• Title/Summary/Keyword: Rheological parameters

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Constitutive Equations for Dilute Bubble Suspensions and Rheological Behavior in Simple Shear and Uniaxial Elongational Flow Fields

  • Seo Dongjin;Youn Jae Ryoun
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.131-138
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    • 2005
  • A theoretical model is proposed in order to investigate rheological behavior of bubble suspension with large deformation. Theoretical constitutive equations for dilute bubble suspensions are derived by applying a deformation theory of ellipsoidal droplet [1] to a phenomenological suspension theory [2]. The rate of deformation tensor within the bubble and the time evolution of interface tensor are predicted by applying the proposed constitutive equations, which have two free fitting parameters. The transient and steady rheological properties of dilute bubble suspensions are studied for several capillary numbers (Ca) under simple shear flow and uniaxial elongational flow fields. The retraction force of the bubble caused by the interfacial tension increases as bubbles undergo deformation. The transient and steady relative viscosity decreases as Ca increases. The normal stress difference (NSD) under the simple shear has the largest value when Ca is around 1 and the ratio Of the first NSD to the second NSD has the value of 3/4 for large Ca but 2 for small Ca. In the uniaxial elongational flow, the elongational viscosity is three times as large as the shear viscosity like the Newtonian fluid.

STUDIES ON THE POLY(4,4-TEREPHTHANILIDEALKYLAMIDE)S (II) Rheological properties and Fibre Performance

  • Seung Sang Hwang;Byo
    • Proceedings of the Korean Fiber Society Conference
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    • 1987.06b
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    • pp.11-11
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    • 1987
  • Among other poly(4,4'-terephthanilidealkylamide)s (PTAA's), poly (4,4'-terephthanilideadipamide) (PTAd) gave clear critical concentration curves. For PTAA's with methylene units more than 6, the critical concentration (C*) seemed to be beyond the solubility limit of H₂SO₄. Under shearing conditions, the nematic domains were easily oriented and stretched in the direction of shear , and a fibrillar structure resulted. At low frequencies, a monotollous reduction of loss tangent (tan) was observed as concentration increased. At high frequencies, however, tan was increased above C* again, and showed maximum at saturation concentration (Cs). With increasing temperature, viscosity of isotropic and anisotropic phases was normally decreased, while viscosity of biphases was increased. Plot of complex viscosity (If) against temperature based on rheological measurements exhibited a good correlation with phase diagram constructed by polarizing microscope observations. Rheological parameters suggested the optimum dope concentration of PTAd with inherent viscosity 2.02 at 30oc is in the vicinity of 19.2 wt%, which seemed to agree well with spinning experiments (around 19.4 wt%). In general, effects of spinning and annealing conditions on the mechanical properties of PTAA fibres were most pronounced in PTAd fibre spun from anisotropic spinning dope .

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The Non Newtonian Flow Mechanism and Rheological Properties of Polyurethane Melts (용융 폴리우레탄의 비 뉴톤 유동 메카니즘과 유변학적인 성질)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.423-428
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    • 2009
  • The non-Newtonian flow curves of polyurethane melts were obtained by using a Physica cone-plate rheometer at various temperatures. The rheological parameters were obtained by applying non-Newtonian flow equation to the flow curves for polyurethane samples. When the polyurethane samples are under increasing-decreasing shear rate modes, the hysteresis loop and thixotropic behavior were shown. Polyurethane melts behave as strong gels when they are subjected to shear flow, but when the applied stress surpasses the yield stress, they exhibit non-linear viscoelasticity. Upon decreasing shear rate, its shear stress remains smaller than the values measured in the increasing shear rate mode, because of broken of its structure.

