• Title/Summary/Keyword: SCR system

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Development and Validation of Urea- SCR Control-Oriented Model for NOX and NH3 Slip Reduction (NOX 및 NH3 Slip 저감을 위한 Urea-SCR 제어기반 모델 개발 및 검증)

  • Lee, Seung Geun;Lee, Seang Wock;Kang, Yeonsik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.1
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    • pp.1-9
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    • 2015
  • To satisfy stricter $NO_X$ emission regulations for light- and heavy-duty diesel vehicles, a control algorithm needs to be developed based on a selective catalytic reaction (SCR) dynamics model for chemical reactions. This paper presents the development and validation of a SCR dynamics model through test rig experiments and MATLAB simulations. A nonlinear state space model is proposed based on the mass conservation law of chemical reactions in the SCR dynamics model. Experiments were performed on a test rig to evaluate the effects of the $NO_X$ and $NH_3$ concentrations, gas temperature, and space velocity on the $NO_X$ conversion efficiency for the urea-SCR system. The parameter values of the proposed SCR model were identified using the experimental datasets. Finally, a control-oriented model for an SCR system was developed and validated from the experimental data in a MATLAB simulation. The results of this study should contribute toward developing a closed-loop control strategy for $NO_X$ and $NH_3$ slip reduction in the urea-SCR system for an actual engine test bench.

Volume Optimization of a Combined System of LNT and SCR Catalysts Considering Economic Feasibility and De-NOx Performance

  • Seo, Choong-Kil;Choi, Byung-Chul;Kim, Young-Kwon
    • Journal of Power System Engineering
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    • v.17 no.1
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    • pp.19-26
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    • 2013
  • The purpose of the study is carried out volume optimization of a combined system consisting of an LNT and SCR catalysts from the standpoint of its economic feasibility and de-NOx performance. Under the rich air-fuel ratio conditions for 5s (${\Phi}$=1.1), CO, $H_2$ and THC were generated at levels of 4%, 1.2% and $110ppmC_1$, respectively. The NOx conversion of the 1+1 combination was 5% lower than that of the 1.5+0.5 combination, however the reduced volume of the LNT catalyst decreased the total cost by about 6%. Therefore, the optimal volume ratio of the LNT and SCR catalysts was found to be the 1+1 catalyst combination, which has the highest total score in the terms of an economic feasibility and the NOx performance.

Numerical Analysis for the Flow Uniformity in the LP-SCR Reactor (LP SCR 반응기 내 유동 균일도 개선을 위한 해석적 연구)

  • Um, Hyung Sik;Kim, Gun Ho;Kim, Dae Hee;Kim, Kyu Jong;Kim, Jung Rae
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.61-63
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    • 2015
  • In the low pressure selective catalytic reduction (LP SCR) system, the uniformity of both ammonia concentration and exhaust gas flow at the SCR catalyst layer are important design factor for the efficient SCR-deNOx performance. According to the shape of the guide vane and static mixer, numerical simulations were conducted to analyze flow patterns and finally to find out the appropriate alternative for uniform flow at the front of catalyst in the real scale LP SCR reactor. The variations of gas velocity and ammonia concentration were quantitatively evaluated. Based on the present results, the shape was devised to satisfy the design criteria.

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De-NOx Characteristics of V2O5 SCR according to the Ratio of TiO2 Crystal Structures

  • Seo, Choong-Kil;Bae, Jaeyoung
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.26-32
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    • 2015
  • The purpose of this study is to investigate the de-NOx performance characteristics according to the $TiO_2$ crystal structures ratio of $V_2O_5$ SCR catalysts. The anatase(100%) SCR catalyst showed the highest desorption peak of 80ppm at about $250^{\circ}C$, and $NH_3$ was not desorbed at $500^{\circ}C$. It can be confirmed that there was many $NH_3$ desorbed at a high temperature among other various crystal structures, which is because the catalyst was more acidized to increase the intensity of acid sites as the content of subacid sulfate ions($NH_2SO_4$) in the rutile phase increases. The anatase/rutile(7%/93%) SCR had the smallest width of de-NOx performance drop according to thermal aging, and had strong durability against thermal aging.

