• 제목/요약/키워드: Retention

검색결과 5,595건 처리시간 0.035초

Study of Retention in Micellar Liquid Chromatography on a C18 Column on the Basis of Linear Solvation Energy Relationships

  • Tian, Minglei;Row, Kyung-Ho
    • Bulletin of the Korean Chemical Society
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    • 제29권5호
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    • pp.979-984
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    • 2008
  • In this study, 8 solutes (aniline, caffeine, p-cresol, ethyl benzene, methylparaben, phenol, pyridine, and toluene) have been tested in terms of linear solvation energy relationships (LSER). Several micellar liquid chromatography (MLC) systems using cationic surfactant cetyltrimethylammonium bromide (CTAB) and a mixture of water with (methanol, n-propanol, and n-butanol) modifiers were characterized using the LSER solvation parameter model. The effects of the surfactant and modifier concentration on the retention in MLC were discussed. LSER model had demonstrated high potential to predict retention factors with high squared correlation coefficients ($r^2$ > 0.99). A comparison of predicted and experimental retention factors suggests that LSER formalism is able to reproduce adequately the experimental retention factors of the solutes studied in the different experimental conditions investigated. This model is a helpful tool to understand the solute-surfactant interactions and evaluate the retention characteristic of micellar liquid chromatography.

Effect of SDS on Retention of Nucleic Acid Components in High-Performance Liquid Chromatography

  • Kim Yong-Nam;Choi Kyeung-Soo;Lee Dai-Woon;Phyllis R. Brown
    • Bulletin of the Korean Chemical Society
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    • 제13권3호
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    • pp.240-245
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    • 1992
  • The effect of the addition of sodium dodecyl sulfate (SDS) to a buffered mobile phase (pH 3.4) on the retention of nucleotides, nucleosides and bases was investigated with a polyvinyl alcohol (PVA) column. Depending on the concentration of SDS, two different trends in the retention of nucleosides and bases containing an $NH_2$ group were observed. If the concentration of SDS was less than 5.5 mM, the retention of compounds containing an $NH_2$ group increased as the concentration of SDS in the mobile phase increased. In contrast, if the concentration was greater than 5.5 mM, the retention of compounds containing an $NH_2$ group decreased. Thus, the SDS acted as an ion-pairing reagent at lower concentration but formed micelles at higher concentrations. The retention behavior of the nucleosides and bases in the presence of a micellar concentration of SDS in the mobile phase on the PVA column was compared to the retention behavior on other types of columns.

조리전 전처리 방법에 따른 시래기의 무기성분의 변화 (Effect of Pre-Treatment Methods before Cooking on Mineral Retention in Siraegi (Raddish Leaves))

  • 박세원;유양자
    • 한국식품조리과학회지
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    • 제13권5호
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    • pp.635-638
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    • 1997
  • Dried raddish leaves were prepared by using three different pre-treatment methods (shady sun-drying, freezing after blanching, and shady sun-drying after blanching). Then, the retention of minerals in dried raddish leaves was determined. It was shown that the retention of most minerals (Na, K, Fe, Ca, Mg) except P was higher when shady sun-drying method was used. The retention of P was shown to be the lowest when freezing after blanching method was used.

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절개사면에 설치된 앵커지지 합벽식 옹벽의 변형거동 (The Deformation Behavior of Anchored Retention Walls installed in Cut Slope)

  • 윤중만;송영석
    • 지질공학
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    • 제19권4호
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    • pp.475-482
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    • 2009
  • 절토사면에 설치된 흙막이벽의 거동은 도심지 굴착공사에 적용된 흙막이벽의 거동과는 다를 것이다. 배면경사지에 설치된 흙막이벽 설계법을 확립하기 위하여는 흙막이벽 및 배면지반의 변형거동을 상세히 규명할 필요가 있다. 따라서, 본 연구에서는 아파트 신축부지 절개사면의 보강을 위하여 앵커지지 흙막이벽과 억지말뚝이 설치된 사면을 대상으로 계측을 수행하였다. 계측결과 굴착초기에는 흙막이벽의 변형이 배면경사지반의 변형보다는 크게 발생되나, 굴착깊이가 깊어짐에 따라 배면경사지반의 변형이 크게 발생되었다. 이는 굴착으로 인한 흙막이벽의 변형이 흙막이말뚝의 강성과 앵커인장력에 의하여 억제되었기 때문으로 판단된다. 앵커에 도입된 선행인장력은 흙막이벽의 거동에만 큰 영향을 미치며, 강우로 인한 흙막이벽의 변형은 지하수위의 변화보다 지표부근에서 침투된 침투수의 영향이 큰 것으로 나타났다. 한편, 굴착배면의 경사진 사면에 설치된 앵커지지 흙막이벽의 수평변위는 굴착배면지반이 수평인 흙막이 굴착의 경우 보다 2~6배 정도 크게 발생하였다.