Mechanical analysis of tunnels supported by yieldable steel ribs in rheological rocks

  • Wu, Kui;Shao, Zhushan;Qin, Su;Zhao, Nannan
    • Geomechanics and Engineering
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    • v.19 no.1
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    • pp.61-70
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    • 2019
  • Yieldable steel ribs have been widely applied in tunnels excavated in rheological rocks. For further understanding the influence of yieldable steel ribs on supporting effect, mechanical behavior of tunnels supported by them in rheological rocks is investigated in this paper. Taking into account the deformation characteristic of yieldable steel ribs, their deformation is divided into three stages. In order to modify the stiffness of yieldable steel ribs in different deformation stages, two stiffness correction factors are introduced in the latter two stages. Viscoelastic analytical solutions for the displacement and pressure in the rock-support interface in each deformation stage are obtained. The reliability of the theoretical analysis is verified by use of numerical simulation. It could be concluded that yieldable steel ribs are able to reduce pressure acting on them without becoming damaged through accommodating the rock deformation. The influence of stiffness correction factor in yielding deformation stage on pressure and displacement could be neglected with it remaining at a low level. Furthermore, there is a linearly descending relationship of pressure with yielding displacement in linear viscoelastic rocks.

Cashew Nut Oil: Extraction, Chromatographic and Rheological Characterisation.

  • Vincent Okechuwku ANIDIOBU;Chioma Oluchi ANIDIOBU
    • The Korean Journal of Food & Health Convergence
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    • v.9 no.4
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    • pp.11-18
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    • 2023
  • Oil was extracted from cashew nuts. The physicochemical parameters of the oil were determined. A chromatographic assay of the oil was carried out using Gas Chromatography-Mass Spectrometry. Seventeen compounds were detected: Phenol, Phenol 2-methyl-, Cyclohexene 4, 4-dimethyl-, m-Fluoro-2-diazoacetophenone 4-dimethyl-, Tetradecanoic acid, Phenol 4-octyl-, n-Hexadecanoic acid. Others are 9, 12-Octadecadienoic acid (Z, Z) - methyl ester, Hexadecanoic acid methyl ester, Methyl stearate, Dodecanoic acid methyl ester, 9, 12, 15-Octadecatrienoic acid methyl ester, 9, 12, 15-Octadecatrienoic acid (Z, Z, Z)-, Oleic acid, Octadecanoic acid, Tetracosanoic acid and 9-Octadecenoic acid methyl ester. Among the components are omega three and omega six essential free fatty acids. The rheological profiling and flow properties of cashew nut oil were determined using a Programmable Rheometer. Cashew nut oil exhibits slight dilatant behaviour at the low end of shear rate. The long chain and high molecular weight of its constituents controlled its rheology. Long-chained 9-Octadecenoic acid methyl ester, 9, 12-Octadecadienoic acid (Z, Z) - methyl ester, Tetracosanoic acid and methyl stearate, coupled with their high molecular weights are responsible for the shear thickening effect observed. Two models, Carreau-Yasuda and Ostwald-de Waele Power Law were employed to fit the rheological data. The Carreau-Yasuda model followed well the data.

The observation of permeation grouting method as soil improvement technique with different grout flow models

  • Celik, Fatih
    • Geomechanics and Engineering
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    • v.17 no.4
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    • pp.367-374
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    • 2019
  • This study concluded the results of a research on the features of cement based permeation grout, based on some important grout parameters, such as the rheological properties (yield stress and viscosity), coefficient of permeability to grout ($k_G$) and the inject ability of cement grout (N and $N_c$ assessment), which govern the performance of cement based permeation grouting in porous media. Due to the limited knowledge of these important grout parameters and other influencing factors (filtration pressure, rate and time of injection and the grout volume) used in the field work, the application of cement based permeation grouting is still largely a trial and error process in the current practice, especially in the local construction industry. It is seen possible to use simple formulas in order to select the injection parameters and to evaluate their inter-relationship, as well as to optimize injection spacing and times with respect to injection source dimensions and in-situ permeability. The validity of spherical and cylindrical flow model was not verified by any past research works covered in the literature review. Therefore, a theoretical investigation including grout flow models and significant grout parameters for the design of permeation grouting was conducted in this study. This two grout flow models were applied for three grout mixes prepared for w/c=0.75, w/c=1.00 and w/c=1.25 in this study. The relations between injection times, radius, pump pressure and flow rate for both flow models were investigated and the results were presented. Furthermore, in order to investigate these two flow model, some rheological properties of the grout mixes, particle size distribution of the cement used in this study and some geotechnical properties of the sand used in this work were defined and presented.

