• Title/Summary/Keyword: SEI layer

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Regional Distribution of Interstitial Cells of Cajal, (ICC) in Human Stomach

  • Yun, Hyo-Yung;Sung, Ro-Hyun;Kim, Young-Chul;Choi, Woong;Kim, Hun-Sik;Kim, Heon;Lee, Gwang-Ju;You, Ra-Young;Park, Seon-Mee;Yun, Sei-Jin;Kim, Mi-Jung;Kim, Won-Seop;Song, Young-Jin;Xu, Wen-Xie;Lee, Sang-Jin
    • The Korean Journal of Physiology and Pharmacology
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    • v.14 no.5
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    • pp.317-324
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    • 2010
  • We elucidated the distribution of interstitial cells of Cajal (ICC) in human stomach, using cryosection and $c-Kit$ immunohistochemistry to identify $c-Kit$ positive ICC. Before $c-Kit$ staining, we routinely used hematoxylin and eosin (HE) staining to identify every structure of human stomach, from mucosa to longitudinal muscle. HE staining revealed that the fundus greater curvature (GC) had prominent oblique muscle layer, and $c-Kit$ immunostaining $c-Kit$ positive ICC cells were found to have typical morphology of dense fusiform cell body with multiple processes protruding from the central cell body. In particular, we could observe dense processes and ramifications of ICC in myenteric area and longitudinal muscle layer of corpus GC. Interestingly, $c-Kit$ positive ICC-like cells which had morphology very similar to ICC were found in gastric mucosa. We could not find any significant difference in the distribution of ICC between fundus and corpus, except for submucosa where the density of ICC was much higher in gastric fundus than corpus. Furthermore, there was no significant difference in the density of ICC between each area of fundus and corpus, except for muscularis mucosa. Finally, we also found similar distribution of ICC in normal and cancerous tissue obtained from a patient who underwent pancreotomy and gastrectomy. In conclusion, ICC was found ubiquitously in human stomach and the density of ICC was significantly lower in the muscularis mucosa of both fundus/corpus and higher in the submucosa of gastric fundus than corpus.

Fabrication of TiO2/polyelectrolyte thin film for a methyl mercaptan gas sensor (메칠멜캅탄 가스센서용 TiO2/전해질폴리머 박막 제조)

  • Kim, Jin-Ho;Hwang, Jong-Hee;Lee, Mi-Jai;Kim, Sei-Ki;Lim, Tae-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.5
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    • pp.221-226
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    • 2010
  • Quartz crystal microbalance (QCM) gas sensor to detect methyl mercaptan ($CH_3SH$) gas was fabricated by depositing $TiO_2$ nanoparticles and polyelectrolyte on the electrode of QCM. The $TiO_2$/poly(sodium 4-styrenesulfonate) (PSS) thin film fabricated by a layer-by-layer self-assembly (LBL-SA) method showed a high surface area and increased the sensitivity of gas sensor. When the QCM sensors coated with triethanolamine (TEA) or ($TiO_2$/PSS) were exposed to methyl mercaptan gas (1.0 ppm), the frequency shifts of QCM with TEA casting film and $TiO_2$/PSS thin film were ca. 9 Hz and ca. 24 Hz, respectively. As the bilayer number of ($TiO_2$/PSS) increased, the frequency shift of QCM sensor with ($TiO_2$/PSS) thin film was gradually increased. In addition, the frequency shift of QCM sensor was gradually increased as the concentration of methyl mercaptan gas increased from 0.5 ppm to 2.0 ppm. In this study, the surface morphology and sensor property of QCM sensor coated with ($TiO_2$/PSS) thin film were measured.

A Study on the Improvement of the Electrochemical Performance of Graphite Anode by Controlling Properties of the Coating Pitch (코팅 피치의 물성제어를 통한 흑연 음극재의 전기화학 성능 향상 연구)

  • Kim, Bo Ra;Kim, Ji Hong;Kang, Seok Chang;Im, Ji Sun
    • Applied Chemistry for Engineering
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    • v.33 no.5
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    • pp.459-465
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    • 2022
  • A pitch coating method was proposed for the purpose of improving the electrochemical properties of natural graphite. The synthesis conditions of pitch coating were optimized via measuring electrochemical properties of pitch-coated graphite anodes. As the synthesis temperature increased, the thermal stability was improved in addition to an increase in the softening point and residual carbon weight. However, the synthesis temperature of 430 ℃ resulted in the synthesis of a large amount of NI (NMP Insoluble) due to excessive condensation reaction. As the surface uniformity and coating thickness increased due to high thermal stability, the initial coulombic efficiency and rate capability of the pitch-coated graphite were improved. However, the graphite coated with the pitch containing excessive NI showed lower electrochemical properties than the uncoated graphite. NI had low dispersibility and formed spheres after heat treatment, so it formed the heterogeneous and thicker SEI layer. The optimum conditions for forming a uniform surface and an appropriate coating layer were investigated.