절개사면에 설치된 앵커지지 흙막이벽의 변형거동 (The Deformation Behavior of Anchored Retention Walls in Cut Slope)

  • 송영석;이재호;김태형
    • 지질공학
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    • 제15권2호
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    • pp.155-168
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    • 2005
  • 절개사면에 설치 된 흙막이벽의 거동은 도심지 굴착공사에 적용된 흙막이벽의 거동과 다르다. 배면경사지 설치된 흙막이벽 설계법을 확립하기 위하여는 흙막이벽 및 배면지반의 변형거동을 상세히 규명할 필요가 있다. 따라서, 본 연구에서는 아파트 신축부지 절개사면의 보강을 위하여 앵커지지 흙막이벽과 억지말뚝이 설치된 사면을 대상으로 현장계측을 수행하였다. 계측결과 굴착초기 흙막이벽의 변형은 배면경사지반의 변형보다 크게 발생되지만, 굴착깊이가 깊어짐에 따라 배면경사지반의 변형이 크게 발생됨을 알 수 있다. 이러한 이유는 굴착초기에 흙막이벽의 변형이 흙막이 말뚝의 강성과 앵커인장력에 의하여 억제되었기 때문으로 판단된다. 앵커에 도입된 선행인장력은 흙막이벽의 거동에만 큰 영향을 미치며, 강우로 인한 흙막이벽의 변형은 지하수위의 변화보다 지표면 부근에서의 침투수에 의해 영향을 받는다 한편, 굴착배면의 경사진 사면에 설치된 앵커지지 흙막이벽의 수평변위는 굴착배면지 반이 수평인 흙막이벽의 수평변위 보다 2-6배정도 크게 발생하였다.

절개사면에 설치된 앵커지지 합벽의 변형거동 및 사면안정효과 (Deformation Behavior and Slope Stability Effect of Anchored Retention Walls Installed in Cut Slope)

  • 홍원표;한중근
    • 한국지반공학회논문집
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    • 제20권9호
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    • pp.57-64
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    • 2004
  • 절개사면에 설치된 앵커지지 흙막이벽의 설계법을 확립하기 위해서는 흙막이벽체 및 배면지반의 변형거동을 규명할 필요가 있다 따라서, 본 연구에서는 아파트 신축부지 절개사면의 보강을 위해 앵커지지 흙막이벽과 억지말뚝이 설치된 사면을 대상으로 계측을 수행하였다. 굴착단계별 앵커설치시 흙막이벽의 수평변위는 감소하고 상대적으로 배면지반의 변형은 증가하는 경향이 있다. 앵커력 도입시 흙막이벽의 수평변위는 전반적으로 감소하며, 앵커의 인장력은 흙막이벽의 변형에는 큰 영향을 미치지만 배면지반의 변형에 미치는 영향은 크지 않았다. 흙막이벽의 최대수평 변위는 굴착깊이의 $1~4\%$사이에 발생하며, 암반굴착면을 갖는 배면수평면인 앵커지지 흙막이벽의 최대수평변위보다 $2\~8$배정도 크게 발생된다. 한편, SLOPILE(Ver 3.0)프로그램을 이용하여 앵커지지 흙막이벽의 사면안정효과를 검토하였으며, 사면안정해석시 앵커지지 흙막이말뚝에 작용하는 측방토압은 배면수평면인 앵커지지 흙막이벽에 적용하는 경험토압의 평균값이 적용가능하다.

산후체증정체(Postpartum Weight Retention)관련 국외 연구논문 분석 (An Analysis of Research on Postpartum Weight Retention)

  • 이성은;유은광
    • 여성건강간호학회지
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    • 제9권3호
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    • pp.287-298
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    • 2003
  • Purpose: To explain the concept of postpartum weight retention and to analyze factor effect on it. Method: A total of 20 studies related postpartum weight retention were selected in the year of 1988-2001 and analysis was done. Result: A demographic factor like parity, age, social and economic level and life style such as exercise, diet, breast feeding are influential factor on postpartum retention weight. But parts of them don't agree the same results. Meanwhile, in some studies, psychological factor like women's self esteem related to postpartum retention weight, body image change, depressing is found to be very related. As a result, postpartum overweight gain could be a bad factor of physical and mental health. In Korea, we have few studies related to them. Conclusion: It is required to do many-sided and deep studies about aspects of postpartum retention weight and the factor that effect on it. Postpartum retention weight should be approached by controling weight from the period of pregnancy. And it would rather be researched through individual approach considered women's various demographic, social-cultural and physical level than be required standardized level of weight gain.

