• Title/Summary/Keyword: Rheological Characteristic

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Impact of fine particles on the rheological properties of uranium dioxide powders

  • Madian, A.;Leturia, M.;Ablitzer, C.;Matheron, P.;Bernard-Granger, G.;Saleh, K.
    • Nuclear Engineering and Technology
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    • v.52 no.8
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    • pp.1714-1723
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    • 2020
  • This study aims at characterizing the rheological properties of uranium oxide powders for nuclear fuel pellets manufacturing. The flowability of these powders must be compatible with a reproducible filling of press molds. The particle size distribution is known to have an impact on the rheological properties and fine particles (<100 ㎛) are suspected to have a detrimental effect. In this study, the impact of the particle size distribution on the rheological properties of UO2 powders was quantified, focusing on the influence of fine particles. Two complementary approaches were used. The first approach involved characterizing the powder in a static state: density, compressibility and shear test measurements were used to understand the behavior of the powder when it is transitioned from a static to a dynamic state (i.e., incipient flow conditions). The second approach involved characterizing the behavior of the powder in a dynamic state. Two zones, corresponding to two characteristic behaviors, were demonstrated for both types of measurements. The obtained results showed the amount of fines should be kept below 10 % wt to ensure a robust mold filling operation (i.e., constant mass and production rate).

Comparison of Rheological Properties of Powder Chlorella sp. Cultivated in Fermentor and Pond

  • Kang, Ki-Rim;Lee, Chung-Yung-J.;Lee, Cherl-Ho
    • Journal of Microbiology and Biotechnology
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    • v.12 no.5
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    • pp.740-745
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    • 2002
  • The current study was conducted to identify the differences in the rheological properties of Chlorella sp. powder cultured in a fermentor and in a pond-like environment. Cells. cultured in the same media were harvested and spray dried. The biomass yield from the fermentor culture was 4.7% (dry basis), while that from the pond was 4.3% (dry basis). Measurements of the loose bulk density, tapping test, Hausner's ratio, and compressibility test all revealed differences between the rheological properties of the Chlorella sp. from the two cultivation systems. Although both the fermentor and pond cultured Chlorella sp. showed the same angle of repose, the mean size of the cells was 2.26 $\mu\textrm{m}$ and 2.89 $\mu\textrm{m}$, respectively. The weight of the Chlorella sp. tablets cultured in the fermentor and pond was 0.663 g/tablet and 0.593 g/tablet, respectively, while the friability of the tablets was 21% and 41%, respectively. Observation by Transmission Electron Microscope (TEM) showed that the cell wall of the Chlorella sp. cultured in the fermentor was thinner and more spherical than that cultured in the pond, thereby providing the main characteristic rheological properties of the powder.

Constitutive equation and damping function for entangled polymers

  • Osaki, Kunihiro
    • Korea-Australia Rheology Journal
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    • v.11 no.4
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    • pp.287-291
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    • 1999
  • The tube model theory of entangled polymer presumes that the polymer chain holds its equilibrium contour length under certain conditions of flow; at times longer than a certain characteristic time, ${\tau}_k$, in the stress relaxation process following any flow history; in steady flow of rates smaller than ${{\tau}_k}^{-1}$; etc. Rheological phenomena associated with this presumption are discussed.

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The Rheological Properties of Poly(acrylonitrile)/Cellulose Acetate Blend Solutions in N,N-Dimethyl Formamide (폴리아크릴로니트릴/셀룰로오스 아세테이트/N,N-디메틸포름아미드 용액의 유연학적 특성)

  • Park, Seung-Han;Song, In-Kyu;Kim, Byoung-Chul
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.384-388
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    • 2009
  • The rheological properties of poly (acrylonitrile) (PAN) and cellulose acetate (CA) blend solutions in N,N-dimethyl formamide (DMF) were investigated in terms of temperature and blend composition. The solutions exhibited a very characteristic rheological behavior with variation of temperature. 8 wt% solution showed an increase of viscosity and a decrease of loss tangent as temperature was increased over the temperature range of 20 and $60^{\circ}C$. At $20^{\circ}C$ the physical properties of the solutions exhibited dependence on the blend composition. At 40 and $60^{\circ}C$, however, the effects of blend ratio on the physical properties notably diminished. The longer relaxation time at higher temperature indicated that the formation of physical structures resulting from intermolecular interactions was promoted with increasing temperature. The odd rheological responses were further elucidated by measuring of the physical properties of dilute solutions. The intrinsic viscosity of the solutions suggested that the coiled chain dimension was reduced with increasing temperature.

