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Pore Structure and Fractal Characters of Cement Mortar Containing γ-C2S (γ-C2S 혼입 시멘트 모르타르의 공극구조 및 Fractal특성)

  • Chen, Zheng-Xin;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.24-25
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    • 2017
  • Gamma-C2S (γ-C2S) is a substance that is difficult to react with water under normal temperature but can absorb a large amount of CO2 in the air. The addition of γ-C2S to cementitious materials through the curing of CO2 can improve the pore structure and improve the durability of the material. In this study, three kind of Ca-bearing materials : CaO, Ca(OH)2, CaCO3, were calcined 2.5h at 1450℃ to synthesize γ-C2S after mixing with SiO2 respectively. Among them, Ca(OH)2 mixed with SiO2 after calcining shows highest content. Synthesized γ-C2S was added to the cement mortar, after water curing for 1 month, accelerated carbonation test was experimented. After 28d accelerated carbonation test, pore structure will be detectived by MIP. Based on the MIP result, following the calculation method of Fractal theory, the pore structure will be quantitative described.

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A UNIFORM LAW OF LARGE MUNBERS FOR PRODUCT RANDOM MEASURES

  • Kil, Byung-Mun;Kwon, Joong-Sung
    • Bulletin of the Korean Mathematical Society
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    • v.32 no.2
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    • pp.221-231
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    • 1995
  • Let $Z_1, Z_2, \ldots, Z_l$ be random set functions or intergrals. Then it is possible to discuss their products. In the case of random integrals, $Z_i$ is a random set function indexed y a family, $G_i$ say, of real valued functions g on $S_i$ for which the integrals $Z_i(g) = \smallint gdZ_i$ are well defined. If $g_i = \in g_i (i = 1, 2, \ldots, l) and g_1 \otimes \cdots \otimes g_l$ denotes the tensor product $g(s) = g_1(s_1)g_2(s_2) \cdots g_l(s_l) for s = (s_1, s_2, \ldots, s_l) and s_i \in S_i$, then we can defined $Z(g) = (Z_1 \times Z_2 \times \cdots \times Z_l)(g) = Z_1(g_1)Z_2(g_2) \cdots Z_l(g_l)$.

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Study on Point Defect for $AgGaS_2$ Single Crystal Thin film Obtained by Photoluminescience Measurement Method (광발광 측정법에 의한 $AgGaS_2$ 단결정 박막의 점결함 연구)

  • Hong, Kwang-Joon;Kim, Koung-Suk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.25 no.2
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    • pp.117-126
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    • 2005
  • A stoichiometric mixture of evaporating materials for $AgGaS_2$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $AgGaS_2$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy (HWE) system. The source and substrate temperatures were $590^{\circ}C\;and\;440^{\circ}C$, respectively The temperature dependence of the energy band gap of the $AgGaS_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=2.7284 eV-(8.695{\times}10^{-4}eV/K)T^2/T(T+332K)$. After the as-grown $AgGaS_2$, single crystal thin films was annealed in Ag-, S-, and Ga-atmospheres, the origin of point defects of $AgGaS_2$ single crystal thin films has been investigated by the photoluminescence(PL) at 10K. The native defects of $V_{Ag},\;V_s,\;Ag_{int},\;and\;S_{int}$, obtained by PL measurements were classified as a donors or acceptors type. And we concluded that the heat-treatment in the Ag-atmosphere converted $AgGaS_2$ single crystal thin films to an optical n-type. Also, we confirmed that Ga in $AgGaS_2$ crystal thin films did not form the native defects because Ga in $AgGaS_2$ single crystal thin films existed in the form of stable bonds.

Molecular Characterization and Expression Analysis of Clathrin-Associated Adaptor Protein 3-δ Subunit 2 (AP3S2) in Chicken

