• Title/Summary/Keyword: Reversible work

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Thermodynamic Analysis of the Diabatic Efficiency of Turbines and Compressors (터빈과 압축기의 비단열 효율에 대한 열역학적 해석)

  • Park, Kyoung Kuhn
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.3
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    • pp.139-148
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    • 2016
  • Thermodynamic analysis is conducted on the first-order approximation model for turbines and compressors. It is shown that the adiabatic efficiency could be greater than unity, depending on the entropic mean temperature, entropy generation, thermal reservoir temperature, and heat transfer. Therefore, adiabatic efficiency applied to a diabatic control volume results in an error overestimating its performance. To resolve this overestimation, it is suggested that a reversible diabatic process be referred to as an ideal process to evaluate diabatic efficiency. The diabatic efficiency suggested in this work is proven to always be less than unity and it is smaller than the exergy efficiency in most cases. The diabatic efficiency could be used as a more general definition of efficiency, which would include adiabatic efficiency.

Biometric Image Cryptographic Algorithm Based on the Property of Wavelet Transform Coefficient (웨이브렛 변환 계수의 특성을 이용한 생체 영상 암호화 알고리즘)

  • Shin, Jonghong
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.12 no.2
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    • pp.41-49
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    • 2016
  • Lossless encryption methods are more applicable than lossy encryption methods when marginal distortion is not tolerable. In this research, the author propose a novel lossless symmetric key encryption/decryption technique. In the proposed algorithm, the image is transformed into the frequency domain using the lifting wavelet transform, then the image sub-bands are encrypted in a such way that guarantees a secure, reliable, and an unbreakable form. The encryption involves scattering the distinguishable frequency data in the image using a reversible weighting factor amongst the rest of the frequencies. The algorithm is designed to shuffle and reverse the sign of each frequency in the transformed image before the image frequencies are transformed back to the pixel domain. The results show a total deviation in pixel values between the original and encrypted image. The decryption algorithm reverses the encryption process and restores the image to its original form. The proposed algorithm is evaluated using standard security and statistical methods; results show that the proposed work is resistant to most known attacks and more secure than other algorithms in the cryptography domain.

Electrochemical Properties of Lithium Sulfur Battery with Silicon Anodes Lithiated by Direct Contact Method

  • Kim, Hyung Sun;Jeong, Tae-Gyung;Kim, Yong-Tae
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.228-233
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    • 2016
  • It is hard to employ the carbon materials or the lithium metal foil for the anode of lithium sulfur batteries because of the poor passivation in ether-based electrolytes and the formation of lithium dendrites, respectively. Herein, we investigated the electrochemical characteristics of lithium sulfur batteries with lithiated silicon anode in the liquid electrolytes based on ether solvents. The silicon anodes were lithiated by direct contact with lithium foil in a 1M lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) solution in 1,2-dimethoxyethane (DME) and 1,3-dioxolane (DOL) at a volume ratio of 1:1. They were readily lithiated up to ~40% of their theoretical capacity with a 30 min contact time. In particular, the carbon mesh reported in our previous work was employed in order to maximize the performance by capturing the dissolved polysulfide in sulfur cathode. The reversible specific capacity of the lithiated silicon-sulfur batteries with carbon mesh was 1,129 mAh/g during the first cycle, and was maintained at 297 mAh/g even after 50 cycles at 0.2 C, without any problems of poor passivation or lithium dendrite formation.

