• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2357-2360
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• 2014

Phosphorus-doped soft carbons were successfully prepared by carbonizing petroleum cokes treated with phosphorus acids, such as $H_3PO_2$, $H_3PO_3$, and $H_3PO_4$. The effect of the type of phosphorus acids used on the composition, structure, and electrochemical performance of the soft carbons was extensively investigated. The soft carbons modified with $H_3PO_3$ and $H_3PO_4$ exhibited dramatically improved reversible capacities and outstanding rate capabilities.

• Carbon letters
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• v.12 no.2
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• pp.81-84
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• 2011

A novel experimental set-up allowing quantitative determination of the adsorption capacity of gas molecules on a surface under high-vacuum conditions is introduced. Using this system, the toluene adsorption capacities of various carbon nanostructures were determined. We found that for a give surface area, the adsorption capacities of toluene of multi-walled carbon nanotubes and nanodiamonds were higher than that of activated carbon, which is widely used as an adsorbent of volatile organic compounds. The adsorption of toluene was reversible at room temperature.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.1
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• pp.172-181
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• 1993

Pseudo-Brayton cycle is defined as an ideal Brayton cycle admitting the difference between heat capacities of working fluid during heating and cooling processes. The endo-pseudo-Brayton cycle which is a pseudo-Brayton cycle with heat transfer processes is analyzed with the consideration of maximum power conditions and the results were compared with those of the endo-Carnot cycle and endo-Brayton cycle. As results, the maximum power is an extremum with respect to the cycle temperature and the flow heat capacities of heating and cooling processes. At the maximum power condition, the heat capacity of the cold side is smaller than that of heat sink flow. And the heat capacity of endo-Brayton cycle is always between those of heat source and sink flows and those of the working fluids of pseudo-Brayton cycle. There is another optimization problem to decide the distribution of heat transfer capacity to the hot and cold side heat exchangers. The ratios of the capacies of the endo-Brayton and the endo-pseudo-Braton cycles at the maximum power condition are just unity. With the same heat source and sink flows and with the same total heat transfer caqpacities, the maximum power output of the Carnot cycle is the least as expected, but the differences among them were small if the heat transfer capacity is not so large. The thermal efficiencies of the endo-Brayton and endo-Carnot cycle were proved to be 1-.root.(T$_{7}$/T$_{1}$) but it is not applicable to the pseudo-Brayton case, instead it depends on comparative sizes of heat capacities of the heat source and sink flow.w.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.1
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• pp.349-354
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• 1991

The power output behavior of the binary cycle composed of two Carnot cycles is analyzed with considering heat transfer processes, in which the finitely constant temperature differences between heat sources and working fluids exists. The power output has the maximum value as an extremum for cycle temperatures and capacities of heat exchangers. In the internally reversible cycle, the power output is independent of the cycle temperature in the intermediate heat exchanger. In this case when the total capacities of heat exchangers are given, three heat exchangers have the same capacities at the maximum power output condition. In addition, when the cycle is not extremum for cycle temperatures and capacities of heat exchangers. At the maximum power output condition, the capacity of heat exchanger at the cold side is slightly more than the hot side as the cycle effectiveness decreases.

• 제어로봇시스템학회:학술대회논문집
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• 1991.10b
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• pp.1873-1878
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• 1991

An high-speed isothermal calorimeter which can trace the progress of a liquid phase reversible reaction was constructed using analog and digital computer. By means of a set point change of the calorimeter, the thermal energy capacity and the heat of reaction in reversible reaction mixture can be measured. The heat of reaction between 2-methyl furan and maleic anhydride and the heat capacities of the adduct were 61,200 J/mol and 2.38 J/ g K, respectively. Also reaction equilibrium constant and reaction rate constants can be estimated from the response curves of the calorimeter.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 2007.02a
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• pp.127-133
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• 2007

We propose new reversible watermarking method for images. Being reversibility, original image and watermarked message should be recovered exactly. We propose different technique for hiding data to pairs. We use new type of histogram (pair histogram), which shows frequencies of each pair in image. We use histogram shift method for data embedding to pairs. We also propose improved version of method which allow hiding data with good performance for high capacities. This algorithm has better result compare to Tian's difference expansion method based on the Haar wavelet decomposition. For proposed algorithm capacity is higher under same PSNR.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.2
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• pp.275-284
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• 1997

