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Synthetic Studies on the Nucleophilic Addition of 1-Methyl-5-mercapto-1,2,3,4-tetrazole to Vinylsulfilimines (Vinylsulfilimine유도체에 대한 1-methyl-5-mercapto-1,2,3,4-tetrazole의 친핵성 첨가물에 관한 연구)

  • Tae-Rin Kim;So-Young Lee;Sang-Yong Pyun
    • Journal of the Korean Chemical Society
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    • v.36 no.2
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    • pp.318-323
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    • 1992
  • Following seven new nucleophilic adducts of sulfilimine compounds were prepared by the addition of 1-methyl-5-mercapto-1,2,3,4-tetrazole to vinylsulfilimine derivatives; S-Phenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-p-tolyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-m-tolyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-p-chlorophenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-p-bromophenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine, S-p-methoxyphenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine and S-p-nitrophenyl-S-2-(1-methyl-1,2,3,4-tetrazole-5-thio)-ethyl-N-p-tosylsulfilimine. The structures of these adducts were confirmed by elemental analyses, MP, UV, IR-and NMR-Spectra.

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Phylogeny of Scopolia Jacq. s. str. based on ITS sequences (ITS 염기서열에 의한 미치광이풀속의 계통)

  • Kim, Young-Dong;Paik, Jin-Hyub;Kim, Sung-Hee;Hong, Suk-Pyo
    • Korean Journal of Plant Taxonomy
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    • v.33 no.4
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    • pp.373-386
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    • 2003
  • Internal transcribed spacer (ITS) sequences of nuclear ribosomal DNA were determined for 14 individuals representing eight taxa from Scopolia s. str. and related genera, Anisodus and Atropanthe. We found that the ITS sequences of Korean endemic species, S. parviflora, are significantly different from its allied species, S. japonica. This is contradictory to traditional taxonomic treatments in which those species are regarded as conspecific. S. parviflora exhibited closer relationship to S. carniolica, which is disjunctly distributed in Europe. In spite of substantially high sequence divergence between S. japonica and S. parvlflora/S. carniolica clade, morphological resemblance is evident among the species. Morphological stasis concept (retardation of morphological differentiation or evolution of similar characters among the disjuncts in a similar ecological habitat) was referred to understand this rather unusual evolutionary feature. S. lutescens, another Korean endemic species, shared almost identical ITS sequences with S. parviflora. Lack of diagnostic character distinguishing the taxa suggests that they are conspecific. Anisodus carniolicoides, which was originally described in Scopolia, was grouped with A. luridus and A. tanguticus. The monophyletic Anisodus formed a sister group relationship with a monotypic genus Atropanthe.

Analysis of Contamination Sources of Staphylococcus aureus Related to Perilla Leaves Using Multi-Locus Variable Number of Tandem Repeat Analysis (MLVA) (Multi-Locus Variable Number of Tandem Repeat Analysis (MLVA)를 이용한 들깻잎 중 Staphylococcus aureus의 오염원분석)

  • Kim, Se-Ri;Shim, Won-Bo;Han, Noo Ri;Chung, Duck-Hwa
    • Journal of Food Hygiene and Safety
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    • v.29 no.4
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    • pp.278-284
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    • 2014
  • To investigate the prevalence of Staphylococcus aureus (S. aureus) during production of perilla leaves, a total of 261 samples, including water, soil, surroundings of cultivation and packing, workers, and perilla leaves, was examined.. To trace the contamination sources of S. aureus related to perilla leaves, MLVA (Multi-Locous Variable number of tandem repeat Analysis), which is a very efficient method to discriminate strains with minimum molecular biology equipment was applied to S. aureus isolated from perilla leaves farms. S. aureus was isolated in perilla leaves from 9 of 38 farms at 0-2.92 log CFU/g. S. aureus was also found in working environment, including packing vinyl, worker clothes, irrigation water and hands. The patterns of MLVA of isolates from perilla leaves matched with those of isolates from packing table, irrigation water, packing vinyl, and hands. The isolates were successfully examined and determined by MLVA, thus elucidating S. aureus source and spread.