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레진 인공치아의 재부착 방법에 따른 전단결합강도에 관한 연구 (A Study on the Shear Bond Strength of Resin Artificial Tooth Depending on Repair Techniques)

  • 김익중;이종혁;조인호
    • 구강회복응용과학지
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    • 제21권2호
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    • pp.143-151
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    • 2005
  • The purpose of this study was to evaluate the most effective method for repairing the exfoliated resin teeth. The specimens were divided into five groups according to repair method and presence of retention holes. The groups were as follows Group1 : Control group Group2 : Sprinkle method with no retention holes Group3 : Sprinkle method with retention holes Group4 : Flask method with no retention holes Group5 : Flask method with retention holes The results were as follows. 1. According to shear bond strength, the value decreased in the order of group1, group5, group3, group2, group4 and there were significant difference between, each group except between group1 and groups5, group2 and group3, group2 and group4(p < 0.05). 2. According to observations of the exfoliation surface, group2 and 4 showed more failure in the denture base resin and repair resin interface, but in group1, 3 and 5 there were more mixed failures. From the results above, there were no significant difference between repair methods without retention holes. But when comparing groups with retention holes, the flask method showed significantly improved results compared to the sprinkle method. Especially, group5 showed similar results as the control group.

3D 프린터를 이용한 회전 버킷이 부착된 저류조의 모형 실험 (Scaled Down Experiment of Retention Basin with a Rotatable Bucket Using 3D Printer)

  • 박성직;이창구;이제명;최원
    • 한국농공학회논문집
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    • 제59권2호
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    • pp.49-55
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    • 2017
  • Recently climate change and urbananization have been increased surface runoff, resulting in flooding. Retention basins have been constructed to control urban flooding by reducing peak flow rate. Recently, the retention basin plays a role in controlling combined sewer overflows (CSOs) as well as urban flooding. In this study, the retention basin with a rotatable bucket was suggested and scale down experiments was performed for the optimum design of the retention basin. Scaled down model was produced using a 3D printer after it was designed as law of similarity. Two times for operating a rotary bucket is required to sweep out the sediments deposited on the bottom of the basin. Optimized dimensions for the retention basin were width of 5 m, height of 5 m, bucket radius of 0.5 m, and bottom slope of 5.0 %. It can be concluded that the results obtained from this study can be used to design the retention basin with a rotatable bucket which does not require energy to operate.

수 종의 지각 과민 완화제가 인산 아연 시멘트 사용시 주조관의 유지력 및 적합도에 미치는 영향 (THE EFFECT OF VARIOUS DESENSITIZING AGENTS ON RETENTION AND FITNESS OF CEMENTED CROWNS WITH ZINC PHOSPHATE CEMENT)

  • 오세욱;이호용
    • 대한치과보철학회지
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    • 제32권2호
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    • pp.181-194
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    • 1994
  • The purpose of this study was to compare the retention and fitness of crown treated with various desensitizing agents on natural teeth. Varnish, dentin primer, bonding agent and potassium oxalate treated groups and control group with no treatment were used. The retention test was executed with the Instron test machine(Instron Co.,U.S.A.) on 24 hours after cementation with zinc phosphate cement. After retention test, the teeth and crowns were washed and recemented. The cemented crowns were embedded in clear resin and sectioned with a diamond saw. The occlusal and marginal fitnesses, were measured indirectly with a stereomicroscopic photographs. The result of this study were obtained as follows : 1. The retention of control group was higher than any other desensitizing agent treated group. 2. The differences of retention among varnish, dentin primer, bonding agent and potassium oxalate treated groups were not statistically significant. 3. There were no statistically significant difference in fitness at occlusal surface and margin among control, varnish, dentin primer, bonding agent and potassium oxalate treated groups. According to these results, desensitizing agents used to protect the pulp from irritation of luting agents may adversely affect the retention of castings. Therefore, desensitizing agents should be used in limited areas carefully.

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