• The Journal of Korean Academy of Prosthodontics
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• v.52 no.3
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• pp.202-210
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• 2014

Purpose: The aim of this study was to evaluate the stress concentration and distribution whether restoring the cavity or not while restoring with metal ceramic crown on tooth with abfraction lesion using finite element analysis. Materials and methods: Maxillary first premolar was selected and made a total of 10 finite element model. Model 1 was natural tooth; Model 2 was tooth with metal ceramic crown restoration which margin was positioned above 2 mm from CEJ; Model 3 was tooth with metal ceramic crown restoration which margin was positioned on CEJ; Model 4 was natural tooth which has abfraction lesion; Model 5 and 6 had abfraction lesion and the other condition was same as model 2 and 3, respectively; Model 7 was natural tooth which had abfraction lesion restored with composite resin; Model 8 and 9 was tooth with metal ceramic crown after restoring on abfraction lesion with composite resin; Model 10 was restored tooth on abfraction lesion with composite resin and metal ceramic crown restoration which margin is positioned on lower border of abfraction lesion. Load A and Load B was also designed. Von Mises value was evaluated on each point. Results: Under load A or load B, on tooth with abfraction lesion, stress was concentrated on the apex of lesion. Under load A or load B, on tooth that abfraction lesion was restored with composite resin, the stress value was reduced on the apex. Conclusion: In case of abfraction lesion was restored with composite resin, the stress was concentrated on the apical border of restored cavity regardless of marginal position. It was favorable to place crown margin on the enamel for restoring with metal ceramic crown.

• Journal of the korean academy of Pediatric Dentistry
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• v.50 no.1
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• pp.104-112
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• 2023

A 3D-printed resin crown is a novel option for esthetic crown restoration for primary teeth, which are typically bonded with resin cement. The purpose of this study was to evaluate the bonding ability of a 3D printing resin and compare it with other indirect resin materials for crown fabrication. The shear bond strengths of two 3D printing resin materials, Graphy (GP) and NextDent (NXT), and two indirect resin materials, VIPI Block (VIPI) and MAZIC Duro (MZ), were compared in the study. For all materials, the shear bond strength at the interface between the surface of the resin material and resin cement was measured. The mean shear bond strength values of GP, NXT, MZ, and VIPI were 23.29 ± 3.88, 26.14 ± 4.67, 25.41 ± 4.03, and 18.79 ± 4.26 MPa, respectively. There was no significant difference among the SBSs of GP, NXT and MZ except for VIPI. The result of this study indicates that the 3D printing resin meets the essential requirement for clinical use by showing clinically adequate bond strength.

• The Journal of the Korean dental association
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• v.57 no.11
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• pp.679-688
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• 2019

A 8-year-old patient presented with a crown-root fracture of the maxillary right central incisor with an oblique subgingival fracture line. A multidisciplinary treatment approach including endodontic treatment, surgical extraction and intraalveolar repositioning was used to gain sufficient crown length of the fractured maxillary incisor. The coronally repositioned maxillary right central incisor was stabilized by a resin wire splint. Apexification using MTA was performed. Resin core and direct resin restoration(Cl IV) on fractured teeth was built up. Clinical and radiographic follow-up of the maxillary right central incisor after 36 months showed no signs of root resorption or pathology and acceptable aesthetics and functions were maintained. Surgical extrusion can be considered as a good treatment modality for young patients.

• Journal of environmental and Sanitary engineering
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• v.21 no.4 s.62
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• pp.49-60
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• 2006

The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 - divinylbenzene(DVB) with 1%, 2%, 4% and 8%-crosslinking and 1-aza-18-crown-6 macrocyclic ligand by copolymerization method. Content of chlorine in styrene-DVB copolymer was decreased as crosslink increased and it is because as crosslink increased 1%, 2%, 4% and 8% DVB content increased and crosslink density increased and cavity was reduced. Functional group of resin almost disappeared as C-C1 peak around $700cm^{-1}$ was substituted with 1-aza-18-C-6 macrocyclic ligand and new peak of C-N around $1020cm^{-1}$ appeared, so it was confirmed that styrene-DVB copolymer and ligand were compounded. As crosslink increased in the analysis of element contents, it resulted in the reduction of nitrogen content and it is because as crosslink increased, it led to the reduction of chlorine content in the process of substitution reaction and it affected macrocyclic ligand substituted. Thermo analysis curve of functional synthetic resin decomposed three part of 1-aza-18-C-6, styrene, and DVB. Form of functional synthetic resin showed distortion of its particles as macrocyclic ligand was introduced to styrene-DVB copolymer and hydrogen of ligand caused substitution with chlorine element of styrene molecule.

• Journal of environmental and Sanitary engineering
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• v.17 no.1
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• pp.63-68
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• 2002

Amount of styrene and divinylbenzene(DVB) was adjusted under injection of nitrogen, copolymer having crosslink of 1%, 2% and 5% was synthesized and zinc chloride was added to it. Put into benzene, swell it, add potassium iodide and 1-aza-15-crown-5 of 21.93g in toluene solution and functional resin which can adsorb heavy metal ions by stir reflex at $55^{\circ}C$ for 30 hours was synthesized. The content of divinylbenzene of this resin was increased as crosslink increase, macroporous gets smaller and the content of chlorine was reduced, which affects macrocyclic ligand in the process of substitution and content of nitrogen was also reduced. And the form of functional synthetic resin was distorted by substitution reaction of hydrogen and chlorine atoms.

