• Title/Summary/Keyword: SCR

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Simultaneous Removal of Mercury and NO by Metal Chloride-loaded V2O5-WO3/TiO2-based SCR catalysts (금속염화물이 담지된 V2O5-WO3/TiO2 계 SCR 촉매에 의한 수은 및 NO 동시 제거)

  • Ham, Sung-Won
    • Clean Technology
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    • v.23 no.2
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    • pp.172-180
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    • 2017
  • Thermodynamic evaluation indicates that nearly 100% conversion of elemental mercury to oxidized mercury can be attained by HCl of several tens of ppm level at the temperature window of SCR reaction. Cu-, Fe-, Mn-chloride loaded $V_2O_5-WO_3/TiO_2$ catalysts revealed good NO removal activity at the operating temperature window of SCR process. The catalysts with high desorption temperature indicating adsorption strength of $NH_3$ revealed higher NO removal activity. The HCl fed to the reaction gases promoted the oxidation of mercury. However, the activity for the oxidation of elemental mercury to oxidized mercury by HCl was suppressed by $NH_3$ inhibiting the adsorption of HCl to catalyst surface under SCR reaction condition containing $NH_3$ for NO removal. Metal chloride loaded $V_2O_5-WO_3/TiO_2$ catalysts showed much higher activity for mercury oxidation than $V_2O_5-WO_3/TiO_2$ catalyst without metal chloride under SCR reaction condition. This is primarily attributed to the participation of chloride in metal chloride on the catalyst surface promoting the oxidation of elemental mercury.

Experimental Study on Characteristics of NOX Reduction with Urea-Selective Catalytic Reduction System in Diesel Passenger Vehicle (승용 디젤차량에서 Urea-SCR 시스템의 NOX 저감 특성에 관한 실험적 연구)

  • Park, Seungwon;Lee, Seangwock;Cho, Yongseok;Kang, Yeonsik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.4
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    • pp.269-275
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    • 2017
  • $NO_X$ reducing technique such as LNT, LNC, and selective catalytic reduction (SCR) have been developed and applied, especially on heavy-duty vehicles. However, it is expected that $NO_X$ reduction techniques will also be applied to diesel passenger vehicles. The urea-SCR system is receiving attention as the most effective $NO_X$ reduction technology without a fuel penalty. Thus, many advanced countries are developing this technology. The urea-SCR system sprays an aqueous urea solution that separates $NO_X$ into $N_2$ and $H_2O$, which are harmless and emitted into the atmosphere. The urea injected in front of the SCR catalyst should be changed to 100% $NH_3$, which is required for $NO_X$ reduction in the SCR system to maximize the reduction efficiency. The purpose of this study was to determine the basic data for the urea-SCR system to maximize the $NO_X$ reduction efficiency by understanding the $NO_X$ reduction characteristics in a real passenger vehicle to comply with the post EURO-6 emission regulation.

Design of SCR-Based ESD Protection Circuit for 3.3 V I/O and 20 V Power Clamp

  • Jung, Jin Woo;Koo, Yong Seo
    • ETRI Journal
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    • v.37 no.1
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    • pp.97-106
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    • 2015
  • In this paper, MOS-triggered silicon-controlled rectifier (SCR)-based electrostatic discharge (ESD) protection circuits for mobile application in 3.3 V I/O and SCR-based ESD protection circuits with floating N+/P+ diffusion regions for inverter and light-emitting diode driver applications in 20 V power clamps were designed. The breakdown voltage is induced by a grounded-gate NMOS (ggNMOS) in the MOS-triggered SCR-based ESD protection circuit for 3.3 V I/O. This lowers the breakdown voltage of the SCR by providing a trigger current to the P-well of the SCR. However, the operation resistance is increased compared to SCR, because additional diffusion regions increase the overall resistance of the protection circuit. To overcome this problem, the number of ggNMOS fingers was increased. The ESD protection circuit for the power clamp application at 20 V had a breakdown voltage of 23 V; the product of a high holding voltage by the N+/P+ floating diffusion region. The trigger voltage was improved by the partial insertion of a P-body to narrow the gap between the trigger and holding voltages. The ESD protection circuits for low- and high-voltage applications were designed using $0.18{\mu}m$ Bipolar-CMOS-DMOS technology, with $100{\mu}m$ width. Electrical characteristics and robustness are analyzed by a transmission line pulse measurement and an ESD pulse generator (ESS-6008).