The Selection of Prevention Technology Systems for Dioxin Treatment: The Analytic Hierarchy Process Approach (계층분석과정을 이용한 다이옥신 방지기술시스템의 선정에 관한 연구)

  • Kwon, Cheol-Shin;Cho, Keun-Tae
    • IE interfaces
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    • v.13 no.4
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    • pp.668-679
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    • 2000
  • Recently, due to the primary emphasis of environmental problem, the proper selection of the prevention technology systems necessary for Dioxin treatment has been one of the critical issues in the industrial sector. This paper shows how an Analytic Hierarchy Process(AHP) model can be used for assessing the performance of selected prevention technology systems: SDA/BF-SCR, SNCR-SDA/BF, SDA/BF, EP-WS-SCR, ED-WS, and EP-SCR-WS essential for Dioxin treatments. The final results show that SNCR-SDA/BF is the most attractive prevention technology system to use in an incinerator system, followed by SDA/BF-SCR, SDA/BF and EP-WS-SCR. This is consistent with the information that we found with respect to the elements that were taken into consideration. Sensitivity analysis is also provided here.

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Design of the Capacitor Discharge Ignition System (용량방전점화장치의 설계)

  • 박송배;김영길
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.13 no.2
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    • pp.5-13
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    • 1976
  • An analytical and experimental design procedure is described for the Capacitor Discharge Ignition (CDI) System with a view to fuel saving ann reduction of gas exhaustion and maintenance need. Specifically, the input and output voltage and current of a given ignition coil were calculated by using a simplified circuit model for the discharging system. The results were compared with the experimental results, from which ratings of the charging capacitor, the SCR and the diodes and the required output valtage of the DC.DC converter were determined so as to satisfy the optimum ignition conditions. Protection circuits for excessive dv/dt and di/dt for the SCR were also analyzed and the results were compared with the observed results, which facilitate selection of the SCR and design of the protection circuit and the trigger circuit. Also, design of the DC.DC converter was simplified based on the analysis and experimental results of the behavior of the converter, An experimental, yet practical CDI system was built, which showed satisfactory performance in the laboratory and field tests. The results were also reported.

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Analysis of Renal Adverse Reaction Caused by Amphotericin B (Amphotericin B 투여에 의한 신장 유해반응 분석)

  • Lee, Song Bin;Kim, Tae Kyung;Ko, Jong Hee;Ahn, Ji Hyune;Kim, Sung Eun;Seok, Hyun Ju;Kim, Hyunah
    • Korean Journal of Clinical Pharmacy
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    • v.22 no.4
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    • pp.340-346
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    • 2012
  • Background: Amphotericin B is a mainstay in the treatment of many systemic fungal infections due to its wide antifungal spectrum and low incidence of resistance. However, the use of amphotericin B is limited by its nephrotoxicity. Objectives: The objective of this study was to evaluate the incidence and risk factors of renal adverse drug reactions (ADRs) of conventional amphotericin B (Fungizone$^{(R)}$). In addition, we compared the changes of serum creatinine (SCr) between patients who remained conventional amphotericin B and patients who were switched to liposomal amphotericin B after occurrence of renal adverse reactions. Methods: Adult hospitalized patients who reported renal adverse reactions caused by conventional amphotericin B from January 2011 to July 2012 at pharmacovigilance center in Yonsei University Healthcare System included in this study. ADRs scored as 'doubtful' in Naranjo probability ADR scale were excluded. We retrospectively analyzed patients' basic clinical characteristics, concurrent diseases or nephrotoxic drugs in order to find variables that can correlate with occurrence of renal ADRs. Changes in SCr were compared between conventional amphotericin B group and liposomal amphotericin B group. Results: A total of 231 ADRs after administration of conventional amphotericin B in 75 patients were reported to pharmacovigilance center and assessed their severities as 'possible', 'probable', or 'definite'. Renal adverse reaction was the most common ADR with incidence rate of 42% (96 of 231 ADRs). Mean change in SCr from baseline was 0.26 mg/dL (change % 37.8) and statistically significant (p=0.000). Simple correlations analysis revealed that the number of concurrent diseases and number of nephrotoxic drugs were positively correlated with changes in SCr, but these results were not statistically significant. Among 43 patients who remained amphotericin B after occurrence of renal ADRs, 27 patients was administered conventional amphotericin B and 16 patients changed to liposomal amphotericin B. Mean change in SCr in amphotericin B group was 0.23 mg/dL (32.75%), whereas mean change in SCr in liposomal amphotericin B group were -0.28 mg/dL (19.38%) and difference between two groups was statistically significant (p=0.003). The numbers of patient with SCr elevation more than 30% were 9 (33.3%) in amphotericin B group and 2 (12.5%) in liposomal amphotericin B group (Odd Ratio=3.50, 95% Confidence Interval 0.65-18.85; p=0.130). Conclusion: An analysis of ADRs due to amphotericin B administration revealed significant mean changes in SCr from baseline. Switching to liposomal amphotericin B showed significant decrease in SCr compared with conventional amphotericin B.

