• Korean Journal of Food Science and Technology
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• v.31 no.1
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• pp.30-35
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• 1999

A simple, rapid, efficient method is for extraction of 13 synthetic water-soluble food colours (Tartrazine, Amarnth, Indigo carmine, New coccine, Sunset yellow FCF, Allura red AC, Eosine, Fast Green FCF, Brilliant Blue FCF, Erythrosine, Acid red, phloxine, Rose Bengal) by polyamide resin and for their quantitative by high performance liquid chromatography (HPLC). Colours (coal-tar dyes) were extracted with polyamide resin and then determinated by HPLC. The HPLC conditions using a reverse phase partition type column $(Nova-pak\;C_{18})$, photodiode array (PDA) detector and 1% Ammonium acetate / 60% acetonitrile in water as eluent, were acceptable for various kinds of colorants. By the use of the proposed method, a survey of coal-tar dyes was carried out on 20 samples and that were detected $4.76{\sim}133.47\;ppm$.

• Journal of the Korean Chemical Society
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• v.17 no.1
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• pp.60-66
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• 1973

When m-phenylenediamine (MPD) or m-aminophenol (MAP) was treated with formaldehyde(F), under $N_2$ stream, at the temperature $-5\sim0^{\circ}C$, addition condensation occurred and insoluble resins formed immediately. Under the same reaction conditions m-phenylenediamine, m-aminophenol and formaldehyde also easily copolycondensed and insoluble MPD-MAP-F type copolymer formed. MPD-MAP-F type copolycondensed resin was superior in both heat-resistant property and adsorptivity of Bromophenol Blue or Methylene Blue than the MPD-F and MAP-F type resins. From the result of TGA, under $N_2$stream, MPD-MAP-F resin showed about $40\%$ weight loss at $800^{\circ}C$, and this type of resin 1g adsorbed 308mg of Bromophenol Blue.

• Journal of the Korean Chemical Society
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• v.25 no.3
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• pp.160-165
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• 1981

Radical copolymerization of the complexed 2-vinylpyridine with vinyl acetate and divinylbenzene initiated by azobisisobutyronitrile was carried out in N, N-dimethylformamide in presence of barium chloride at $98{\circ}C$. In the preparation of 2-vinylpyridine-vinylacetate-divinylbenzene terpolymer, the optimum reaction conditions were studied by means of various temperatures and times. 2-vinylpyridine-vinylalcohol-divinybenzene resin was prepared by transesterificating 2-vinylpyridine-vinylacetate-divinylbenzene terpolymer with a 1% methanolic sodium hydroxide solution. 2-Vinylpyridine-vinylphosphate-divinyldenzene was prepared by phosphorylating 2-vinylpyridine-vinylalcohol-divinylbenzene resin with phosphoric acid and urea. The compositions of each synthetic resin were identified by means of infrared absorption spectroscopy. The ion exchange capacities of each 2-vinylpyridine-vinylalcohol-divinylbenzene and 2-vinylpyridine-vinylphosphate-divinylbenzene terpolymer was 3.69 meq/g and 5.38 meq/g.

• Journal of the Korean Chemical Society
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• v.24 no.2
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• pp.129-138
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• 1980

The formation constants of the mixed-ligand complexes in the Cd(II), Cu(II) and Pb(II)-Trien-OH system were studied by polarograph. The formation constant $(log{\beta}_{ij})$ was determined at $25^{\circ}C$ in the ionic strength of 0.1. It was also confirmed that the mixed ligand complexes in this system were formed above pH 10.2, 10.5 and 9.0 for Cu(II), Cd(II) and Pb(II) by the calculation of the distribution for complexes at the various pH. Masking of Cd(II) by conversion to anionic EDTA-complexes has been used to separate Cu(II) from Cd(II) through passage of a combined Trien-EDTA solution on an cationic resin column. The optimal condition for the separation of Cu(II) from Cd(II) is confirmed at the pH range above 9.0, not only by considering the theoretical equation of the conditional-exchange-constant of metal on the cation exchange resin,but also by calculating the distribution of the mixed ligand complexes in the resin at the various pH with computer. By analyzing the synthetic sample of Cu(II) and Cd(II) with a EDTA masking at pH 9.5, it is found that the results of the experiment are satisfied with the theoretical value.

• Applied Chemistry for Engineering
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• v.19 no.3
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• pp.304-309
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• 2008

Cryptand series ion exchange resins were synthesized with 1-aza-12-crown-4 macrocyclic ligand attached to styrene (4 series dangerous matter) divinylbenzene (DVB) copolymer with crosslink of 1％, 2％, 4％ and 8％ by a substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, electron micrograph, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of uranium (${UO_2}^{2+}$) ion were investigated. The uranium ion showed a fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium (${UO_2}^{2+}$) > nickel ($Ni^{2+}$) > gadolinium ($Gd^{3+}$) ion. The adsorption was in order of 1％, 2％, 4％, and 8％ crosslinked resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

• Analytical Science and Technology
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• v.22 no.1
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• pp.92-100
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• 2009

Azacrown resins were synthesized by mixing 1-aza-12-crown-4 macrocyclic ligand into styrene (2th petroleum in 4th class hazardous materials) divinylbenzene (DVB) copolymer with crosslinkage of 1%, 2%, 5% and 10% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, thermogravimetric analysis (TGA), surface area (BET), and IR-spectroscopy. The effects of pH, time, crosslinkage of resins and dielectric constant of solvent on adsorption of metal ions by resin adsorbent were investigated. Metal ions showed a great adsorption over pH 3 and adsorption equilibrium of metal ions was about two hours. In addition, adsorptive selectivity of metals on the resin in ethanol solvent was increased in the order of ${UO_2}^{2+}$ > $Ca^{2+}$ > $Sm^{3+}$ ion and adsorption of uranium ion was decreased with increase of crosslinkage such as 1%, 2%, 5% and 10% and was inversely proportional to the order of dielectric constant of solvents.