Reduced Scale Model Experiments and Numerical Simulation for Flow Uniformity in de-NOx SCR Reactor (배연탈질 SCR 반응기내 유동균일 화를 위한 축소모형실험 및 전산해석)

  • 이인영;김동화;이정빈;류경옥
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.4
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    • pp.347-354
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    • 2001
  • SCR (Selective Catalytic Reduction) process is presently considered as one of the most effective techniques for removing nitric oxides from exhaust gases. In this study, based on the conceptually designed SCR reactor of 500 MW coal fired power plant. a reduced scale (1/20) SCR reactor model was made to analyze the flow pattern in front of catalyst layer according to the guide vane's design factors such as the number, interval, and angle of vanes. The results of the test were compared to those numerical simulation in order to assure the reliability of two methods. On the basis of our study. the critical Reynolds number (2.0$\times$ 10$^{5}$ ) was proposed for ensuring the similarity between the reduced scale model and the prototype of SCR reactor. Optimum design parameters of guide vanes were determined as follows, 4 vanes, the first vane angle of 93$^{\circ}$, and the vane intervals of 0.85 S/n, 1.05 S/n, 1.1 S/n, 1.0S/n, 1.0S/n (S: the distance of duct, n: the number of guide vanes). The excellent agreement between the results of the numerical simulation and the reduced scale model provides the validation of two methods for prediction of flow through SCR reactor.

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The Effects of Zeolite Structure and Ion-exchange Material on NH3-SCR Reaction (제올라이트 종류 및 이온교환 물질에 따른 NH3-SCR 촉매 반응 특성)

  • Hwang, Inhye;Lee, Junho;Kim, Hongsuk;Jeong, Youngil
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.1
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    • pp.135-141
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    • 2014
  • $NH_3$-SCR has high NOx removal efficiency approximately 80~90%. Recently, the copper or iron ion-exchanged zeolite catalysts are widely used as automobile SCR catalysts. In this paper, the effect of the space velocity, temperature of reaction and $NO_2$ addition on the $NH_3$-SCR reaction were studied using various zeolite SCR catalysts. The test was conducted with small sized fresh catalysts in a laboratory fixed-bed flow reactor system using simulated gases. It is found that the activity of the BEA is better than MFI. It seems that three-dimensional framework and a wide pore entrance of BEA enhances the SCR activity. It is also found that low temperature activity of Cu-zeolites was better than Fe-zeolites. Once $NO_2$ was added, the NOx conversion activity of the Cu-zeolite was slightly enhanced, whereas remarkable improvement was achieved by Fe-zeolite.

Development of a variable resistance-capacitance model with time delay for urea-SCR system

  • Feng, Tan;Lu, Lin
    • Environmental Engineering Research
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    • v.20 no.2
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    • pp.155-161
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    • 2015
  • Experimental research shows that the nitric oxides ($NO_X$) concentration track at the outlet of selective catalytic reduction (SCR) catalyst with a transient variation of Adblue dosage has a time delay and it features a characteristic of resistance-capacitance (RC). The phenomenon brings obstacles to get the simultaneously $NO_X$ expected to be reduced and equi-molar ammonia available to SCR reaction, which finally inhibits $NO_X$ conversion efficiency. Generally, engine loads change frequently, which triggers a rapid changing of Adblue dosage, and it aggravates the air quality that are caused by $NO_X$ emission and ammonia slip. In order to increase the conversion efficiency of $NO_X$ and avoid secondary pollution, the paper gives a comprehensive analysis of the SCR system and tells readers the key factors that affect time delay and RC characteristics. Accordingly, a map of time delay is established and a solution method for time constant and proportional constant is carried out. Finally, the paper accurately describes the input-output state relation of SCR system by using "variable RC model with time delay". The model can be used for a real-time correction of Adblue dosage, which can increase the conversion efficiency of $NO_X$ in SCR system and avoid secondary pollution forming. Obviously, the results of the work discover an avenue for the SCR control strategy.

Real-time SCR-HP(Selective catalytic reduction - high pressure) valve temperature collection and failure prediction using ARIMA (ARIMA를 활용한 실시간 SCR-HP 밸브 온도 수집 및 고장 예측)

  • Lee, Suhwan;Hong, Hyeonji;Park, Jisoo;Yeom, Eunseop
    • Journal of the Korean Society of Visualization
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    • v.19 no.1
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    • pp.62-67
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    • 2021
  • Selective catalytic reduction(SCR) is an exhaust gas reduction device to remove nitro oxides (NOx). SCR operation of ship can be controlled through valves for minimizing economic loss from SCR. Valve in SCR-high pressure (HP) system is directly connected to engine exhaust and operates in high temperature and high pressure. Long-term thermal deformation induced by engine heat weakens the sealing of the valve, which can lead to unexpected failures during ship sailing. In order to prevent the unexpected failures due to long-term valve thermal deformation, a failure prediction system using autoregressive integrated moving average (ARIMA) was proposed. Based on the heating experiment, virtual data mimicking temperature range around the SCR-HP valve were produced. By detecting abnormal temperature rise and fall based on the short-term ARIMA prediction, an algorithm determines whether present temperature data is required for failure prediction. The signal processed by the data collection algorithm was interpolated for the failure prediction. By comparing mean average error (MAE) and root mean square error (RMSE), ARIMA model and suitable prediction instant were determined.