Photocatalytic Degradation of Rhodamine B, Methyl Orange and Methylene Blue with CdS and CdZnS/ZnO Catalysts under Visible Light Irradiation (가시광선하에서 CdS와 CdZnS/ZnO 광촉매를 이용한 로다민 B, 메틸 오렌지 및 메틸렌 블루의 광분해 반응)

  • Jeon, Hyun Woong;Jeong, Min Gyo;An, Byeong Yun;Hong, Min Seong;Seong, Sang Hyeok;Lee, Gun Dae
    • Clean Technology
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    • v.26 no.4
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    • pp.311-320
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    • 2020
  • In this study, the photocatalytic degradation of rhodamine B (RhB), methyl orange (MO) and methylene blue (MB) was carried out under visible light irradiation using CdS and CdZnS/ZnO photocatalysts prepared by a simple precipitation method. This study focused on examining the effect of physicochemical properties of dye and photocatalyst on the reaction pathway of photocatalytic degradation. The prepared photocatalysts were characterized by XRD, UV-vis DRS and XPS. Both the CdS and CdZnS/ZnO photocatalysts exhibit an excellent absorption in the visible light and the UV light regions. It was observed that the photocatalytic degradation of MO proceeds via the same reaction mechanism on both the CdS and CdZnS/ZnO photocatalysts. However, the photocatalytic degradation of RhB and MB was found to proceed through a different reaction pathway on the CdS and CdZnS/ZnO catalysts. It is interesting to note that MB dimer was formed on the CdS catalyst at the beginning of the photocatalytic reaction, while the MB monomer was degraded during the overall photocatalytic reaction on CdZnS/ZnO. The above results may be mainly ascribed to the difference of band edge potential of the conduction band in the CdS and CdZnS/ZnO semiconductors and the adsorption property of dye on the catalysts.

An OTHBVS Cell Line Expresses the Human HBV Middle S Protein

  • Park, Sung-Gyoo;Guhung Jung
    • Journal of Microbiology
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    • v.37 no.2
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    • pp.86-89
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    • 1999
  • An OTHBVS cell line from HepG2 was established. This cell line stably expresses the human hepatitis B virus (HBV) middle S protein that includes the preS2 region which is important for HBV particle entry into the hepatocyte. To establish this cell line, the middle S open reading frame (ORF), with a promoter located in the 5' region and enhancer located in the 3' region, was cloned downstream from the metallothionine (MT) promoter of the OT1529 vector. In this vector, expression of the middle S protein was constructed to be regulated by its own promoter and enhancer. Expression of the large S protein which contains the preS1 region in addition to the middle S protein was designed to be regulated by the MT promoter. When extracts of OTHBVS cells were examined with an S protein detection kit (RPHA, Korea Green Cross Co.), an S protein was detected. Total mRNA of OTHBVS cell examined by northern blot analysis with an S ORF probe revealed small/middle S transcripts (2.1 kb). When the MT promoter was induced by Zn, large S transcripts (2.4 kb) were detected. The GP36 and GP33 middle S proteins were presumably detected, but large S proteins were not detected by immunostain analysis using anti-preS2 antibody.

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Structural Relationships Among Parents' and Teachers' Autonomy Support, Children's Basic Psychological Needs, and Children's Participation in Decision-Making (부모와 교사의 자율성 지지, 아동의 기본심리욕구, 아동의 의사결정 참여 간의 구조적 관계)

  • Chae, Eun Young;Lee, Jae Yeon
    • Korean Journal of Child Studies
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    • v.38 no.1
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    • pp.139-151
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    • 2017
  • Objective: The purpose of this study was to explore the structural relationships among parents' and teachers' autonomy support, children's basic psychological needs, and children's participation in decision-making. Methods: The participants were 687 elementary school students (5th and 6th grades) in Seoul and Gyeonggi-do. The data were analyzed using SEM. Results: First, parents' and teachers' autonomy support had a direct effect on children's participation in decision-making. Second, parents' and teachers' autonomy support had an indirect effect on children's participation in decision-making through the children's basic psychological needs. Third, children's basic psychological needs mediated the effects of parents' and teachers's autonomy support and children's participation in decision-making. Conclusion: The findings suggest the importance of the mediating effect of children's basic psychological needs, between parents' and teachers' autonomy support and children's participation in decision-making. The findings can be used as an important basis for prospective research and practices for improving children's participation in decision-making.

