• Journal of the Korean Society of Safety
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• v.28 no.3
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• pp.33-38
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• 2013

Many occupational workers or professionals have to walk on the various floors for a long period of time. The objective of this study was to develop the safety shoes with increased traction through the material selection. In order to fulfill our objective, first, two kinds of filler were selected to compare the wear mechanism at outsole surface. The developed rubber materials were tested with two kinds of portable slip meters. The sample safety shoes with developed rubber materials were also tested with subject in the laboratory. During walking, the safety shoes were naturally abraded with counter surface. The coefficient of friction(COF) was gradually decreased with number of steps to 30,000, while the COF was abruptly increased from 30,000 to 40,000. The experimental results showed that COF tested with silica rubber was at least 10% higher than that with carbon black rubber in wet or detergent condition. It has been well recognized that filler properties play a important role in wet traction in the tire industry. However it has been unclear that filler properties would be decisive factor in safety shoes. Our study shows that silica exhibits a higher slip resistance than carbon black without reference to wear states in wet or detergent condition. So, this results will provide guides for outsole compounders to develop new products and improve product performance.

• Journal of Adhesion and Interface
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• v.4 no.1
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• pp.28-34
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• 2003

Steel tire cords were subjected to plasma polymerization coating of acetylene in order to enhance the adhesion to rubber compounds. Plasma polymerization coating was varied to plasma polymerization coating of acetylene, argon plasma etching+plasma polymerization, or argon plasma. etching+plasma polymerization with Ar carrier gas. Adhesion was evaluated via TCAT samples and compared to those with brass coated tire cord. For durability study, plasma polymer cooled tire cords were aged in lab atmosphere for 1, 3, 5, 10 or 15 days, while TCAT specimens prepared with plasma polymer coated tire cords were aged in distilled water, 10% NaCl solution or $100^{\circ}C$ oven for 1, 2, 3 or 4 weeks. After testing, failure surfaces were analyzed with SEM/EDX. Among the treatments, the highest adhesion was obtained by Ar etching+acetylene plasma. polymerization coating with Ar carrier gas, providing almost same pull-out force as the brass coated tire cords. Upon the aging of the tire cords in the lab atmosphere, brass coated tire cords provided better adhesion than plasma polymer coated tire cords, while the TCAT samples with plasma polymer coated tire cords exhibited similar or slightly superior durability to those with brass coated tire cords.

• Elastomers and Composites
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• v.50 no.2
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• pp.110-118
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• 2015

In this study, diethylaminoethyl methacrylate-styrene-butadiene terpolymer (DEAEMA-SBR), in which diethylaminoethyl methacrylate (DEAEMA) was introduced to the SBR molecule as a third monomer, was synthesized by cold emulsion polymerization. It is expected that amine group introduced to a rubber molecule would improve dispersion of silica by the formation of hydrogen bond (or ionic coupling) between the amine group and silanol groups of silica surface. The chemical structure of DEAEMA-SBR was analyzed using proton nuclear magnetic resonance spectroscopy (H-NMR), Fourier transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC) and differential scanning calorimetry (DSC). Then, various properties of DEAEMA-SBR/silica composite such as crosslink density, bound rubber content, abrasion resistance, and mechanical properties were evaluated. As a result, bound rubber content and crosslink density of DEAEMA-SBR/silica compound were higher than those of the SBR 1721 composite. Abrasion resistance and moduli at 300% elongation of the DEAEMA-SBR/silica composite were better than those of SBR 1721 composite due to the high bound rubber content and crosslink density. These results are attributed to high affinity between DEAEMA-SBR and silica. The proposed study suggests that DEAEMA-SBR can help to improve mechanical properties and abrasion resistance of the tire tread part.

• Elastomers and Composites
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• v.47 no.2
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• pp.121-128
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• 2012

Waste EPDM(W-EPDM) collected from the automotive weather strip and the gasket of a laundry machine has not been effectively recycled. Using this W-EPDM powder and other ingredients, i.e., binder(polyolefin resin, polyolefin elastomer, etc.), filler and additives, various economic rubber composites were made by extrusion. In advance of main experiments, the effects of ultrasonic treatment of W-EPDM on the property of rubber composites, comparison in the property of the composites of W-EPDM with those of virgin and devulcanized EPDM, and waste tire rubber were investigated. Also, the properties of the rubber composites extruded with a 12-screw extruder were compared with those extruded with twin-screw extruder. Various W-EPDM composites for synthetic turf filler and car mat were extruded and injection molded, and 3 main properties of tensile strength, elongation and hardness were investigated to develop economical and proper recipes of the rubber composites.

• Elastomers and Composites
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• v.52 no.2
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• pp.114-130
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• 2017

Enhancing the properties of rubber, such as the tensile strength, modulus, and wear abrasion, by the addition of carbon black and silica as fillers is very important for improving the performance of rubber products. In this review, we summarize the general features of 'the reinforcement of rubber by fillers' and the equations for representing the reinforcement phenomena. The rubber reinforcement was attributed to enhancement of the following: the rubber, bound rubber, formation of networks, and combination between rubber chains and silica followed by entanglement. The reinforcement capability of silica species with different surface and networked states demonstrated the importance of the connection between the silica particles and the rubber chains in achieving high reinforcement. The model involving combination followed by entanglement can provide a plausible explanation of the reinforcement of rubber by carbon black and silica because the combination facilitates the concentration of rubber chains near the filler particles, and entanglement of the rubber chains around the filler particles enforces the resistance against deformation and breakage of rubber compounds, resulting in high reinforcement.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.357-363
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• 2015

The development of the environment-friendly tire that meets the standard requirements according to tire labeling system can be improved through using highly homogeneous silica immobilized zinc oxide nanoparticles. In this study, a considerable amount of nanoporous silica was essentially added into nano zinc oxide to improve the physiochemical properties of the formed composite. The introduction of nanoporous silica materials in the composite facilitates the improvement of the wear-resistance and increases the elasticity of the tread. Therefore, the introduction of nanoporous silica can replace carbon black as filler in the formation of composites with desirable properties for conventional green tire. Herein, mesoporous silica immobilized zinc oxide nanoparticle with desirable properties for rubber compounds was investigated. Composites with homogeneous dispersion were obtained in the absence of dispersants. The dispersion stability was controlled through varying the molar ratio, ageing time and mixing order of the reactants. A superior dispersion was achieved in the sample obtained using 0.03 mol of zinc precursor as it had the smallest grain size (50.5 nm) and then immobilized in silica aged for 10 days. Moreover, the specific surface area of this sample was the highest ($649m^2/g$).