Characteristics of Air Pollutants Emission from Medium-duty Trucks Equipped EGR and SCR in Korea (국내 EGR과 SCR 장착 중형트럭 대기오염물질 배출 특성)

  • Son, Jihwan;Kim, Jounghwa;Jung, Sungwoon;Yoo, Heungmin;Hong, Heekyung;Mun, Sunhee;Choi, Kwangho;Lee, Jongtae;Kim, Jeongsoo
    • Journal of ILASS-Korea
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    • v.21 no.3
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    • pp.130-136
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    • 2016
  • NOx and PM are important air pollutants as vehicle management policy aspect. Medium-duty truck is the main source of the pollutants although the vehicle market share is only 3.5%. National emission portion of NOx and PM form the mobile sourece are 14% and 16% respectively. In this study it was investigated that characteristics of air pollutants emission on medium duty truck equipped with EGR and SCR system. Vehicle's test reflected driving cycle on the chassis dynamometer, and applied test cycle was WHVC(World Harmonized Vehicle Cycle) mode. The test cycle include three segments, represent urban, rural and motorway driving. Based on the test results NOx, PM, HC were less emitted form SCR vehicle than EGR vehicle. And CO was less emitted form EGR vehicle than SCR vehicle due to CO oxidation reaction on DPF surface. And most air pollutants reduced as average vehicle speed increased. Pollutants were less emitted on motorway section than urban and rural sections. But highly NOx emission on motorway section was verified according to increased EGR ratio on fast vehicle speed. HC and CO additional emission was identified as 68%, 58% respectively during SCR vehicle's cold engine start emission test. NOx additional emission was detected by 24% on SCR vehicle's condition of engine cold start while not detected on vehicle equipped with EGR. SCR vehicle's additional NOx emission was derived from low reaction temperature during engine cold start condition. medium-duty truck emission characteristics were investigated in this study and expected to used to improve air pollutants management policy of medium-duty truck equipped with SCR & EGR.

The Dessing and Implementation of the SPR/SCR Management System for Reliability Data Collection and Analysis (신뢰성 데이터 수집 및 분석을 위한 SPR/SCR 관리 시스템의 설계 및 구현)

  • Lee, Chang-Hui;Han, Pan-Am
    • The Transactions of the Korea Information Processing Society
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    • v.4 no.2
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    • pp.409-429
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    • 1997
  • Problems encountered during software development or pteration nay result from defects in the software,ghrdware,or their oterations.Because of their diversity,the determination of the sources of a problem and its corrective adtion requires a centrally controlled system for monitoring provlems and detemining systematiccauses. In the paper,the SPR/SCR management system was developed and applied for the collection and analysis of the error data,process data and product data delected by each phasd in SDLC.There are four objectibes in the SPR/SCR management system.The first is to assure that software errors are documented,corrected,and vot forgottem. The second is to assure that SPR.are assessed for their validity.The third is to provide feedback on SPR status to the developer and the user.The fourth is ot prvide data for measuring and prediciting sofware quality and reliability.These goals could be satisfied by the application of the SPR/SCR mangement system.Also,the accomplishment rate of software reliability,criterion of test completion,estimation of release time, efficient development and management can be reflected by applying the SPR/SCR management system.

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Study on NOx Reduction with Multi-Perforated Tube Geometry in Integrated Urea-SCR Muffler (촉매삽입형 Urea-SCR 머플러 다공튜브 형상변화에 따른 NOx 저감 특성에 관한 연구)

  • Moon, Namsoo;Lee, Sangkyoo;Ko, Sangchul;Lee, Jeekeun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.12
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    • pp.1017-1026
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    • 2014
  • A multi-perforated tube is generally installed between the muffler inlet and in front of selective catalytic reduction (SCR) catalysts in the integrated urea-SCR muffler system in order to disperse the urea-water solution spray uniformly and to make better use of the SCR catalyst, which would result in an increase nitrogen oxide ($NO_x$) reduction efficiency and a decrease in the ammonia slip. The effects of the multi-perforated tube orifice area ratios on the internal flow characteristics were investigated analytically by using a general-purpose commercial software package. From the results, it was clarified that the multi-perforated tube geometry sensitively affected the generation of the bulk swirling motion inside the plenum chamber set in front of the SCR catalyst and to the uniformity index of the velocity distribution produced at the inlet of the catalyst. To verify the analytical results, engine tests were carried out in the ESC and ETC modes. Results of these tests indicated that the larger flow model in the longitudinal direction showed the highest NOx reduction efficiency, which was a good agreement with the analytical results.