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http://dx.doi.org/10.5806/AST.2009.22.1.092

Adsorption of uranium(VI), calcium(II), and samarium(III) ions on synthetic resin adsorbent with styrene hazardous materials  

Kim, Joon-Tae (Department of Chemistry, Chosun University)
Publication Information
Analytical Science and Technology / v.22, no.1, 2009 , pp. 92-100 More about this Journal
Abstract
Azacrown resins were synthesized by mixing 1-aza-12-crown-4 macrocyclic ligand into styrene (2th petroleum in 4th class hazardous materials) divinylbenzene (DVB) copolymer with crosslinkage of 1%, 2%, 5% and 10% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, thermogravimetric analysis (TGA), surface area (BET), and IR-spectroscopy. The effects of pH, time, crosslinkage of resins and dielectric constant of solvent on adsorption of metal ions by resin adsorbent were investigated. Metal ions showed a great adsorption over pH 3 and adsorption equilibrium of metal ions was about two hours. In addition, adsorptive selectivity of metals on the resin in ethanol solvent was increased in the order of ${UO_2}^{2+}$ > $Ca^{2+}$ > $Sm^{3+}$ ion and adsorption of uranium ion was decreased with increase of crosslinkage such as 1%, 2%, 5% and 10% and was inversely proportional to the order of dielectric constant of solvents.
Keywords
1-aza-12-crown-4; macrocyclic ligand; crosslinkage; styrene divinylbenzene (DVB);
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