  • Oh, Jae-Don;Bigirwa, Godfrey;Lee, Seokhyun;Song, Ki-Duk
    • Korean Journal of Poultry Science
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    • v.46 no.1
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    • pp.31-37
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    • 2019
  • A chicken clathrin-associated adaptor protein $3-{\delta}$ subunit 2 (AP3S2) is a subunit of AP3, which is involved in cargo protein trafficking to target membrane with clathrin-coated vesicles. AP3S2 may play a role in virus entry into host cells through clathrin-dependent endocytosis. AP3S2 is also known to participate in metabolic disease developments of progressions, such as liver fibrosis with hepatitis C virus infection and type 2 diabetes mellitus. Chicken AP3S2 (chAP3S2) gene was originally identified as one of the differentially expressed genes (DEGs) in chicken kidney which was fed with different calcium doses. This study aims to characterize the molecular characteristics, gene expression patterns, and transcriptional regulation of chAP3S2 in response to the stimulation of Toll-like receptor 3 (TLR3) to understand the involvement of chAP3S2 in metabolic disease in chicken. As a result, the structure prediction of chAP3S2 gene revealed that the gene is highly conserved among AP3S2 orthologs from other species. Evolutionarily, it was suggested that chAP3S2 is relatively closely related to zebrafish, and fairly far from mammal AP3S2. The transcriptional profile revealed that chAP3S2 gene was highly expressed in chicken lung and spleen tissues, and under the stimulation of poly (I:C), the chAP3S2 expression was down-regulated in DF-1 cells (P<0.05). However, the presence of the transcriptional inhibitors, BAY 11-7085 (Bay) as an inhibitor for nuclear factor ${\kappa}B$ ($NF{\kappa}B$) or Tanshinone IIA (Tan-II) as an inhibitor for activated protein 1 (AP-1), did not affect the expressional level of chAP3S2, suggesting that these transcription factors might be dispensable for TLR3 mediated repression. These results suggest that chAP3S2 gene may play a significant role against viral infection and be involved in TLR3 signaling pathway. Further study about the transcriptional regulation of chAP3S2 in TLR3 pathways and the mechanism of chAP3S2 upon virus entry shall be needed.

Pressure Dependence on the Aquation of s-cis-[Co(ee)$Cl_2$]+ and s-cis-[Co(eee)$Br_2$]+ ions (s-cis-$[Co(eee)Cl_2$]^+ 및 s-cis-$[Co(eee)Br_2]^+ $착이온의 수화반응에 미치는 압력의 영향)

  • Jong-Jae Chung;Sung-Oh Bek
    • Journal of the Korean Chemical Society
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    • v.32 no.4
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    • pp.318-322
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    • 1988
  • We studied the aquation reaction of s-cis-$[Co(eee)Cl_2]^+$ and s-cis-$[Co(eee)Br_2]^+$ complex ions under the various temperatures and pressures. In these complexes eee is $NH_2-CH_2CH_2-S-CH_2CH_2-NH_2$. The rate law of the aquation reactions of these two complexes obeys $Rate = k_{obsd}$[CO(III)], where rate constants of s-cis-$Co(eee)Cl_2]^+$ and s-cis-$[Co(eee)Br_2]^+$ respectively are $0.687{\times}10^{-4}$ $sec^{-1}$ and $4.10{\times}10^{-4}$ $sec^{-1}$ in condition of 0.1M $HClO_4\;and\;40^{\circ}C$. In the same condition, the activation entropies of s-cis-[Co(eee)$Cl_2$]+ and s-cis-(Co(eee)Br_2$]+ complexes respectively are -15.5 eu and -7.54eu, and the activation volumes are $-4.6cm^3mole^{-1}$ and $-4.2cm^3mole^{-1}$. From these data, we could infer the mechanism of the aquation reaction as the interchange dissociation (Id) mechanism.

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Transparent Electrode Performance of TiO2/ZnS/Ag/ZnS/TiO2 Multi-Layer for PDP Filter (TiO2/ZnS/Ag/ZnS/TiO2 다층막의 PDP 필터용 전극 특성)

  • Oh, Won-Seok;Lee, Seo-Hee;Jang, Gun-Eik;Park, Seong-Wan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.9
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    • pp.681-684
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    • 2010
  • The $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ multilayered structure for the transparent electrodes in plasma display panel was designed by essential macleod program (EMP) and the multilayered film was deposited on a glass substrate by direct-current (DC)/radio-frequency (RF) magnetron sputtering system. During film deposition process, the Ag layer in $TiO_2$/Ag/$TiO_2$ structure became oxidized and the filter characteristic was degraded easily. In this study, ZnS layer was adopted as a diffusion blocking layer between $TiO_2$ and Ag to prevent the oxidation of Ag layer efficiently in $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ structure. Based on the AES depth profiling analysis, the Ag layer was effectively protected by the ZnS layer as compared with the $TiO_2$/Ag/$TiO_2$ multilayered films without ZnS as an antioxidant layer. The 3 times stacked $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ films have low sheet resistance of $1.22{\Omega}/{\square}$ and luminous transmittance was as high as 62% in the visible ranges.