1/4 Car Vibration Simulation Using An Empirical MR Damper Model (실험적 MR댐퍼 모델을 사용한 1/4차량 진동 시뮬레이션)

  • Baek, Woon-Kyung;Yang, Bo-Suk;Lee, Jong-Seok;Kang, Tae-Ho;Ryu, Sung-Won
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.05a
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    • pp.638-643
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    • 2005
  • This study is about a semi-active quarter car simulation method including a MR(magneto-rheological) damper. The MR damper was modeled as Spencer model that can capture nonlinear and hysteretic behavior. The parameters of the Spencer model were extracted from a random excitation test and optimum treatment of the test data. Then, a suspension control algorithm based on Sky-hook theory was applied for the quarter car simulation. Also, an experiment was dong using a quarter car simulator to confirm the simulation results with the Spencer MR damper model

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Design of Direct-Shear Mode MR Damper (전단 모드형 자성유체댐퍼의 설계)

  • Kim, Hae-Lan;Lee, Young-Shin;Lee, Eun-Yup;Lee, Gyu-Seop;Oh, Boo-Jin
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.626-631
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    • 2007
  • MR(Magneto-rheological) fluid is smart material that can be changed viscosity by controlling the magnetic field. MR damper with MR fluid can control damping force. It can be used extensively many engineering structures for reducing the effect of dynamic external disturbances. There are three kinds of MR dampers, such as valve mode, direct-shear mode and squeeze mode. In this study, design process of direct-shear mode MR damper with the MR fluid gap was developed. The parameters that used in the direct-shear mode MR damper Informed from the experiment of valve mode MR damper of Lord company. Magnetic analysis with finite element method was performed to find the optimal annular gap.

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Estimation of Degree of Consolidation in Soft Ground Using Field Measurements and Rheology Model (현장 계측치와 유변학적 모형을 이용한 연약지반의 압밀도 추정)

  • Lee, Dal-Won;Yoon, Hyun-Jung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.2
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    • pp.87-96
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    • 2005
  • In this research, an attempt is made to derive the practical estimation of the degree of consolidation in soft clay from field measurements under embankments. For the practical estimation of pore water pressure in soft clay, the elasto-viscous rheological model was proposed, with a transform of parameters and a field geotechnical measurements in southern Korea. By using the rheological properties of soft clays and the dissipation of excess pore water pressure behaviour during step loading, a degree of consolidation or pore water pressure estimation in the future can be performed, and are shown to be generally close to the field measurements of pore water pressure. Finally, a pore water pressure behaviour in soft clay can be explained through measured data in field and the excess pore water pressure data can also be used to estimate settlement.

Performance Evaluation of a Semi-Active ER Damper with Free Piston and Spring (부동피스톤과 스프링을 갖는 반능동 ER댐퍼의 성능평가)

  • Choe, Seung-Bok;Kim, Wan-Gi
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.3 s.174
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    • pp.691-700
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    • 2000
  • This paper presents a novel type of a semiactive damper featuring an electro-rheological(ER) fluid. Unlike conventional cylindrical ER damper, the proposed one has controllable orifices by the intensity of electric fields (We call it orifice type). The dynamic model of the orifice type ER damper is formulated by incorporating field-dependent Bingham properties of an arabic gum-based ER fluid. Design parameters such as electrode gap are subsequently determined on the basis of the dynamic model. After manufacturing the orifice type ER damper, field-dependent damping forces and damping force controllability are empirically evaluated. In the evaluation procedure, conventional cylindrical ER damper is adopted and its performance characteristics are compared with those of the orifice type ER damper. In addition, the proposed one is installed with a full-car model and its vibration control performance associated with a skyhook controller is investigated.