Effect of Application of Swine Slurry on Productivity of Sorghum × Sorghum Hybrid and Soil Environment in Reclaimed Land (간척지에서 돈분액비 시용이 수수 × 수수 교잡종의 생산성 및 토양환경에 미치는 영향)

  • Choi, Ki-Choon;Jung, Min-Woong;Cho, Nam-Chul;Park, Hyung-Soo;Yoon, Sei-Hyung;Kim, Jong-Geun;Song, Chae-Eun;Choi, Eun-Min;Kim, Cheon-Man;Lim, Young-Chul
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.31 no.2
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    • pp.159-166
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    • 2011
  • This experiment was carried out to investigate the effect of application of swine slurry (SS) and slurry composting-biofilteration liquid fertilizer (SCB) on productivity of sorghum${\times}$sorghum hybrid (SSH) and soil environment in reclaimed land of Sukmoon in Korea. Dry matter (DM) yields of SSH in the treatments of SS and chemical fertilizer (CF) were higher than those of in SCB treatment in reclaimed land, but DM yields in SS and CF did not show a significant difference as compared to SCB. Nutritive values of SSH were not different among CF, SS and SCB. In soil samples collected at the end of the experiment, the concentration of organic matter was significantly increased by SS and SCB as compare to that at the beginning of the experiment (P<0.05), whereas the concentration of total nitrogen was not affected by SS and SCB. To investigate the moisture content of soil, the soils were collected from three layers; surface (0~5 cm), intermediate (10~15 cm), and deep (20~25 cm) layer. The moisture contents of soils increased according to the soil depth and the soil moisture was immediately affected by the amount of rainfall. Therefore, we suggest that the cultivation of SSH using SS in reclaimed land is possible and that additional nitrogen fertilizer was surely applied in case of application of SCB to cultivate SSH.

The cholesterol Accumulation decreasing effect of Porpbyra yezoensis extract in kidney of Murine with hypercholesterolemia induced by Triton WR-1339 (Triton WR-1339에 의한 고콜레스테롤증 유발시 해조류 김 추출물의 신장내 콜레스테롤 축적 감소효과)

  • Park, In-Sick;Ahn, Sang-Hyun;Chang, Jae-Man;Kim, Jin-Tack;Kim, Ho-Hyun
    • The Journal of Dong Guk Oriental Medicine
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    • v.7 no.1
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    • pp.43-51
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    • 1998
  • Renal tissues of ICR mouse were intraperitoneally injeced with Porpbyra yezoensis extract(PE) after Triton WR-1339(TX) injection were observed to investigate the cholesterol accumulation decreasing effect of PE. The renal tissues were obtained at hour 24, 48, and 72 after TX injection that were fixed in fromol-calcium solution and were cryocut. The tissue stained by sudan black B for lipid and perchloric acid-naphthoquinone method for cholesterol. The parietal layer of Bowman's capsule is swelled as cuboidal type at hour 48 after TX injection and the lipid blot and cholesterol particle were noticeably increased in glomerulus and these appeared in convoluted tubule, collecting tubule, and Helen's loop. In PE treated group, the lpid blot and cholesterol particle were considerably decreased in glomerulus than TX group. As results indicated that the accumulation of lipid including cholesterol caused by TX injection were mitigated in renal tissues by the antihypercholesterolemia effect of PE.

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AFM Study on Surface Film Formation on a Graphite Negative Electrode in a $LiPF_6$-based Non-Aqueous Solution (AFM을 이용한 $LiPF_6$를 주성분으로 하는 비수용액중에서의 흑연 음극 표면에 형성되는 피막에 관한 연구)