• Analytical Science and Technology
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• v.21 no.2
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• pp.109-116
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• 2008

Resins were synthesized by mixing 1-aza-18-crown-6 macrocyclic ligand into styrene(dangerous matter) divinylbenzene(DVB) copolymer with crosslink of 1%, 2%, 6% and 12% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, elemental analysis, thermogravimetric analysis, electron microscopy, and IR. The effects of pH, time, crosslink of resins and dielectric constant of solvent on adsorption of uranium ion by resin adsorbent were investigated. Uranium ion showed a great adsorption above pH 3 and adsorption equilibrium of metal ions was established in about two hours. In addition, adsorptive selectivity of resin in ethanol solvent was $UO{_2}^{2+}$ > $Zn^{2+}$ > $Lu^{3+}$ ion and adsorption of uranium ion increased with the increase of the degree of crosslinking (1%~12%) and was inversely in proportional to the order of dielectric constant of solvents.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.139-140
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• 2017

This technology employs a method of forming a single-ply PLUS waterproofing sheet layer comprised of applying a single-ply synthetic polymer layer on a vibrating structure (steel frame, RC) or an inclined surface by using a T joint lap-filling coil and an embedded metal coated sheet. The T - joint reinforcing lap-filling coil was used to block the ingress channel of the rainwater by applying the material in the vulnerable area where the three sides of the waterproof sheet overlapped. Conventional waterproofing techniques have a problem in that the waterproof sheet is pierced because the end portion of the waterproof sheet applied to the vertical portion is fixed by a nail, and the sealant applied to the end portion of the sheet cannot easily secure long-term waterproof durability due to the influence of the external environment. Therefore, the developed technology secured the waterproof durability against the vertical part by using the embedded metal sheet. In addition, automatic hot-air fusing is used to improve the quality of waterproof construction and point fixation method using fixed hardware. This is a technology that is not significantly restricted in the high degradation level regions of domestic waterproof construction environments in Korea such as low-temperature environment, wet floor.

• Journal of Conservation Science
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• v.30 no.2
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• pp.181-187
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• 2014

AThe studies on ceramic preservation have been conducted widely in various institutions such as national/ public museums and research labs as well as the excavation institutions and university museums. Although there are some differences in preservation methodologies and materials used across the institutions, the variation is minimal. Specifically, epoxy resin is mostly used for ceramic restoration for its high cohesiveness, low contraction and high strength although there are some variations in for Ceramic Preservation. The synthetic resin type used according to the type of damage in the ceramic. However, the yellowing or the change of color across the time after the restoration is the weakness of epoxy resin. In this study, we aim to develop a material which minimizes this yellowing of epoxy resin while enhancing its cohesiveness and strength as well as other physical properties. We made the new material to have similar properties with those used widely for the ceramic restoration, such as EPO-TEK301$^{(R)}$, L30$^{(R)}$, XTR-311$^{(R)}$ through comparative experiments. The cohesiveness of the newly developed resin was improved to 2.51(MPa), which is similar level of XTR-311$^{(R)}$ of the 2.30(MPa) but about 2x higher than the other resins EPO-TEK301$^{(R)}$, L30$^{(R)}$ (1.21 and 1.81 (MPa), respectively). Especially, the experiment on yellowing shows that the existing resins show the range of color change at 10~25(${\Delta}E^*ab$), but the new low yellowing epoxy resin has the color change value at 8.3 (${\Delta}E^*ab$), the value lowering the yellowing effect to 1 to 3 times of the existing epoxy resin, thereby solving the issue of generating sense of differences due to change of color or yellowing.

• Journal of the Korean Wood Science and Technology
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• v.44 no.3
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• pp.389-397
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• 2016

In this study, ethanol was produced from a biomass hydrolysate that had been treated by electrodialysis (ED) and Amberlite XAD resin to remove fermentation inhibitors. Most of the acetic acid (95.6%) was removed during the ED process. Non-ionizable compounds such as total phenolic compounds, 5-hydroxymethyl furfural, and furfural were effectively removed by the XAD resin treatment. Ethanol production was improved when the ED-treated hydrolysate was treated with XAD-4 resin for a short reaction time. The highest ethanol production from ED-treated hydrolysate was $6.16g/{\ell}$ (after 72 h of fermentation) when the treatment with XAD-4 resin was for 5 min. Among the lignin-derived fermentation inhibitors tested, syringaldehyde in low concentrations (1 and 2 mM) in the hydrolysate increased ethanol production, whereas a high concentration (5 mM) inhibited the ethanol production process. A synthetic medium containing syringaldehyde and ferulic acid was prepared to investigate the synergistic effect of inhibitors on ethanol fermentation. Ethanol production decreased in the mixture of 1 mM syringaldehyde and 1 mM ferulic acid, implying that the effect of ferulic acid on ethanol fermentation is comparable to that of syringaldehyde.