• Resources Recycling
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• v.27 no.1
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• pp.74-83
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• 2018

This study conducted the Life Cycle Assessment(LCA) on waste rubber recycling technology for recovering rubber product from the waste tires. Environmental impacts were assessed for the five categories of impacts: global warming, resource depletion, acidification, eutrophication, photochemical oxide production, and ozone layer depletion. When recycling 1ton of waste tire containing rubber, global warming impact was 1.77E+02 kg $CO_2-eq.$, resource depletion impact was 1.23E+00 kg Sb-eq., acidification impact was 5.92E-01 kg $SO_2-eq.$, eutrophication impact was 1.23E-01 kg $PO{_4}^{3-}-eq.$, photochemical oxide production impact was 3.42E-01 kg $C_2H_4-eq.$, and ozone layer depletion impact was 1.87E-04 kg CFC11-eq. In terms of overall environmental impacts, carbon, softener and electricity the greatest impact, so it is necessary to compare the environmental impacts of the raw materials to replace carbon and softener, and a method to reduce the filler usage in the process is needed. In addition, it is necessary to improve energy efficiency, change to low-energy sources, and apply renewable energy.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.7
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• pp.905-912
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• 2013

Rubber is one of the most commonly used materials in various fields because of its unique viscoelastic properties. Friction occurs when a tire constantly makes contact with the ground. As a result, friction causes wear. The frictional energy caused by friction is a primary factor in the wear mechanism. The frictional energy is affected by various conditions (temperature, roughness of ground, shape of rubber, load, and materials). In this study, the analysis was preceded by considering the vertical load and the horizontal velocity to the rubber using ABAQUS/explicit. The contact pressure, and friction energy are derived using the shear force and slip distance. The actual behavior of the rubber test data were compared with the analysis results.

• Earthquakes and Structures
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• v.27 no.2
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• pp.127-142
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• 2024

The amount of wave propagation through a rubber concrete construction is the subject of the current investigation. Rubber tire waste was used to make two different types of cement mixtures. One type contains sand substitute in amounts ranging from 15% to 60% of the total volume, while the other has gravel with diameters of 3/8 and 8/15 and 15% sand in the same mixture. A wide variety of concrete forms and compositions were created, and their viscous and solid state characteristics were assessed, along with their short-, medium-, and long-term strengths. Diffusion, density, mechanical strength resistance to compressive force, and ultrasound wave propagation were also assessed. The water-to-cement ratio and plasticizer were used in this investigation. In the second part of the study, an analytical model is presented that simulates the experimental model in predicting the speed of waves and the frequencies accompanying them for this type of mixture. Higher order shear deformation beam theory for wave propagation in the rubberized concrete beam is developed, considering the bidirectional distribution, which is primarily expressed by the density, the Poisson coefficient, and Young's modulus. Hamilton's concept is used to determine the governing equations of the wave propagation in the rubberized concrete beam structure. When the analytical and experimental results for rubber concrete beams were compared, the outcomes were very comparable. The addition of rubber gravel and sandy rubber to the mixture both resulted in a discernible drop in velocities and frequencies, according to the data.

• The tire
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• s.64
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• pp.18-21
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• 1976

목하개최중인 오끼나와 국제해양전람회에서 처음으로 신도시교통 시스템이라고 하는 CVS(Computer Controlled Vehicle System)가 실용화되었다. 이 CVS는 동해양박람회장 2km의 전용궤도를 무인으로 콤퓨우터어에 의해서 운전하여 6명승의 전 16대가 연일 아무 트러블도없이 활약, 관계방면의 관심을 집중시키고 있다. 그런데 이 충승 해양박의 CVS에 채용된 차륜이 고무의 타이어란 점에 주목하기바란다. 고무의 타이어라고 하드라도 이 알맹이가 다르다. 어떻게 다른고하니 보통타이어의 알맹이는 공기이며 그 공기가 큰 역할을 하여주고 있는바이나 이 타이어의 경우는 공기의 대신에 포옴러버어(Form Rubber)가 차있다고 하는 점이다. 알맹이가 공기가 아니란 것은 타이어에 있어서 최대의 약점인 빵꾸라고 하는 고장이 없다는 것이다. 최근노우 빵꾸타이어라고 하는 안전타이어의 많은 시작품이 세계각타이어 메이커어로부터 발표되고 있으나 광의로 이「포옴충진타이어」도 그 1종이라고 할 수가 있을 것 같다. 물론 동종의 타이어는 일찍부터 각방면에서 시작연구는 되고 있었으나 용도가 너무나 한정되어 실용화가 충분하다곤 할 수가 없었다. 그러나 구빈고무가 만든 이 포옴 충진타이어는 훌륭하게 오끼나와 해양박에서 실용화된 것이다. 동사기술진의 설명에 의하면 알맹이는 물론이고 모든 면에 있어서 종래의 그것과는 일맥 상통한 것이라고 한다.