• Title/Summary/Keyword: S2-

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Synthesis and Characterization of CuInS2 Semiconductor Nanoparticles and Evolution of Optical Properties via Surface Modification (CuInS2 나노 반도체 합성 및 표면 개질을 통한 광학적 효율 분석 연구)

  • Yang, Hee-Seung;Kim, Yoo-Jin
    • Journal of Powder Materials
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    • v.19 no.3
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    • pp.177-181
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    • 2012
  • Copper composite materials have attracted wide attention for energy applications. Especially $CuInS_2$ has a desirable direct band gap of 1.5 eV, which is well matched with the solar spectrum. $CuInS_2$ nanoparticles could make it possible to develop color-tunable $CuInS_2$ nanoparticle emitter in the near-infrared region (NIR) for energy application and bio imaging sensors. In this paper, $CuInS_2$ nanoparticles were successfully synthesized by thermo-decomposition methods. Surface modification of $CuInS_2$ nanoparticles were carried out with various semiconductor materials (CdS, ZnS) for enhanced optical properties. Surface modification and silica coating of hydrophobic nanoparticles could be dispersed in polar solvent for potential applications. Their optical properties were characterized by UV-vis spectroscopy and photoluminescence spectroscopy (PL). The structures of silica coated $CuInS_2$ were observed by transmission electron microscopy (TEM).

The Rate of Superoxide Radical (${O_2}^-$.) Production in Normal Fenton's Reagent at Different pHs (펜톤반응에서 pH의 변화에 따른 superoxide radical (${O_2}^-$.)의 생성)

  • 김용수;공성호;김재호
    • Journal of Soil and Groundwater Environment
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    • v.7 no.2
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    • pp.73-81
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    • 2002
  • In normal Fenton's reagent, the reductive mechanism of carbon tetrachloride (CT) with superoxide radical (${O_2}^-$.) was observed and the rate of ${O_2}^-$. production was investigated as a function of $H_2O$$_2$ concentration and pH. As pH was increased, the rate of 1-hexanol degradation was rapidly decreased from 90% (at pH 3) to 5% (at pH 11). On the other hand, more degradation of carbon tetrachloride was observed at higher pH regimes indicating Fenton's reaction is an oxidant-reductant co-existing system at neutral pHs. The rate of $O_2^{-}$ . production was observed at different $H_2$$O_2$ concentrations and at different pHs. The rate increased from (45.3$\pm$7.8) x $10^{-6}$ M/s to (151.0$\pm$26.2) x $10^{-6}$ M/s ($294mM H_2$$O_2$) at pH 11: the rate 3150 increased from (22.1$\pm$3.8) x $10^{-6}$ M/s at pH 7 to (151.0$\pm$26.2) x $^10{-6}$ M/s at pH 11 with 294mM $H_2$$O_2$, These results showed that Fenton's reagent could be applied at wide pH regimes. Especially, carbon tetrachloride, which can not be easily adsorbed to soils and then can be dissolved into groundwater causing a cancer, could be efficiently treated by Fenton's reagent.reagent.

Size Dependence of the Photo- and Cathodo-luminescence of Y2O2S:Eu Phosphors

  • Sung, Hye-Jin;Ko, Ki-Young;Kim, Hyun Soo;Kweon, Seok-Soon;Park, Jong-Yun;Do, Young-Rak;Huh, Young-Duk
    • Bulletin of the Korean Chemical Society
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    • v.27 no.6
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    • pp.841-846
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    • 2006
  • $Y_2O_2S$:Eu phosphors were synthesized via solid-state reactions. $Y_2O_2S$:Eu phosphor particles of various sizes were obtained by varying the firing temperature and firing time. The photoluminescence properties of these $Y_2O_2S$:Eu phosphors were examined. In addition, the cathodoluminescence properties of the $Y_2O_2S$:Eu phosphors were examined for applied voltages of 3-8 kV. The relationship between the luminescence intensity and particle size of the$Y_2O_2S$:Eu phosphors was investigated. The photoluminescence and cathodoluminescence of the $Y_2O_2S$:Eu phosphors are affected differently by variations in particle size.