Freezing and Melting Phenomena of Urea-water Solution for Diesel Vehicle SCR System (디젤차량 SCR 시스템용 요소수용액의 동결과 해동 현상)

  • Choi, B.C.;Seo, C.K.;Myong, K.J.
    • Journal of Power System Engineering
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    • v.13 no.4
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    • pp.5-10
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    • 2009
  • Urea-SCR system, the selective catalytic reduction using urea as reducing agent, is a powerful technique to reduce nitrogen oxides(NOx) emitted from diesel engines. However, a tank of urea(32.5 wt%)-water solution can be frozen in low ambient temperature levels of below $-11^{\circ}C$. The purpose of this study is to understand freezing and melting phenomena of the urea-water solution, and its can be applied to get the urea-water solution from frozen it within 5 minutes after cold start. Factors considered were the type of heater and the urea tank shape. From the results, it was found that melting volume of cartridge heater B during 5 minutes of heating period was 83ml when supplying electric power of 150W. Horizontal heater B, which was put in the narrow bottom space of the tank T1, had fast melting characteristics.

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Frozen and Melting Characteristics of Urea-aqueous Solution for Urea-SCR System by Circulation of Engine Coolant (엔진 냉각수 순환에 의한 urea-SCR 시스템용 요소수의 동결 및 해동 특성)

  • Choi, B.C.;Kim, Y.K.;Kim, H.N.
    • Journal of Power System Engineering
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    • v.15 no.4
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    • pp.42-47
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    • 2011
  • The purpose of this study is to investigate the best melting condition with various winding number of a heating pipe, supplying quantity of engine coolant and coolant temperature at the inlet of the heating pipe. Also, it is to suggest getting method of an appropriate quantity of the agent for the urea-SCR system within 10 minutes. For this matter, this study identifies the temperature distribution of inside of urea-tank while it is frozen at the low temperature condition, and suggests the best melting condition of the frozen urea within 10 minutes. From the results, it was found that 2L of melted urea was obtained by the coolant flow rate of 200L/hr at $70^{\circ}C$ for 10 minutes from the start of engine operating.

High Pulse SCR Inverter for Utility Interactive Renewable Power Generation System (계통연계형 대체에너지 발전시스템을 위한 고펄스 SCR 인버터)

  • Jung, Jae-Hyuck;Kim, Hyun-Jung;Choi, Se-Wan;Kim, Young-Seok;Won, Chung-Yuen
    • Proceedings of the KIPE Conference
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    • 2001.07a
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    • pp.85-89
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    • 2001
  • In this paper, a new line-commutated SCR inverter for renewable power generation system is proposed. The proposed inverter system includes a 6-pulse SCR inverter and an auxiliary circuit. By the proper operation of the auxiliary circuit, the pulse number of the inverter system is increased and the output harmonic currents are reduced. Analysis, control and simulation for 24 pulse operation of the proposed scheme is presented and the experimental results will be provided in the final paper.

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