The Relationship between Young Children's Temperament and Emotion Regulation: The Mediation Effect of Mother's Parenting Stress (유아의 기질과 정서조절능력의 관계: 양육스트레스의 매개효과)

  • Park, Ye Rang;Lee, Joo-Yeon
    • Korean Journal of Childcare and Education
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    • v.13 no.4
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    • pp.1-17
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    • 2017
  • Objective: The purpose of this study was to examine the relationships among young children's temperament, emotional regulation, and their mother's parenting stress. This study also analyzed the mediating effect of mother's parenting stress on the relationship between the other two variables. Methods: A total of 304 mothers with young children that lived in Gwangju and Jeollanamdo participated in this study. The data were analyzed using Pearson's correlation coefficient, hierarchical multiple regression analysis, and the Sobel test. Results: The main results are as follows. First, adaptability temperament was positively correlated with children's emotional regulation and negatively correlated with mother's parenting stress. There was no statistically significant relationship between activity temperament and other variables, whereas regularity temperament had only a significant relationship with emotional regulation. Second, it was found that mother's parenting stress partially mediated between children's adaptability temperament and emotional regulation. Conclusion: The results of this study imply that mother's parenting stress is a very important factor on young children's emotional regulation. Also, the present study suggests that children's adaptability temperament and mother's parenting stress should be considered together in order to improve young children's emotional regulation.

Difference in a venture's performance depending on the initial invested round: Focusing on absorptive capacity and a venture capital's reputation

  • Jeong, Ji-Hye;Kim, Ju-Hui;Nam, Dae-Il
    • 한국벤처창업학회:학술대회논문집
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    • 2017.04a
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    • pp.49-49
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    • 2017
  • This paper provides theory and evidence on how venture capital's (VC's) investment influence on new venture (NV) performance. Despite the wealth of research on the relationship between VC's investment and NV's performance, there are conflicts about whether the VC's investment can contribute to the performance of NV and NV's market value or not. For the accurate measure of the investment effect from VC, this research explored how the venture capital's investment in each development stage affects the NV's performance. The research was based on signaling theory and the theory of information asymmetry and looked for which factors affect a NV's performance. Using a sample of 364 firms went to public from 2000 to 2007, we find NV performance increases as NV acquires initial investment of VC in the early stage of development. While NV's potential absorptive capacity moderates the main relationship positively, we find no indication that NV's realized abortive capacity and NV's reputation have significant effect on the main relationship as moderators.

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Synthesis and Optical Properties of Ca1-xSrxS:Ce Phosphors (Ca1-xSrxS:Ce 형광체의 합성과 광 특성)

  • Heo, Yeong-Deok;Seong, Hye-Jin;Do, Yeong-Rak
    • Journal of the Korean Chemical Society
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    • v.50 no.6
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    • pp.471-476
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    • 2006
  • series of Ca1-xSrxS:Ce phosphors were synthesized by solid-state reactions. The Ca1-xSrxS:Ce phosphors have a strong absorption in region from 430 nm to 470 nm. The emission peaks of CaS:Ce are located at 510 nm and 570 nm. The partial replacement of Ca by Sr in Ca1-xSrxS:Ce causes a blue shift of emission wavelengths. The Ca1-xSrxS:Ce can be used as bluish green and yellow emitting phosphors for white light emitting diodes (LEDs) pumped by the blue LED. We reported the optical properties of Ca1-xSrxS:Ce phosphors for application in phosphor converted white LEDs.

Effect of Consumer′s Characterististics and Involvement on Infant′s Clothing Purchasing Behavior (소비자 특성 및 관여도가 유아복 구매 행동에 미치는 영향)

  • 이경화;나수임
    • The Research Journal of the Costume Culture
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    • v.6 no.4
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    • pp.50-61
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    • 1998
  • This study aims to make clear how consumer's characteristic and involvement in infant's clothing effect on the purchasing behavior. Using questionnaire as a researching tool, I collected the date from 366 housewives who live in Seoul and have kids aged from two to six year-old. The results of the study were as follows : First, they showed a significance on the correlation between sub-variants of involvement in their child's clothing like interest, importance and cognition of danger and those of purchasing behavior like directions to trademark, beauty and practicality, and so that, ti was realized that the involvement have a great effect on their purchasing behavior like. This was of the same opinion that when they think economic significance seriously, they also think practical function importantly. It seems that such a result derived from the fact that infant's clothing is most involved in practicality and economy rather than in trademark, beauty and popularity which are important on adult's clothing because infant's growth is so rapid that it requires to change sooner. Second, as for the correlation between the involvement in their child's clothing and the purchasing behavior according with the consumer's characteristics, they showed a significant correlation according with the consumer's characteristics like husband's profession, average monthly income and monthly expense to purchase infant's clothing. I found, therefore, economic factors like husband's profession, average monthly income and monthly expense to purchase infant's clothing were of most important. It suggests that the higher the consumer's income is, the grater it have an effect on the purchasing behavior.

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