Synthesis and Luminescent Characteristics of $BaGa_2S_4:Eu^{2+}$ Phosphor by Solid-state Method

  • Kim, Jae-Myung;Park, Joung-Kyu;Kim, Kyung-Nam;Lee, Seung-Jae;Kim, Chang-Hae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1096-1099
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    • 2006
  • $II-III_2-(S,Se)_4$ structured of phosphor have been used at various field because those have high luminescent efficiency and broad emission band. Among these phosphors, europium doped $BaGa_2S_4$ was prepared by solid-state method and we try to look into an application possibility due to an emissive property of UV region. Also, general sulfide phosphors were synthesized by using injurious $H_2S\;CS_2$ gas. However, this study prepared $BaGa_2S_4:Eu^{2+}$ phosphor is addition to excess sulfur under 5% $H_2/95%\;N_2$ reduction atmosphere. So, this process could large scale synthesis because of non-harmfulness and simple process. The photo-luminescence efficiency of the prepared $BaGa_2S_4:Eu^{2+}$ phosphor increased 20% than commercial $SrGa_2S_4:Eu^{2+}$ phosphor. The prepared $BaGa_2S_4:Eu^{2+}$ could apply to green phosphor for white LED of three wavelengths.

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Interaction of Alkali Oxide and $SO_3$ on $3CaO.SiO_2$ Formation and Microstructure ($3CaO.SiO_2$ 생성반응과 미세조직에 있어서 Alkali Oxide와 $SO_3$의 상호작용)

  • 정해문;최상흘
    • Journal of the Korean Ceramic Society
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    • v.30 no.12
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    • pp.1071-1079
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    • 1993
  • Interaction of alkali oxides and SO3 and C3S formation and microstructure was studied using K2CO3 and Na2CO3 as alkali sources and (NH4)2SO4 for SO3. When SO3/K2O=1.43 as mole ratio, K2O and SO3 react to form K2SO4, this phase is immiscible with other oxide melt and thus could not affect C3S formation as well as its microstructure. In a condition of SO3/K2O 1, C3S crystals were round and grown in a much larger size. With addition of Na2O and SO3 by only 1wt% each, C3S formation was strongly hindered. Since C2S was stabilized by Na+ and SO4-2, it could not react to give C3S formation. However in the condition of SO3/Na2O=1.43, a little amount of C3S was formed. It is considered that small amount of Na2SO4 was formed, this phase was immiscible with clinker liquid, and the C3S crystals were formed locally in the liquid part of relatively low Na2O and SO3 compositions. These crystals had irregular and rough surfaces and contained more inclusions than those grown from K2O.SO3 system.

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Cathodoluminescent properties of rare-earthe-doped $SrGa_2S_4$ thin film phosphors excited with low energy electrons

  • Nakanishi, Yoichiro
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.1015-1019
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    • 2002
  • The deposition of $SrGa_2S_4$ thin film phosphors doped with Ce or Eu aiming at application for FEDs has been carried out by a multi-source deposition technique. A $SrGa_2S_4$ phase was formed by annealing process and $SrGa_2S_4$ thin films which were deposited using a $Ga_2S_3/Sr$ flux ratio larger than 50 and annealed in $H_2$S showed luminance and luminous efficiency of about 1700 cd/$m^2$ and 2.95 lm/W, respectively, with (0.13, 0.10) chromaticity in the activation with Ce, and about 4000 cd/$m^2$ and 7.05 lm/W, respectively, with (0.36, 0.60) under excitation with 3 kV and 60A/$cm^2$. The results obtained this experiment demonstrate the potential of $SrGa_2S_4$ thin film phosphors for FED screens.

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비면허대역용 선박중심직접통신(MX-S2X) 개발현황 및 향후계획

  • 김혜진;김병기;김원용;김부영;심우성
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2023.11a
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    • pp.149-151
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    • 2023
  • MX-S2X(선박중심직접통신)은 선박을 중심으로 한 D2D 통신을 통해 육상·선박·시설의 유기적 연결을 제공함으로써, 해양 분야의 4차 산업혁명에서 해상 통신 기술 인프라로서의 핵심 역할이 가능할 것으로 기대 된다. '초고속해상무선통신망 무설설비 다각화 및 통신연계 기술개발 '의 1단계 3차년도에서는 2차년도에 제작한 MX-S2X 1차 시제품에 대한 기능을 보완하고 ISM 대역의 소출력 요구사항을 만족하기 위한 DSSS을 적용하여 2차 시제품을 구현/제작하고 실제 해상환경에서 성능을 검증한다. 본 논문에서는 MX-S2X 2차 시제품에 대한 1, 2차 실해역 시험결과 및 향후 계획에 대해 공유한다.

