Journal of Integrative Natural Science (통합자연과학논문집)

The Basic Science Institute Chosun University (조선대학교 기초과학연구원)
권호 표지
DOI QR코드

DOI QR Code

Adsorption and Separation of U (VI), Co (II), and Dy (III) Metal Ions on Crown Synthetic Resin

  • Kim, Joon-Tae (Department of Oriental Medicine Materials, Dongshin University)
  • Received : 2017.01.11
  • Accepted : 2017.03.25
  • Published : 2017.03.30
Download PDF
⟨ Previous Next ⟩

Abstract

Synthetic resins were combined 1-aza-12-crown-4 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 8%, and 16% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on metal ion adsorption for resin adsorbent, the metal ions showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in ethanol solvent was the order of uranium ($UO_2{^{2+}}$) > cobalt ($Co^{2+}$) > dysprosium ($Dy^{3+}$) ion, adsorbability of the metal ion was the crosslink in order of 1%, 2%, 8%, and 16% and it was increased with the lower dielectric constant. In addition, theses metal ions could be separated in the column with 1% crosslink resin by using nitric acid (pH 2.0) as an eluent.

Keywords

References

  1. K. W. Chi, Y. S. Ahn, K. T. Shim, H. Huh, and J. S. Ahn, "Synthesis of diazacrown ethers containing phenolic side arms and their complex with divalent metal ions", B. Korean Chem. Soc., Vol. 23, No. 5, pp. 688-692, 2002. https://doi.org/10.5012/bkcs.2002.23.5.688
  2. H. K. Frensdorff, "Salt complexes of cyclic polyethers. Distribution equilibriums", J. Am. Chem. Soc., Vol. 93, pp. 4684-4688, 1971. https://doi.org/10.1021/ja00748a006
  3. P. G. Grimslery, L. F. Lindoy, H. C. Lip, R. J. Smith, and J. T. Baker, "Synthesis of new 14-, 15- and 16membered crown compounds containing oxygen and nitrogen heteroatoms", Aust. J. Chem., Vol. 30, pp. 2095-2098, 1977. https://doi.org/10.1071/CH9772095
  4. J. D. Kim, "Extraction characteristics of heavy metals for soil washing of mine tailings-contaminated soil according to particle size distribution", Journal of the Korean Chemical Society, Vol. 19, No. 1, pp. 98-104, 2008.
  5. Y. G. Ha, "Decomposition of monazite sand", Journal of the Korean Chemical Society, Vol. 23, pp. 136-140, 1979.
  6. G. Bombieri and G. De paoli, "Crown ether complexes of actinide elements (an x-ray study of the conformational change of the crown ether within the $UO_2(NO_3)_2(H_2O)_2$ (18-crown-6) molecule)", Journal of Inorganic and Nuclear Chemistry, Vol. 40, pp. 799-802, 1978. https://doi.org/10.1016/0022-1902(78)80154-7
  7. T. Hayashita, J. H. Lee, S. Chen, and R. A. Bartsch, "Selective column concentration of alkali-metal cations with a crown ether carboxylic acid resin", Anal. Chem., Vol. 63, pp. 1844-1847, 1991. https://doi.org/10.1021/ac00017a032
  8. E. Blasius and P.-G. Maurer, "Darstellung von austauschern mit kryptanden als ankergruppen", Macromol. Chem. Phys., Vol. 178, pp. 649-657, 1977. https://doi.org/10.1002/macp.1977.021780302
  9. J. T. Kim, "Adsorption of uranium(VI), calcium(II), and samarium(III) ions on synthetic resin adsorbent with styrene hazardous materials", Analytical Science and Technology, Vol. 22, pp. 92-100, 2009.
  10. H. Egawa, T. Nonaka, and M. Ikari, "Preparation of macroreticular chelating resins containing dihydroxyphosphino and/or phosphono groups and their adsorption ability for uranium", J. Appl. Polym. Sci., Vol. 29, pp. 2045-2055, 1984. https://doi.org/10.1002/app.1984.070290613
  11. J. T. Kim, "Adsorption of uranium(VI) ion on 1aza-12-crown-4 synthetic resin with styrene hazardous material", J. Chosun Natural Sci., Vol. 6, pp. 104-110, 2013. https://doi.org/10.13160/ricns.2013.6.2.104
  12. M. Y. Suh, T. Y. Eom, and I. S. Suh, "Chromatographic behavior of cryptand[2,2] modified resin on metal cations", B. Korean Chem. Soc., Vol. 8, pp. 366-372, 1987.
  13. K. Joe, E.-H. Lee, K.-W. Kim, and K. Song, "Adsorption of an uranyl ion onto a divinylbenzene amidoxime resin in sodium carbonate solutions", Analytical Science & Technology, Vol. 21, pp. 326-331, 2008.
  14. K. C. Kang, S. S. Kim, M. H. Baik, S. H. Kwon, and S. W. Rhee, "Sorption of aqueous uranium(VI) ion onto a cation exchangeable K-birnessite collid", Analytical Science and Technology, Vol. 23, pp. 566-571, 2010. https://doi.org/10.5806/AST.2010.23.6.566
  15. J. T. Kim, "Adsorption characteristics of uranium(VI) ion on OenNdien resins with styrene hazardous material", Applied Chemistry for Engineering, Vol. 22, pp. 697-702, 2011.
  16. G. H. Roh and J. T. Kim, "Absorption and separation of Ca(II), Pb(II), and Nd(III) metal ions on synthetic resin adsorbent with styrene hazardous materials in reinforcement water fire extinguishing agent", Journal of environmental and sanitary engineering, Vol. 25, pp. 1-10, 2010.
  17. S. M. Howdle, K. Jerabek, V. Leocorbo, P. C. Marr, and D. C. Sherrington, "Reversibly collapsible macroporous poly(styrene-divinylbenzene) resin", Polymer, Vol. 41, pp. 7273-7277, 2000. https://doi.org/10.1016/S0032-3861(00)00018-5
  18. J. T. Kim, "Adsorption Characteristics of Al(III), Ni(II), Sm(III) ions on resin with styrene hazardous materials in reinforcementwater fire extinguishing agent", J. Chonsun Natural Sci., Vol. 6, pp. 151-157, 2013. https://doi.org/10.13160/ricns.2013.6.3.151
  19. C. J. Pedersen, "Crystalline salt complexes ofmacrocyclic polyethers", J. Am. Chem. Soc., Vol. 92, pp. 386-391, 1970. https://doi.org/10.1021/ja00705a605
  20. N. A. Lange, "Lange's handbook of chemistry", 13th, ed. J. A. Dean, New York: McGraw-Hill Book Company, pp. 9-65, 1985.

Cited by

  1. Adsorption Characteristics of U ranium (VI) Ion on Cryptand Synthetic Resin Adsorbent vol.10, pp.4, 2017, https://doi.org/10.13160/ricns.2017.10.4.225