role. The findings contribute to the scope of information systems acting as an art education platform academically, and provide effective and theoretical support for the actual operation of art education institutions.

Experimental and numerical FEM of woven GFRP composites during drilling

  • Abd-Elwahed, Mohamed S.;Khashaba, Usama A.;Ahmed, Khaled I.;Eltaher, Mohamed A.;Najjar, Ismael;Melaibari, Ammar;Abdraboh, Azza M.
    • Structural Engineering and Mechanics
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    • v.80 no.5
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    • pp.503-522
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    • 2021
  • This paper investigates experimentally and numerically the influence of drilling process on the mechanical and thermomechanical behaviors of woven glass fiber reinforced polymer (GFRP) composite plate. Through the experimental analysis, a CNC machine with cemented carbide drill (point angles 𝜙=118° and 6 mm diameter) was used to drill a woven GFRP laminated squared plate with a length of 36.6 mm and different thicknesses. A produced temperature during drilling "heat affected zone (HAZ)" was measured by two different procedures using thermal IR camera and thermocouples. A thrust force and cutting torque were measured by a Kistler 9272 dynamometer. The delamination factors were evaluated by the image processing technique. Finite element model (FEM) has been developed by using LS-Dyna to simulate the drilling processing and validate the thrust force and torque with those obtained by experimental technique. It is found that, the present finite element model has the capability to predict the force and torque efficiently at various drilling conditions. Numerical parametric analysis is presented to illustrate the influences of the speeding up, coefficient of friction, element type, and mass scaling effects on the calculated thrust force, torque and calculation's cost. It is found that, the cutting time can be adjusted by drilling parameters (feed, speed, and specimen thickness) to control the induced temperature and thus, the force, torque and delamination factor in drilling GFRP composites. The delamination of woven GFRP is accompanied with edge chipping, spalling, and uncut fibers.