• Title/Summary/Keyword: Rubber Mixing

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Properties of SBR Nanocomposites Reinforced with Organoclay/Carbon Black Dual Phase Fillers (카본 블랙/유기화 클레이로 보강된 SBR 나노 복합재료: 모폴로지와 기계적 물성)

  • Kang, B.S.;Kim, W.
    • Elastomers and Composites
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    • v.42 no.1
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    • pp.9-19
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    • 2007
  • In this study, SBR (Styrene-butadiene rubber: solid content: 25 wt%) nanocomposites reinforced with carbon/organoclay(C18-MMT) were manufactured by a latex method. The SBR nanocomposites was made with the dual phase fillers. The mixing ratios, i.e. carbon black/C18-MMT, were 50/0, 49/1, 48/2, 47/3, 45/5, 44/6, 40/10. Total filler content of compounds was restricted to 50 phr. Cure characteristics and mechanical properties of SBR nanocomposites with carbon black and C18-MMT were evaluated. The SBR nanocomposites containing 49/1 ratio of carbon black/C18-MMT showed good dispersity and excellent values of ODR torque, tensile strength, modulus and tear energy. It was found that the improvement of the mechanical properties was mainly due to the reinforcing effect, i.e., the improvement of dispersion of silicates in the rubber matrix.

Rubber Compounds with High Gas Barrier Property by Mixing Nylon 6 to Maleic Anhydride Grafted ENR 50 (무수 말레인산으로 그래프트된 ENR 50에 Nylon 6를 혼합한 기체 고차단성 고무 배합물)

  • Lim, Jong Hyuk;Cho, Ur Ryong
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.770-776
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    • 2013
  • The ENR 50 having the lowest gas permeability was blended with Nylon 6 which exhibits superior gas permeability, excellent wear resistance by using a twin-screw extruder. The blended materials showed the increased gas barrier property and physical properties, but did not yield a great synergistic effect due to low dispersion of Nylon 6 to ENR 50. To improve dispersion of Nylon 6 in the rubber matrix, maleic anhydride (MAH) was grafted to ENR 50. The grafting reaction between MAH and ENR 50 was evidenced using IR spectroscopy. The grafted and blended materials, ENR 50- g-MAH/Nylon 6 compounds, resulted in an enhanced gas barrier property and physical properties compared with compounds without MAH. The compound at 5 phr of MAH showed the highest crosslinking density and the best performances.

Application of Hybrid Seismic Isolation System to Realize High Seismic Performance for Low-rise Lightweight Buildings (저층 경량건물의 고성능 내진을 위한 복합면진시스템의 적용)

  • Chun, Young-Soo
    • Land and Housing Review
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    • v.4 no.2
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    • pp.185-192
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    • 2013
  • This study presents application effects of hybrid seismic isolation system to realize high seismic performance for low-rise lightweight buildings through a non-linear analysis and onsite experiments. The complex seismic isolation system applied in this study is a method of mixing sliding bearing and laminated rubber bearing in order to overcome limitation of laminated rubber bearing in increasing natural period of the whole seismic isolation system. As a result of the non-linear analysis, seismic isolation buildings designed with complex seismic isolation system are safe because its maximum response displacement is within allowable design displacement even for a strong earthquake which rarely occurs and its maximum response shear is less than design seismic force. As a result of the onsite experiment, the rigidity of seismic isolation stories corresponds to approximately 95.8% of the design equivalent stiffness value. This indicates that actual properties of the whole seismic isolation system correspond to design values.