  • Jeong, Soon-Ki
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.6
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    • pp.1313-1318
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    • 2006
  • The mechanism fur the surface film formation was studied by in situ Atomic Force Microscopy (AFM) observation of a highly oriented pyrolytic graphite (HOPG) basal plane surface during cyclic voltammetry at a slow scan-rate of 0.5 mV $s^{-1}$ in 1 moi $dm^{-3}$ (M) $LiPF_6$ dissolved in a mixture of ethylene carbonate (EC) and diethyl carbonate (DEC). Decomposition of the electrolyte solution began at a potential around 2.15 V vs. $Li^+$/Li on step edges. In the potential range 0.95-0.8 V vs. $Li^+$/Li, flat areas (hill-like structures) and large swelling appeared on the surface. It is considered that these two features were formed by the intercalation of solvated lithium ions and their decomposition beneath the surface, respectively. At potentials more negative than 0.80 V vs. $Li^+$/Li, particle-like precipitates appeared on the basal plane surface. After the first cycle, the thickness of the precipitate layer was 30 nm. The precipitates were considered to be decomposition of the lithium salt ($LiPF_6$) and solvent molecules (EC and DEC), and to have an important role in suppressing further solvent decomposition on the basal plane.

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Effect of Pyrolysis Fuel Oil Based Carbon Coating onto CFX Cathode on High-rate Performance of Lithium Primary Batteries (불화탄소 전극의 열분해 연료유 기반 탄소 코팅이 리튬일차전지의 고율속 성능에 미치는 영향)

  • Sangyeop Lee;Naeun Ha;Seongjae Myeong;Chaehun Lim;Sei-Hyun Lee;Young-Seak Lee
    • Applied Chemistry for Engineering
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    • v.35 no.4
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    • pp.321-328
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    • 2024
  • The performance of carbon fluoride-based lithium primary batteries (Li/CFX) is limited due to poor rate capability resulting from the low conductivity of carbon fluoride, which is used as the active material. Therefore, in this study, we applied a carbon coating using pyrolysis fuel oil on carbon fluoride to overcome this limitation and considered its electrochemical performance. An amorphous carbon layer was formed on the surface of the carbon fluoride through carbon coating, and the surface physicochemical properties of the carbon fluoride were meticulously considered based on the heat treatment temperature. The advanced research chemical 1000 heat treated at 450 ℃ (ARC@C450) sample, which was commercial carbon fluoride heat-treated at 450 ℃, showed the largest increase in the concentration of sp2 carbon bonds (62%) and the highest formation of semi-ionic C-F bonds. Also, the primary battery using the ARC@C450 sample as a cathode active material exhibited stable discharge capability at the highest rate of 5 C (392 mAh/g), and the Rct value was reduced by 53% compared to the untreated sample. Therefore, we proposed pyrolysis fuel oil-based carbon coating as a method to overcome the low conductivity of carbon fluoride, and the carbon-coated carbon fluoride showed excellent rate performance, suggesting its potential application in high-power primary batteries.

Geochemical Characteristics and Quaternary Environmental Change of Unconsolidated Sediments from the Seokgwan-dong Paleolithic Site in Seoul, Korea (서울 석관동 유적의 미고결 퇴적층의 지구화학적 특성 및 제4기 지표환경변화)

  • Lee, Hyo-Min;Lee, Jin-Young;Kim, Ju-Yong;Hong, Sei-Sun;Park, Jun-Bum
    • The Journal of the Petrological Society of Korea
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    • v.25 no.4
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    • pp.373-388
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    • 2016
  • To understand human activity in the past, the information about past environmental change including geomorphological and climatic conditions is essential and this can be traced by using age dating and geochemical analysis of sediments from the prehistoric sites. The sedimentary sequence of Seokgwan-dong Paleolithic Site located in Seoul was 5m long unconsolidated sediments and consists of lower part bedrock weathering sediments, slope deposits and upper-part fluvial deposits. In this study, upper part sediments were used to reconstruct past environmental change through age dating and various physical and chemical analyses including grain size, magnetic susceptibility and mineral and elements. The fluvial sediments can be divided into 4 units including three organic layers. Grain size analysis results showed that the sediments were very poorly sorted with fining upward features. Magnetic susceptibility was relatively high in the organic layers, indicating environmental changes causing mineral composition change at that times. The mineral and major element composition are similar to Jurassic biotite granite which mainly consists of quartz, K-feldspar, biotite and muscovite. The radiocarbon age of $14,240{\pm}80yr$ BP was obtained from the lower most organic layer of Unit III(O), suggesting that the fluvial sediments formed at least from the early stage of deglacial period after the end of Last Glacial Maximum. Subsequent wet and warm climates and resultant fluvial process including slope sedimentation during the Holocene may have been responsible for the sedimentary sequence in Seokgwan-dong paleolithic site and surrounding area. The observed organic layers suggests frequent wetland occurrence combined with natural levee changes in this area.