• The Journal of Advanced Prosthodontics
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• v.7 no.6
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• pp.475-483
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• 2015

PURPOSE. The objective of this study was to evaluate the influence of various cement types on the stress distribution in monolithic zirconia crowns under maximum bite force using the finite element analysis. MATERIALS AND METHODS. The models of the prepared #46 crown (deep chamfer margin) were scanned and solid models composed of the monolithic zirconia crown, cement layer, and prepared tooth were produced using the computer-aided design technology and were subsequently translated into 3-dimensional finite element models. Four models were prepared according to different cement types (zinc phosphate, polycarboxylate, glass ionomer, and resin). A load of 700 N was applied vertically on the crowns (8 loading points). Maximum principal stress was determined. RESULTS. Zinc phosphate cement had a greater stress concentration in the cement layer, while polycarboxylate cement had a greater stress concentration on the distal surface of the monolithic zirconia crown and abutment tooth. Resin cement and glass ionomer cement showed similar patterns, but resin cement showed a lower stress distribution on the lingual and mesial surface of the cement layer. CONCLUSION. The test results indicate that the use of different luting agents that have various elastic moduli has an impact on the stress distribution of the monolithic zirconia crowns, cement layers, and abutment tooth. Resin cement is recommended for the luting agent of the monolithic zirconia crowns.

• The Journal of Korean Academy of Prosthodontics
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• v.30 no.3
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• pp.437-443
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• 1992

This study was performed to investigate the availability of adhesive resin cement for luting agent of cast crown. The resin cements used in this study were Panavia-Ex(Kuraray Co., Japan) and C & B-Metabond (Parkell Bio-Materials U.S.A.). Zinc phosphate cement was Flecks zinc cement(Mizzy Inc., U.S.A.) The film thickness of cast crown at gingival margin, lateral wall and occlusal surface was observed with measuring microscope(Modek MXT 70 Matsuzawa Seiki Co., Japan) and the retention of cast crown was measured with Instron Universal Test Machine (Instron Engineering Co., U.S.A.) The results were as follows : 1. The value of retention of cast crown was the highest in the use of Panavia-EX, followed by C & B-Metabond and 2inc phosphate cement, respectively. 2. There was no difference in film thickness among the three cements, but the film thickness in all cements was highest at occlusal surface.

• The Journal of Korean Academy of Prosthodontics
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• v.38 no.2
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• pp.214-225
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• 2000

The purpose of this study was to investigate the effects of investing conditions on the marginal discrepancy of conical telescope outer crown with Co-Cr-Ti alloy(Dentitan) and to compare the marginal discrepancy and the retention force of outer crowns using different pattern materials(plastic foil, casting wax, pattern resin). To evaluate the effects of investing conditions on the marginal discrepancy, patterns with plastic foil were invested under three different liquid/powder ratio conditions using phosphate bonded investment(Univest-nonprecious): standard, 10% decreased and 10% increased. At each liquid/powder ratio condition, metal ring was lined with single or double layers of ceramic ring liner. The marginal discrepancy of outer crown at different investing conditions was measured by ${\times}100$ compact measuring microscope(STM5, Olympus, Japan). For measurement of the marginal discrepancy and the retention force of outer crown using different pattern materials, the investing condition of 10% decreased liquid/powder ratio and double layers of ring liner was selected because this investing condition resulted in the best fit of outer crown. Marginal discrepancy was measured in the same way above and retention force on universal testing machine. Under the conditions of this study, the following conclusions were drawn: 1. The thickness of ring liner had more influence on the marginal discrepancy of outer crown than the liquid/powder ratio, and the acceptable marginal fitness could not be expected at the investing condition directed by investment manufacturer 2. There were no differences in the marginal discrepancy of outer crown among three different pattern materials(P>0.05). 3. Casting wax showed the greatest retention force(1640g) of outer crown, followed by pattern resin(1110g), plastic foil(820g). However, there was no significant difference between plastic foil and pattern resin(P>0.05). 4. Plastic foil showed the least variation in marginal discrepancy and retention force.

• The Journal of Korean Academy of Prosthodontics
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• v.42 no.1
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• pp.41-48
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• 2004

Statement of problem : The Cement as well as restoration required esthetics for making natural color restoration. Purpose : The purpose of this research is to evaluate color stability of restoration intermediated by resin cement which is used for cementation of all ceramic crown. Material and method : After making Empress 2 ingot into the size of $10mm{\times}10mm{\times}1mm$ according to indication, it glazed and made 48 Empress 2 blocks. Three kinds of resin cement(Rely-X, Variolink 2, Choice) having same shade cemented between Empress 2 blocks and Ivory shade tiles and made 48 specimens in the thickness of $30{\mu}m$ and $80{\mu}m$. After measureing color difference using spectorphotomenter, the result of this study were as follows. Results : The color difference of resin cement used in experiment increased in the order Rely-X, Variolink 2. As the thickness of cement increases, the color difference of all kinds of cement found statistically sifnificant difference but, this result is clinically acceptable. Conclusion : More resarch would have to be done in order to decrease the color difference as cement's thickness.

• Journal of Integrative Natural Science
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• v.10 no.1
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• pp.43-50
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• 2017

Synthetic resins were combined 1-aza-12-crown-4 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 8%, and 16% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on metal ion adsorption for resin adsorbent, the metal ions showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in ethanol solvent was the order of uranium ($UO_2{^{2+}}$) > cobalt ($Co^{2+}$) > dysprosium ($Dy^{3+}$) ion, adsorbability of the metal ion was the crosslink in order of 1%, 2%, 8%, and 16% and it was increased with the lower dielectric constant. In addition, theses metal ions could be separated in the column with 1% crosslink resin by using nitric acid (pH 2.0) as an eluent.