The Variation Rate of Shear Modulus for Anisotropic Magneto-rheological Elastomer due to Volume Fraction of CIP (CIP 부피비에 따른 이방성 MRE의 전단계수 변화율)

  • Jeong, Un-Chang;Yoon, Ji-Hyun;Yang, In-Hyung;Lee, You-Yub;Oh, Jae-Eung
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.21 no.12
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    • pp.1132-1137
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    • 2011
  • MRE(magneto-rheological elastomers) is a material which shows reversible and various modulus in magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb vibration of broader frequency range. These characteristic phenomena result from the orientation of magnetic particles named carbonyl iron powder(CIP) in rubber matrix. In this paper, simulation on variation rate of shear modulus for anisotropic MRE due to volume fraction of CIP and an effective permeability model was applied to predict the field-induced shear modulus of MREs. Also, the variation rate of shear modulus for anisotropic MRE was derived using magneto-mechanical theory. Based on Maxwell-Garnett mixing rule, the increment of shear modulus was calculated to evaluate the shear modulus of MREs with column structure of CIP due to induced current. The simulation results on variation rate of shear modulus can be applied to the variable mechanical system of MRE such as tunable vibration absorber, stiffness variable bush and mount.

Rheological Properties of Exopolysaccharide Produced by Xanthomonas sp. EPS-1 (Xanthomonas sp. EPS-1이 생산하는 다당류의 리올로지 특성)

  • Son, Bong-Soo;Park, Seok-Kyu;Kang, Shin-Kwon;Lee, Sang-Won;Sung, Nack-Kie
    • Microbiology and Biotechnology Letters
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    • v.23 no.3
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    • pp.269-274
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    • 1995
  • For the screening of a new functional exopolysaccharide, sugar composition and rheological properties of exopolysaccharide produced from Xanthomonas sp. EPS-1 were investigated. The average molecular weight of exopolysaccharide was determined to be approximately 2.l $\times$ 10$^{6}$ dalton. The new exopolysaccharide EPS-1 was composed of mannose, glucose, galactose and gluco- samine. IR analysis showed that the exopolysaccharide EPS-1 was assumed to be polymer with carbohydrates. NMR analysis showed that exopolysaccharide EPS-1 was presumed to be 4 units of sugar and trace of CH$_{3}$ group. Exopolysaccharide EPS-1 solution showed a characteristic of non-Newtonian fluid properties. At the concentration of 1.0%, the consistency index and the flow behavior index were shown at 10.8352 poise-sec and 0.4419, respectively. All dispersions were pseudoplastic fluids described accurately by Power-law model. Exopolysaccharide EPS-1 was highly viscous at low concentration, with good stability over a wide range of pH 5 to 13. The excellent compatibility of exopolysaccharide EPS-1 was represented with salts such as sodium chloride.

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Measurement of Shear Modulus Increment Ratio of Magneto-rheological Elastomer based on Silicon Matrix due to Induced Magnetic field (Silicon Matrix MRE 의 인가자기장에 따른 전단계수 증가율 측정)

  • Oh, Jae-Eung;Roh, Jeong-Joon;Lee, Sun-Hoon;Kim, Jin-Su;Jeong, Un-Chang
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2014.10a
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    • pp.288-291
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    • 2014
  • MRE(Magneto-rheological Elastomer) is a material which shows reversible and various modulus in magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb broader frequency range of vibration. These characteristic phenomena result from the orientation of magnetic particle (i.e., chain-like formation) in rubber matrix. In this study, Silicon was used as a matrix in order to manufacture MREs. Magnetic reactive powder(MRP), having rapid magnetic reaction, was selected as a magnetic particle to give magnetic field reactive modulus. The mechanical properties of manufactured MREs were measured with the application of magnetic field. The analysis of MR effect was carried out by FFT analyzer with various induced magnetic field. As the addition of CIP and induced magnetic field intensity increased, increment of MR effect was observed.

