DOI QR코드

DOI QR Code

Adsorption of uranium(VI), calcium(II), and samarium(III) ions on synthetic resin adsorbent with styrene hazardous materials

스타이렌 위험물을 포함한 합성수지 흡착제에 의한 U(VI), Ca(II), Sm(III) 이온들의 흡착

  • Received : 2008.12.24
  • Accepted : 2009.02.10
  • Published : 2009.02.25

Abstract

Azacrown resins were synthesized by mixing 1-aza-12-crown-4 macrocyclic ligand into styrene (2th petroleum in 4th class hazardous materials) divinylbenzene (DVB) copolymer with crosslinkage of 1%, 2%, 5% and 10% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, thermogravimetric analysis (TGA), surface area (BET), and IR-spectroscopy. The effects of pH, time, crosslinkage of resins and dielectric constant of solvent on adsorption of metal ions by resin adsorbent were investigated. Metal ions showed a great adsorption over pH 3 and adsorption equilibrium of metal ions was about two hours. In addition, adsorptive selectivity of metals on the resin in ethanol solvent was increased in the order of ${UO_2}^{2+}$ > $Ca^{2+}$ > $Sm^{3+}$ ion and adsorption of uranium ion was decreased with increase of crosslinkage such as 1%, 2%, 5% and 10% and was inversely proportional to the order of dielectric constant of solvents.

1%, 2%, 5% 및 10%의 가교도를 가진 스타이렌(제4류 위험물중 제2석유류) 디비닐벤젠 공중합체에 1-aza-12-crown-4 거대고리 리간드를 치환반응으로 결합시켜 수지들을 합성하였다. 이들 수지의 합성은 염소 함량, 원소 분석, 열중량 분석, 비표면적(BET) 그리고 IR-분광법으로 확인하였다. 수지 흡착제에 의한 금속 이온들의 흡착에 미치는 pH, 시간, 수지의 가교도 그리고 용매의 유전상수에 따른 영향들을 조사하였다. 금속 이온들은 pH 3 이상에서 큰 흡착율을 보였으며, 금속 이온들의 흡착 평형은 2시간 정도였다. 한편, 에탄올 용매에서 수지에 대한 금속 이온의 흡착 선택성은 ${UO_2}^{2+}$ > $Ca^{2+}$ > $Sm^{3+}$ 이온이었고, 우라늄 이온의 흡착력은 1%, 2%, 5% 및 10%의 가교도 순으로 감소하였으며, 용매의 유전상수 크기에 반비례하였다.

Keywords

References

  1. L. F. Lindoy, K. R. Adam, D. S. Bladwine, A. Bashall, M. McPartlin and H. R. Powell, J. Chem. Soc., Dalton Trans., 237-246(1994)
  2. M. A. Ahearn, J. Kim, A. J. Leong, L. F. Lindoy, G. V. Meehan and O. A. Mattews, J. Chem. Soc., Dalton Trans., 3591-3599(1996)
  3. P. G. Grimslery, L. F. Lindoy, H. C. Lip, R. J. Smith and J. T. Baker, Aust. J. Chem., 30, 2095-2100(1977) https://doi.org/10.1071/CH9772095
  4. J. Kim. T. H. Ahn, M. R. Lee, M. H. Cho and S. J. Kim, J. Kor. Chem. Soc., 43(2), 167-171(1999)
  5. K. W. Chi, Y. S. Ahn, K. T. Shim, H. Huh and J. S. Ahn, Bull. Kor. Chem. Soc., 23(5), 688-694(2002) https://doi.org/10.5012/bkcs.2002.23.5.688
  6. H. K. Frensdorff, J. Am. Chem. Soc., 93(3), 4684-4692 (1971) https://doi.org/10.1021/ja00748a006
  7. H. C. Lip, L. F. Lindoy, J. H. Rea, R. J. Smith, K. Henrick, M. Mcpartin and P. A. Tasker, Inorg. Chem. 19(11), 3360-3365(1980) https://doi.org/10.1021/ic50213a030
  8. K. S. Huh and S. G. Sin, J. Korean. Ind. Eng. Chem., 9(5), 680-687(1998)
  9. Y. J. Park, K. K. Park, M. Y. Suh, S. K. Yoon, K. S. Choi, K. Y. Jee and W. H. Kim, J. Kor. Chem. Soc., 44(4), 305-311(2000)
  10. J. S. Lee and B. S. Choi, Analy. Sci & Tech., 21(4), 272-278(2008)
  11. G. Bombieri and G. Depaoli, Inorg. Chem. Acta., 18, 123-129(1976)
  12. T. Hayashita, J. H. Lee, S. Chem and R. A. Bartsch, Anal. Chem., 63(17), 1844-1851(1991) https://doi.org/10.1021/ac00017a032
  13. E. Blasius and K. P. Janzen, Pure & Appl. Chem., 54, 2115-2122(1982) https://doi.org/10.1351/pac198254112115
  14. E. Blasius and P. G. Maurer, Makromol. Chem., 178, 649-657(1977) https://doi.org/10.1002/macp.1977.021780302
  15. H. Otsuka, H. Najima, M. Takagi and K. Ueno, Anal. Chim. Acta, 147, 227-233(1983) https://doi.org/10.1016/0003-2670(83)80088-9
  16. H. B. Yang, J. G. Lim, E. H. Lee and J. H. Yoo, J. Korean. Ind. Eng. Chem., 10(1), 143-147(1999)
  17. H. Egawa, T. Nonaka and M. Ikari, J. Appl. Poly. Sci., 29, 2045-2053(1984) https://doi.org/10.1002/app.1984.070290613
  18. S. K. Park and J. T. Kim, J. Korean. Ind. Eng. Chem., 13(8), 765-771(2002)
  19. S. H. Lee, K. R. Kim, J. S. Shon, J. H. Yoo and H. S. Chung, J. Ind. Eng. Chem., 5(4), 296-301(1999)
  20. J. G. Oh, J. Kor. Chem. Soc., 48(2), 215-219(2004) https://doi.org/10.5012/jkcs.2004.48.2.215
  21. K. B. Chung, H. H. Kim and S. H. Chang, J. Ind. Eng. Chem., 6(1), 8-12 (2000)
  22. S. M. Howdle, K. Jerabek, V. Leocorbo, P. C. Marr and D. C. Sherrington, Polymer, 41, 7272-7279 (2000)
  23. M. Y. Suh, T. Y. Eom, I. S. Suh and S. J. Kim, Bull. Kor. Chem. Soc., 8(5), 366-371 (1987)
  24. Y. Marcus, 'Introduction to liquid state chemistry', John Wiley & Sons, London, (1977)
  25. C. J. Pederson, J. Am. Chem. Soc., 92(2), 386-391 (1970) https://doi.org/10.1021/ja00705a605