A study of Frequency Distributions by the Action styles (작업환경에서 오는 시력분포 및 고찰)

  • Kang, Hyang Nyeo;Kim, Sung Tae
    • Journal of Korean Ophthalmic Optics Society
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    • v.5 no.2
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    • pp.99-105
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    • 2000
  • The classifying distribution by the action style was opticion 100, photoartist 100, college student 100 for the simple myopic 35%, for the simple myopic astigmatism 2%, for the compound myopic astigmatism 30.6% for the mixed astigmatism 62.6% for the compound hyperopic astigmatism 37.4% for the ratio of emmetropia 22.4% respectively. The retractive erroreye were -0.50~-2.00Dptr for the simple myopia 14%, -2.00~-6.00Dptr 16%, -6.00Dptr 5%, C-0.25(90.180)~C-2.00DptrAxis(90, 180) 2% for the simple myopicastigmatismS-0.25C-0.25DptrAxis(90, 180)~S-1.00C-1.00DptrAxis (90, 180) 22.6%, S-1.00C-1.00 DptrAxis (90, 180)~S-2.00C-2.00DptrAxis(90, 180) 8% for the compound myopic astigmatism. S+0.25C -0.25DptrAxis(90, 180)~S+2.00C-2.00DptrAxis(90,180) 6.2% for the mixed astigmatism. S+0.25C+0.25DptrAxis(90,180)~S+1.00C+1.00DptrAxis(90,180) 3.4%, S+1.00C+1.00DptrAxis(90,180)~S+2.00C+2.00DptrAxis(90,180) 0.34% for the compound hyperopic astigmatism.

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A Study on the Charateristics of the Korean Adult Female Sound According to Sasang Constitution Using PSSC with a Sentence (사상체질음성분석기(四象體質音聲分析機)(PSSC)를 통한 한국인 성인여성(成人女性)의 체질별(體質別) 음향특성연구(音響特性硏究) - 단문(短文)을 중심으로 -)

  • Youn, Ji-Young;Yoon, Woo-Young;Cho, Sung-Eon;Wang, Hyang-Lan;Jeon, Jong-Weon;Kim, Dal-Rae;Yoo, Jun-Sang
    • Journal of Sasang Constitutional Medicine
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    • v.18 no.3
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    • pp.75-93
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    • 2006
  • 1. Objectives and Methods Sasang Constitutional Medicine is the original Korean Medicine. The purpose of this study was to objectify the diagnosis of Sasang Constitution. 212 Women's sentences were analyzed into 228 factors like Pitch, APQ, Shimmer, Octave and Energy, etc. Women's sentences were classified into 3 categories: total group, under 54 years old group and over 55 years old group. 2. Results 1) In Total group Soyangin's Center feq.(3) was significantly high compared with Taeyangin and Taeumin groups. Taeumin's Pitch2 was significantly high compared with Soeumin and Taeyangin groups. Taeyangin's Pitch S.D. was significantly high compared with Soyangin group. Taeyangin's Octave6 was significantly high compared with Soeumin group. There were no significant differences among constitutional groups in APQ and Shimmer segment. On the point of Energy, Taeyangin's G Tot E(1), G# Tot E(1), G dev.(1), G# dev.(1), G Tot E(2), G# Tot E(2), G dev.(4) and G# dev.(4) were significantly high compared with other groups. Soyangin's A#S.D.(2) was significantly high compared with Taeyangin group. Taeyangin's A#S.D.(3) was significantly high compared with Taeumin group. Taeyangin's F S.D.(5), F# S.D.(5) and Max Average were significantly high compared with Soeumin group. Taeumin's Peak3 and Peak4 were significantly high compared with Taeyangin group. Taeumin's PeakValue1 was significantly high compared with Soeumin group. Taeyangin's PeakValue2 was significantly high compared with Soeumin group. Taeyangin's PeakValue3 and PeakValue5 were significantly high compared with Other groups. 2) In Under 54 years old group, there were no significant differences among constitutional groups in APQ, Shimmer and Octave segment. Taeumin's Center freq.(2) was significantly high compared with Taeyangin and Soyangin groups. Taeumin's Pitch(2) and Pitch(3) were significantly high compared with Taeyangin and Soeumin groups. Taeyangin's and Taeumin's Pitch S.D. were significantly high compared with Soyangin group. Taeyangin's and Soyangin's Octave2 were significantly high compared with Taeumin group. On the point of Energy, Taeyangin's and Soyangin's A# S.D.(2) were significantly high compared with Soeumin group. Taeyangin's and Soyangin's G# dev.(1), G# dev.(2) were significantly high compared with Taeumin group. Taeyangin's and Taeumin's F# S.D.(3) were significantly high compared with Soeumin group. Taeyangin's and Soyangin's Max Average were significantly high compared with Soeumin group. Taeumin's Peak3 was significantly high compared with Taeyangin and Soeumin groups. Taeyangin's and Taeumin's PeakValue2 were significantly high compared with Soeumin group. Taeyangin's and Soeumin's PeakValue3 were significantly high compared with Taeumin group. Taeyangin's and Soyangin's PeakValue5 were significantly high compared with Soeumin group. Taeyangin's and Soyangin's PeakValue9 were significantly high compared with Taeumin group 3) In Over 55 years old group, there were no significant differences among constitutional groups in Pitch, APQ, and Peak segment. Soeumin's F Shimmer(1) and F Shimmer(2) were significantly high compared with Taeyangin and Taeumin groups. Soeumin's G# Shimmer(1) and G# Shimmer(2) were significantly high compared with Soyangin group. Taeyangin's Octave5 and Octave6 were significantly high compared with Soeumin group. On the point of Energy, Soyangin's C S.D., F# S.D.(1), F# S.D.(2) and G dev.(2) were significantly high compared with other groups. Soyangin's F# S.D.(3) was significantly high compared with Taeumin and Soeumin groups. Taeyangin's and Taeumin's G# S.D.(2) and G# S.D.(3) were significantly high compared with Soyangin group 3. Conclusions From above result, there is the possibility of efficient standard guide for constitution diagnosis by analysis of voice