Quantitative estimation of reversibility of the discharge process undergone by nickel hydroxide film cathodically deposited on pure nickel as a positive supercapacitor electrode using cyclic voltammetry and potential drop method

  • Pyun Su-Il;Moon Sung-Mo
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.8-13
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    • 1998
  • This work presents the way how to evaluate the degree of reversibility of the discharging process undergone by the nickel hydroxide film cathodically deposited on pure nickel as a positive electrode for electrochemical capacitor using the combined cyclic voltammetry and potential drop method, supplemented by galvanostatic discharge and open-circuit potential transient methods. The time interval necessary just to establish the current reversal of anodic to cathodic direction from the moment just after applying the potential inversion of anodic to cathodic direction, was obtained on cyclic voltammogram. The cathodic charge density passed upon dropping the applied potential, was calculated on potentiostatic current density-time curve. Both the time interval and the cathodic charge density in magnitude can be regarded as being measures of the degree of reversibility of the discharging process undergone by the positive active material for supercapacitor, i.e. , the longer the time interval is, the lower is the degree of reversibility and the greater the cathodic charge density is, the higher is the degree of reversibility. From the applied potential dependences of the time interval and cathodic charge density, discharge at $0.42 V_{SCE}$ was determined to be the most reversible.

Program Development for Drawing of 26 Properties and System Analysis on T-s Diagram of Water or Vapor (물의 T-s 선도 상에서 26 종류의 물성치 작도 및 시스템 해석 프로그램 개발)

  • Kim, Deok-Jin
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.157-164
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    • 2008
  • The temperature-entropy diagram of water or vapor displays graphically the thermophysical properties, so it is very conveniently used in various thermal systems. On general T-s chart of water, there are temperature, pressure, quality, specific volume, specific enthalpy, specific entropy. However, various state and process values besides above properties can be plotted on T-s diagram. In this study, we developed the software drawing twenty six kinds of properties, that is temperature, pressure, quality, specific volume, specific internal energy, specific enthalpy, specific entropy, specific exergy, exergy ratio, density, isobaric specific heat, isochoric specific heat, ratio of specific heat, coefficient of viscosity, kinematic coefficient of viscosity, thermal conductivity, prandtl number, ion product, static dielectric constant, isentropic exponent, velocity of sound, joule-thomson coefficient, pressure coefficient, volumetric coefficient of expansion, isentropic compressibility, and isothermal compressibility. Also, this software can analyze and print the system values of mass flow rate, volume flow rate, internal energy flow rate, enthalpy flow rate, entropy flow rate, exergy flow rate, heat flow rate, power output, power efficiency, and reversible work. Additionally, this software support the functions such as MS-Power Point.

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Changes in Polyamine Level and Chloroplast DNA Methylation in Chlamydomonas reinhardtii (Chlamydomonas의 Polyamine 함량변화와 엽록체 DNA Methylation)

  • 이순희
    • Journal of Plant Biology
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    • v.37 no.1
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    • pp.101-109
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    • 1994
  • Relationship between polyamine level and DNA methylation in the absence or presence of MGBG(l mM), which is an enzyme-activated reversible inhibitor of SAMDC, has been investigated during gametogenesis of Chlamydomonas. In the absence of MGBG, polyamine levels decreased in Chlamydomonas 137C(+) and 137C(-) during gametogenesis. And polyamine level of 137C(+) was 2-5 times as much as that of 137C(-) and showed a significant decrease unlike that of 137C(-). In vitro, MGBG inhibited ctDNA methylation of 137C(+) by 20-30% but did not inhibited that of 137C(-). Also, MGBG inhibited DNA methylase by 60% in vitro. The results obtained in the present work suggest the possibility that the changes of polyamine level may be associated with ctDNA methylation during gametogenesis of Chlamydomonas.omonas.

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Electrochemical Detection of Glutathione on SAMs on Gold Using an Electroactive Quininoid-Type Molecule

  • Kim, So-Hyun;Kim, Jae-Il;Park, Hye-Ri;Kim, Mi-Kyoung;Chong, Yoo-Hoon;Yeo, Woon-Seok
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2574-2576
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    • 2009
  • In this work, we describe a new sensor that specifically responds to biothiols, i.e., glutathione (GSH), in solution. An electrochemical transducing strategy was utilized and cyclic voltammetry (CV) was employed to monitor the presence of GSH in real time. Our approach harnessed self-assembled monolayers (SAMs) on gold consisting of an alkanethiolate which was terminated by electroactive quininoid moiety. Prior to thiol molecule treatment, the characterisitc reversible redox peaks of the electroactive quininoid group was observed, while the reduction peak was dramatically shifted upon a treatment of GSH. This sensor showed the capability to detect the GSH in solution in the range of 1 mM $\sim$ 100 aM. We believe that this strategy will provide an important tool for accurate, sensitive, rapid, and low-cost determination of GSH.