Thermodynamic behavior of a composite system which is composed of two simple thermal subsystems with constant heat capacities is analyzed, and several thermodynamic phenomena are investigated. The changes of the states and the potential work of the composite system are shown as the interaction between the subsystems in the composite system. The potential work is defined as the possible maximum available work from the composite system, and it is a thermodynamic property of the composite system. The decrease of the potential work is the same as the available work output from the composite system in reversible processes. The dissipation of available work is directly connected to the generation of entropy. The concepts of exergy and internal energy can be explained as a special case of the potential work.

• Journal of Electrochemical Science and Technology
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• v.10 no.1
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• pp.55-60
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• 2019

Herein, the effect of counter anions on the formation of a solid electrolyte interphase (SEI) in a propylene carbonate (PC)-based electrolyte solution was investigated. Although the reversible capacities were different, reversible intercalation and de-intercalation of lithium ions occurred in the graphite negative electrode in the PC-based electrolyte solutions containing 1 M $LiClO_4$, $LiPF_6$, $LiBF_4$, and $LiCF_3SO_3$ at low temperature ($-15^{\circ}C$). This indicated that the surface films acted as an effective SEI to suppress further co-intercalation and decomposition reactions at low temperature. However, the SEIs formed at the low temperature were unstable in 1 M $LiPF_6$ and $LiBF_4/PC$ at room temperature ($25^{\circ}C$). On the other hand, increasing reversible capacity was confirmed in the case of $LiCF_3SO_3/PC$ at room temperature, because the SEI formed at the low temperature was still maintained. These results suggest that counter anions are an important factor to consider for the formation of effective SEIs in PC-based electrolyte solutions.

• Journal of the Korean Electrochemical Society
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• v.7 no.1
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• pp.1-8
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• 2004

This paper deals with the recent development of high-voltage cathode materials of mono- and di- metal ions substituted spinel $LiMn_2O_4$ for lithium batteries. $LiCu_xMn_{2-x}O_4(0{\leq}x{\leq}0.5)$ shows reversible intercalation/deintercalation in two potential regions, $3.9\~43\;and\;4.8-5.0V$ and stable electrochemical cycling behavior but with low capacity. $LiNi_{0.5}Mn_{1.5}O_4$ obtained by a sol-gel process delivers a capacity of 127mAh $g^{-1}$ on the first cycle and sustains a value of 124 mAh $g^{-1}$ even after the 60th cycle. The $Li_xCr_yMn_{2-y}O_4(0{\leq}x{\leq}0.5)$ solid-solutions exhibit enhanced specific capacity, larger average voltage, and improved cycling behaviors for low Cr content. $LiCr_yMn_{2-y}O_4$ presents a reversible Li deintercalation process at 4.9V, whose capacity is proportional to the Cr content in the range of $0.25{\leq}x{\leq}0.5$ and delivers higher capacities. $LiM_yCr_{0.5-y}Mn_{1.5}O_4(M=Fe\;or\;Al)$ shows that the capacity retention is lowered compared with lithium manganate. The cumulative capacities obtainable with Al-substitutted materials are less than those with Fe-substituted materials. $LiCr_xNi_{0.5-x}Mn_{1.5}O_4(x=0.1)$ delivers a high initial capacity of 1$152mAh\;g^{-1}$ with excellent cycleability.

• Journal of the Korean Ceramic Society
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• v.40 no.11
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• pp.1085-1089
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• 2003

In the present study effects of SnO$_2$-impregnation on the cell performance of Mesocarbon Microbeads (MCMB) electrode in the Li-ion battery have been investigated. Sn element was impreganted into MCMB powders by the chemical titration, and then post annealed at 250$^{\circ}C$ for 1 h in ambient atmosphere to be transformed as tin-oxide. From the measurement for the cell performance with the half cell in which the SnO$_2$-impregnated MCMB was used as an anode, the SnO$_2$-impregnated MCMB showed higher charge/discharge capacities, higher reversible specific charge capacity and better cycleability than a raw MCMB. As the amount of impregnated SnO$_2$ increased, both reversible and irreversible capacities increased.