Browse > Article

Resin Synthesis of Adsorbent Uranium(VI) Ion using 1-Aza-18-Crown-6  

Kim, Sun-Hwa (Dept. of Environmental Engineering, Dongshin University)
Kim, Hae-Jin (Dept. of Oriental Medicine Materials, Dongshin University)
Publication Information
Journal of environmental and Sanitary engineering / v.21, no.4, 2006 , pp. 49-60 More about this Journal
Abstract
The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 - divinylbenzene(DVB) with 1%, 2%, 4% and 8%-crosslinking and 1-aza-18-crown-6 macrocyclic ligand by copolymerization method. Content of chlorine in styrene-DVB copolymer was decreased as crosslink increased and it is because as crosslink increased 1%, 2%, 4% and 8% DVB content increased and crosslink density increased and cavity was reduced. Functional group of resin almost disappeared as C-C1 peak around $700cm^{-1}$ was substituted with 1-aza-18-C-6 macrocyclic ligand and new peak of C-N around $1020cm^{-1}$ appeared, so it was confirmed that styrene-DVB copolymer and ligand were compounded. As crosslink increased in the analysis of element contents, it resulted in the reduction of nitrogen content and it is because as crosslink increased, it led to the reduction of chlorine content in the process of substitution reaction and it affected macrocyclic ligand substituted. Thermo analysis curve of functional synthetic resin decomposed three part of 1-aza-18-C-6, styrene, and DVB. Form of functional synthetic resin showed distortion of its particles as macrocyclic ligand was introduced to styrene-DVB copolymer and hydrogen of ligand caused substitution with chlorine element of styrene molecule.
Keywords
styrene; 1-aza-18-crown-6(1-aza-18-C-6); macrocyclic ligand; crosslink; divinylbenzene(DVB);
Citations & Related Records
연도 인용수 순위
  • Reference
1 C. A Davis, A. J. Leong, L. F. Lindoy, J. Kim and S. H. Lee, Lanthanide nitrate complexes of some macrocyclic polyethers, J. Aust. Chem. Soc., Dalton Trans., 51, 189-196, 1998
2 Z. U. Bae, S. B. Lee, S. H. Chang and U. R. Kim, Potentiometric determination of potassium Ion using 15-crown-5 derivatives with anthracence for the ion selective material, J. Kor. Chem. Soc., 45, 31-39, 2001
3 G. Bombieri and G. Depaoli, Crown ether complexes of actinide element, Inorg. Nucl. Chem., 18, 799-802, 1979
4 K. S. Huh and S. G. Sin, Preparation of glycidylmethacrylate-divinylbenzene copolymers contaning phosphoric acid groups and adsorption characteristics of uraniums. J. Kor. Ind. Eng. Chem., 9, 680-688, 1998
5 C. J. Pederson, Crystalline salt complexes of macrocyclic polyethers J. Am. Chem. Soc., 92, 386-394, 1969   DOI
6 S. K. Park and J. T. Kim, Adsorption of uranium ion utilizing cryptand ion exchange resin, Anal. Sci. & Tech., 17, 91-97, 2004
7 M. Nakajima, K. Kimura and T. Shono, Liquid chromatography of alkali and alkaline earth metal ions, Anal. Chem., 55, 463-469, 1983   DOI   ScienceOn
8 H. Egawa, T. Nonakaand M. lkari, Preparation of macroreticular chelating resms containing dihydroxyphosphino and/or phosphono groups and their adsorption ability for uranium, J. Appl. Poly. Sci., 29, 2045-2055, 1984   DOI   ScienceOn
9 L. F. Lindoy, K. R. Adam, D. S. Bladwine, A. Bashall, M. McPartlin, H. R. Powell, Metal-ion recognition. Donor-set control of silver, lead discrimination using mixed-donor macrocyclic ligand, J. Chem. Soc., Dalton Trans., 237-238, 1994
10 H. Otsuka, H. Najima, M. Takagi and K. Ueno, Anal. Extraction of alkali metal picrates by crown ethers having uncharged coordinating flexible side-chains, Chem. Acta., 147, 227-233, 1983   DOI
11 K. Kimura, H. Harino, E. Hayata and T. Shono, Ligued chromatography of alkali and alkaline-earth metal ions using octadecyclsilanized silica columns modified in situ with lipoihilic crown ethers, Anal. Chem. 58, 2233-2237, 1986   DOI   ScienceOn
12 T. Hayashita, J. H. Lee, S. Chem and R. A. Bartsch, Selective column concentration of alkali-metal cations with a crown ether carboxylic, Anal. Chem., 63, 1844-1850, 1991   DOI
13 M. A. Ahearn, J. Kim, A. J. Leong, L. F. Lindoy, G. V. Meehan and O. A. Mattews, Metal-ion recognition. The interaction of copper, silver and lead with 22-membered macrocycles incorporating N204-, N2S202- and N2S4-donor set, J. Chem. Soc., Dalton Trans., 3591-3594, 1996
14 E. Blasius, K.P. Janzen, M. Keller, H. Lander, T. Nguyen-Tien and G. Scholten, Austauscher mit cyclischen polyether als ankergruppen-1, Talanta, 27, 107-126, 1979   DOI   ScienceOn
15 S. K. Park and J. T. Kim, Adsorption of uranium ion on the 1-Aza-15-crown-5 synthetic resin adsorbent, J. Kor. Ind. Eng. Chem., 13, 765-770, 2002
16 E. Blasius and K. P. Janzen, Preparation and application of polymers with cyclic polymer anchor groups, Pure and Apply, Chem, 54, 2115-2128, 1982   DOI