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Subcloning of Nodulin 26 Wild Type(S262) and Phosphorylation Site Mutant(S262D) into the Yeast Expression Vector pYES2

  • Cha, Youn-Soo
    • Preventive Nutrition and Food Science
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    • v.2 no.1
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    • pp.61-65
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    • 1997
  • Wild type nodulin 26(nod 26) cDNA(S262) and phodphorylation aite mutant(S262D) were constructed by a yeast expression system using pYES2 plasmids(pTES2-D262 and pTES2-S262D) were sc-reened by restriction mapping with BamHI of KpnI. S262 nod 26 contained a sreine residue at position 262 and S262D nod 26 contained the substitution mutation of serine to aspartic acid residue at position 262 were verified by automated floursent DNA sequencing.

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화학기상증착법을 이용한 $MoS_2$ 증착에 관한 연구

  • Mun, Ji-Hun;Kim, Dong-Bin;Hwang, Chan-Yong;Gang, Sang-U;Kim, Tae-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.116.2-116.2
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    • 2013
  • 최근 그래핀, hexagonal boron nitride (h-BN) 및 $MoS_2$ (molybdenum disulfide)와 같은 2차원 결정 물질들은 무어의 법칙 (Moore's Law)를 뛰어넘어 계속적인 소자의 소형화를 가능케 하고 또한 대면적, 저비용 소자 개발을 가능케 하는 우수한 특성을 가진 차세대 반도체 트랜지스터 소재로 각광받고 있다. $MoS_2$는 bulk 상태일 때는 1.2 eV의 indirect 밴드갭을 가지지만 단층형태일 때는 1.8 eV의 direct 밴드갭을 가지며 dielectric screening 기법 등을 통해 mobility를 향상시킬 수 있는 것으로 연구된 바 있다. 본 연구에서는 화학기상증착(chemical vapor deposition, CVD)법을 이용하여 $MoS_2$박막을 형성하기 위한 기초연구인 Mo전구체의 특성 평가 및 적합한 공정조건 개발 연구를 수행하였다. 사용한 전구체는 $Mo(CO)^6$ (Molybdenum hexacarbonyl)이고, 온도 및 압력, 반응기체($H_2S$, Hydrogen sulfide) 유량 등의 공정 조건 변화에 따른 거동을 Fourier transform infrared spectroscopy (FT-IR) 시스템을 사용하여 측정하였다. 또한 $Mo(CO)^6$의 분자구조를 상용 프로그램인 Gaussian으로 시뮬레이션 하여 실제 FT-IR 측정 결과값과 비교 분석하였다. 화학기상증착법을 이용한 $MoS_2$ 증착조건 최적화를 위하여 다양한 온도, 유량, 압력, 및 기판 종류에 대하여 증착 실험을 수행하였으며, 증착된 샘플은 scanning electron microscope (SEM), Raman spectroscopy를 이용하여 분석하였다.

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On Negative Correlation Bit-to-Symbol(: B2S) Mapping for NOMA with Correlated Information Sources in 5G Systems (5G 시스템에서 상관 정보원의 비직교 다중접속을 위한 음수의 상관관계 계수 B2S 사상)

  • Chung, Kyu-Hyuk
    • The Journal of the Korea institute of electronic communication sciences
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    • v.15 no.5
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    • pp.881-888
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    • 2020
  • In this paper, in order to improve the degraded BER performance of the stronger channel user in non-orthogonal multiple access(: NOMA) with interactive mobile users, we propose the negative correlation bit-to-symbol(: B2S) mapping. First, the closed-form expression for the BER of the negative correlation B2S mapping receiver is derived, and then it is shown that the BER of the negative correlation B2S mapping receiver is improved, compared with those of the ideal perfect successive interference cancellation(: SIC) receiver and positive correlation receiver. Additionally, based on the analytical expression, signal-to-noise(: SNR) gain is calculated, and the superiority of the negative correlation B2S mapping receiver is validated.