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Rheological Properties of Biopolymer Produced by Bacillus coagulans CE-74 (Bacillus coagulans CE-74가 생산하는 Biopolymer의 물성)

  • Lee, Seon-Ho;Son, Gyu-Mok;Choi, Cheong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.2
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    • pp.198-203
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    • 2000
  • A highly viscous biopolymer from Bacillus coagulans CE-74 was purified and its rheological properties were studied The rheological properties of biopolymers produced by Bacillus coagulans CE-74 were studied at the temperature ranges with 20~8$0^{\circ}C$, at the concentration of 0.5~4.0%, at the pH ranges from 3 to 1 and at the shear rate fo 7.34~73.38 sec-1. The apparent viscosity of biopolymer was decreased with increasing shear rate, and thereby biopolymer showed pseudoplastic characteristics. Biopolymer solution showed a characteristic of non-Newtonian fluid properties. At the concentration of 1%, the consistency index and the flow behavior index were shown at 2.64 poise. sec11 and 0.8571, respectively. All dispersions were pseudoplastic fluids described accurately by Herschel-Bulkley model. The change of the biopolymer viscosity on pH showed the highest value at the pH 7.0 and it showed lower at acidic conditon that at alkaline condition comparatively.

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Mechanical analysis of tunnels supported by yieldable steel ribs in rheological rocks

  • Wu, Kui;Shao, Zhushan;Qin, Su;Zhao, Nannan
    • Geomechanics and Engineering
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    • v.19 no.1
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    • pp.61-70
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    • 2019
  • Yieldable steel ribs have been widely applied in tunnels excavated in rheological rocks. For further understanding the influence of yieldable steel ribs on supporting effect, mechanical behavior of tunnels supported by them in rheological rocks is investigated in this paper. Taking into account the deformation characteristic of yieldable steel ribs, their deformation is divided into three stages. In order to modify the stiffness of yieldable steel ribs in different deformation stages, two stiffness correction factors are introduced in the latter two stages. Viscoelastic analytical solutions for the displacement and pressure in the rock-support interface in each deformation stage are obtained. The reliability of the theoretical analysis is verified by use of numerical simulation. It could be concluded that yieldable steel ribs are able to reduce pressure acting on them without becoming damaged through accommodating the rock deformation. The influence of stiffness correction factor in yielding deformation stage on pressure and displacement could be neglected with it remaining at a low level. Furthermore, there is a linearly descending relationship of pressure with yielding displacement in linear viscoelastic rocks.

"Cohesiveness of Hyaluronic Acid Fillers": Evaluation Using Multiple Cohesion Tests

  • Kyun Tae Kim;Won Lee;Eun-Jung Yang
    • Archives of Plastic Surgery
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    • v.51 no.1
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    • pp.14-19
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    • 2024
  • Background Hyaluronic acid fillers can be manufactured using various processes. They have multiple properties, including their concentration, degree of modification, and rheological data. Cohesion is one such property to evaluate gel integrity; however, there is no standardized method for calculating this parameter. This study aimed to evaluate different tests for calculating hyaluronic acid cohesion and discuss the importance of hyaluronic acid cohesion as a consideration when selecting fillers. Methods The cohesion levels of five different hyaluronic acid fillers with different rheological properties were evaluated and compared using the drop weight, compression, tack, and dispersion time tests. Results The cohesion tests yielded different results in the samples. Samples 2 and 4 showed approximately two times the number of droplets when compared with Sample 5 in drop weight test. Samples 1, 2, 3, and 4 were superior to Sample 5 in tack test. Samples 1, 2, and 3 showed cohesive appearances at 95 seconds in most cases in dispersion test. Rheological test results did not reflect the measures of cohesion. Conclusion Although there are no definite standardized tests to evaluate the cohesion of hyaluronic acid fillers, our proposed tests showed similar results for different hyaluronic acid filler products. Further studies are needed to evaluate the cohesion of hyaluronic acid fillers and determine the clinical use of this distinguishing characteristic for clinicians selecting the product of choice. Level of evidence statement: These data are Level IV evidence.