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Studies of Sulphate in Portland Cement Clinker (Cement Technology 1971.9)

  • Gutt W.;Smith M. A.
    • Cement
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    • s.51
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    • pp.20-30
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    • 1973
  • 1) electron-microprobe를 응용하여 $CaO-SiO_2-Al_2O_3$ 계에서 생성한 $C_2S$, $C_3S$ 에 존재하는 sulfate의 solid, solution을 정량적으로 구할 수 있었으며 이 결과로 $C_2S$$Al_2O_3$, $SO_3$ 등이 solid soln 등으로 침적되고 이들이 $C_3S$의 생성을 억제한다는 mechanism이 확인되었다. 2) phase equilibrium(상평형)에 의하면 $Na_2SO_4$, $K_2SO_4$는 mineralizer로서 작용하며 $C_3S$ 의 생성을 돕는다. 그러나 $K_2SO_4$$Al_2SO_3$ 가 결합상태로 존재할 경우는 1,400 $^{\circ}C$에서 광범위한 liquid를 생성하며 quenching하면 glass질과 $\beta-C_2S$ 만이 얻어지고 $C_3S$ 는 생성되지 않는다. 또 이를 1,250 $^{\circ}C$ 까지 서냉하면 $C_2S$ 와 Ca, K, Al, S, 등을 함유한 새로운 물질이 생성된다. 3) $CaO-SiO_2-Al_2O_3-Fe_2O_3$ 계에서 $C_3S$ 의 생성에 미치는 $Na_2SO_4$, $K_2SO_4$ 의 영향을 실험실적으로 검토한 결과 complex interaction이 확인되었으며 $Na_2SO_4$ 는 어떤 경우에는 mineralizing effect를 상실한다는 재미 있는 사실이 발견되었다.

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Optical Properties of $CdAl_2S_4 : Co_{2+}$ Single Crystal ($CdAl_2S_4 : Co_{2+}$ 단결정의 광학적 특성)

  • Kim, Hyung-Gon;Kim, Nam-Oh;Son, Kyeong-Choon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.7
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    • pp.382-387
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    • 2000
  • The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals were grown by the chemical transport reaction method using iodine as a transport agent. The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$single crystals were crystallized into a defect chalcopyrite structure. The optical energy gap of the $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals was found to be 3.377 eV and 2.924 eV, respectively, at 300 K. Blue emission with peaks in 456nm~466nm at 280K was observed in the $CdAl_2S_4$ single crystal. Optical absorption and emission peaks due to impurities in the $CdAl_2S_4 Co^{2+}$ single crystal were observed and described as originating from the electron transition between energy levels of the $Co^{2+} ion sited at the Td symmetry point.

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