Dynamic prediction fatigue life of composite wind turbine blade

  • Lecheb, Samir;Nour, Abdelkader;Chellil, Ahmed;Mechakra, Hamza;Ghanem, Hicham;Kebir, Hocine
    • Steel and Composite Structures
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    • v.18 no.3
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    • pp.673-691
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    • 2015
  • In this paper we are particularly focusing on the dynamic crack fatigue life of a 25 m length wind turbine blade. The blade consists of composite materiel (glass/epoxy). This work consisted initially to make a theoretical study, the turbine blade is modeled as a Timoshenko rotating beam and the analytical formulation is obtained. After applying boundary condition and loads, we have studied the stress, strain and displacement in order to determine the critical zone, also show the six first modes shapes to the wind turbine blade. Secondly was addressed to study the crack initiation in critical zone which based to finite element to give the results, then follow the evolution of the displacement, strain, stress and first six naturals frequencies a function as crack growth. In the experimental part the laminate plate specimen with two layers is tested under cyclic load in fully reversible tensile at ratio test (R = 0), the fast fracture occur phenomenon and the fatigue life are presented, the fatigue testing exerted in INSTRON 8801 machine. Finally which allows the knowledge their effect on the fatigue life, this residual change of dynamic behavior parameters can be used to predicted a crack size and diagnostic of blade.

Phase change properties of amorphous $Ge_1Se_1Te_2$ and $Ge_2Se_2Te_5$ chalcogenide thin films. (비정질 $Ge_1Se_1Te_2$$Ge_2Se_2Te_5$ 칼코게나이드박막의 상변화특성)

  • Chung, Hong-Bay;Cho, Won-Ju;Koo, Sang-Mo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.118-119
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    • 2006
  • In the present work, we investigate the basic physical and thermal properties and electrical resistance change due to phase change in chalcogenide-based $Ge_1Se_1Te_2$ and $Ge_2Se_2Te_5$ thin films. The phase transition from amorphous to crystalline states, and vice versa, of $Ge_1Se_1Te_2$ and $Ge_2Se_2Te_5$ thin films by applying electrical pulses have been studied. The reversible phase transition between the amorphous and crystalline states, which is accompanied by a considerable change in electrical resistivity, is exploited as means to store bits of information.

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Binder-Free Synthesis of NiCo2S4 Nanowires Grown on Ni Foam as an Efficient Electrocatalyst for Oxygen Evolution Reaction

  • Patil, Komal;Babar, Pravin;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.30 no.5
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    • pp.217-222
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    • 2020
  • The design and fabrication of catalysts with low-cost and high electrocatalytic activity for the oxygen evolution reaction (OER) have remained challenging because of the sluggish kinetics of this reaction. The key to the pursuit of efficient electrocatalysts is to design them with high surface area and more active sites. In this work, we have successfully synthesized a highly stable and active NiCo2S4 nanowire array on a Ni-foam substrate (NiCo2S4 NW/NF) via a two-step hydrothermal synthesis approach. This NiCo2S4 NW/NF exhibits overpotential as low as 275 mV, delivering a current density of 20 mA cm-2 (versus reversible hydrogen electrode) with a low Tafel slope of 89 mV dec-1 and superior long-term stability for 20 h in 1 M KOH electrolyte. The outstanding performance is ascribed to the inherent activity of the binder-free deposited, vertically aligned nanowire structure, which provides a large number of electrochemically active surface sites, accelerating electron transfer, and simultaneously enhancing the diffusion of electrolyte.