A Study on the Viscoelastic Properties of Rubber Blends for Shoes Outsole (신발 밑창용 고무 블렌드물의 점탄성적 특성에 대한 연구)

  • Park, Cha-Cheol;Pyo, Kyung-Duk
    • Elastomers and Composites
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    • v.45 no.4
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    • pp.309-315
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    • 2010
  • The CIIR blends, which is use for shoes outsole, with SSBR, XNBR and KBR were prepared with various mixing ratio. The viscoelastic properties of these blends, such as tensile modulus, rebound resilience, storage modulus, tan${\delta}$, and creep properties were measured. In the rebound resilience measurement, KBR showed the highest value, which means the lowest energy absorption to stress. As SSBR, XNBR and KBR blends with CIIR, the rebound resilience of the mixtures showed tendency to increase in arithmetic average. In the creep measurement, CIIR showed the highest visconse strain to stress, SSBR and KBR showed lower visconse strain. Maximum tan${\delta}$ peak of CIIR, SSBR and XNBR appeared at $-30^{\circ}C$, $5^{\circ}C$ and $0^{\circ}C$ respectively.

The Physical Properties of Ethylene Vinylacetate Emulsion Mixed with SBR, Urethane, Epoxy and Acryl Latex (아크릴, 에폭시, 우레탄 및 SBR계 라텍스를 혼합한 에틸렌 비닐아세테이트계 에멀젼 수지의 물리적 특성)

  • Suh, Won-Dong
    • Elastomers and Composites
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    • v.35 no.3
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    • pp.196-204
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    • 2000
  • SBR, polyurethane, acryl and epoxy latex were separately mixed with ethylene -vinylacetate emulsion(EVA) in the range of $0{\sim}50wt%$. For the mixtures, the various physical properties such as defoamerability, mechanical property, and water resistance were experimentally examined. The excellent defoamer was BYK-021 and the appropriate use of it was 0.3 phr for the total components. The shrinkage of compounds was influenced by the compatability of resins and the formation of voids. The mechanical properties was related to the cohesive force of resin particles, the coagulation of cement particles and the co-bonding of resin particles with cement particles. Mixing latex separately showed better properties then non-mixing in the shrinkage ratio, flexural strength, adhesive strength, and impact strength. The water resistance of composites mixed with cement was worse than that of EVA resin.

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A Study on the Mixing of Pulverization Matters when the Contrast Medium is connected to the Automatic Injection Device using the Syringe Connector (Syringe Connector를 이용하여 조영제를 자동 주입장치에 연결 시 분쇄물 혼입에 관한 연구)

  • Kim, Hyeon ju;Kim, Ji eun;Han, Yu bean;Choi, Seung hyun;Kang, Yun ki;Jung, Yu jin;Jung, Min young;Lee, Hoo min
    • Journal of the Korean Society of Radiology
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    • v.12 no.6
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    • pp.777-783
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    • 2018
  • The purpose of this study was to investigate the degree of tearing of the rubber when the spike of the syringe connector was connected to the bottle of the contrast medium composed of the rubber compound type and to investigate the presence of the synthetic rubber due to tearing and grinding and the size of the pulverized product when the pulverized matters rubber was detected. As a result, in the case of tearing degree, the front side of the first contact with the end of the syringe connector was torn more than the back side by about $3.14{\pm}0.04mm$, and the pulverized matters was detected on average 7 to 15 on the 10 contrast mediums. The average particle size was measured to be about $7.89{\pm}0.31{\mu}m$. In addition, it is necessary to develop a micro_filter type automatic injection system for blocking off the pulverized matters as well as additional experiments through various experiments and analysis methods, and it is considered that interest of related organizations will be needed in preparation of fatal accidents when pulverized matters is introduced.

The Functionalization and Preparation Methods of Carbon Nanotube-Polymer Composites: A Review (탄소나노튜브-폴리머 복합체의 기능화와 제조방법)

  • Oh, Won-Chun;Ko, Weon-Bae;Zhang, Feng-Jun
    • Elastomers and Composites
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    • v.45 no.2
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    • pp.80-86
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    • 2010
  • Carbon nanotubes (CNTs) exhibit excellent mechanical, electrical, and magnetic properties as well as nanometer scale diameter and high aspect ratio, which make them an ideal reinforcing agent for high strength polymer composites. The functionalized CNTs are believed to be very promising in the fields such as preparation of functional and composite materials. CNT-Polymer composites are expected to have good processability characteristics of the polymer and excellent functional properties of the CNTs. However, since CNTs usually form stabilized bundles due to Van der Waals interactions, are extremely difficult to disperse and align in a polymer matrix. The biggest issues in the preparation of CNT-reinforced composites reside in efficient dispersion of CNTs into a polymer matrix, and the alignment and control of the CNTs in the matrix. There are several methods for the dispersion of nanotubes in the polymer matrix such as solution mixing, bulk mixing, melt mixing, in-situ polymerization and chemical functionalization of the carbon nanotubes, etc. These methods and preparation of high performance CNT-polymer composites are described in this review.

Thermal and Electrical Properties of PS/MWCNT Composite Prepared by Solution Mixing: Effect of Surface Modification of MWCNT (Solution Mixing법에 의한 PS/MWCNT 복합재료의 열 및 전기전도 특성: MWCNT 표면 개질의 영향)

  • Park, Eun-Ju;Lee, Jeong-Woo;Jung, Dong-Soo;Shim, Sang-Eun
    • Elastomers and Composites
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    • v.45 no.1
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    • pp.17-24
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    • 2010
  • Herein, the effect of the dispersion uniformity of the multi-wall carbon nanotube (MWCNT) on the thermal and electrical conductivity of polystyrene (PS)/MWCNT composite was investigated. The PS/MWCNT composites were prepared by solution mixing from dispersions of various MWCNTs in PS/tetrahydrofuran (THF) solution. Three types of MWCNTs were used; pristine MWCNT, hydroxyl functionalized MWCNT, which was functionalized with $KMnO_4$ in the presence of a phase transfer catalyst at room temperature, and pristine MWCNT with BYK-9077 as a dispersant. It was found that the stable dispersion state of MWCNT in PS/THF solutions significantly improved the thermal and electrical conductivity of the ultimate composites. It is noted that the thermal and electrical conductivity of PS/3 wt% pristine MWCNT composite with BYK-9077 were about 9.4 and 30~50% higher than those of PS/3 wt% pristine MWCNT composite, respectively.

Electric Properties of Silicone Rubber on Reinforcing Agent Dependence (보강제 변화에 따른 실리콘 고무의 전기 특성)

  • 이성일
    • Journal of the Korea Safety Management & Science
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    • v.6 no.1
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    • pp.301-309
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    • 2004
  • An inorganic filling agent, ATH (alumina trihydrate) was used to induce inorganic-organic coupling by mixing with stearic acid, acryl silane, vinyl silane as surface treatment agents in order to apply as a high voltage insulating material. Volumetric resistivity was shown to vary with surface treatment agents, and the highest value was obtained in case of the mixture with vinyl silane. The dielectric breakdown intensity was shown to decrease gradually and saturate to a stable value, possibly due to the increase of cross link density in the vinyl radicals introduced to silica surface, resulting in stable dielectric breakdown intensity in the final stages. Tracking and flame retardant properties were also shown to be the best among the samples investigated in this study.

Adaptive tuned dynamic vibration absorbers working with MR elastomers

  • Zhang, X.Z.;Li, W.H.
    • Smart Structures and Systems
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    • v.5 no.5
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    • pp.517-529
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    • 2009
  • This paper presents the development of a new Adaptive Tuned Dynamic Vibration Absorber (ATDVA) working with magnetorheological elastomers (MREs). The MRE materials were fabricated by mixing carbonyl iron particles with silicone rubber and cured under a strong magnetic field. An ATDVA prototype using MRE as an adaptable spring was designed and manufactured. The MRE ATDVA worked in a shear mode and the magnetic field was generated by a magnetic circuit and controlled through a DC power supply. The dynamic performances or the system transmissibility at various magnetic fields of the absorber were measured by using a vibration testing system. Experimental results indicated that this absorber can change its natural frequency from 35Hz to 90Hz, 150% of its basic natural frequency. A real time control logic is proposed to evaluate the control effect. The simulation results indicate that the control effect of MRE ATDVA can be improved significantly.