• Korean Journal of Environmental Agriculture
• /
• v.3 no.2
• /
• pp.23-29
• /
• 1984

Agricultural soil samples collected from 121 sites (plastic film house 59, up-land 30 and orchard 32 sites) were evaluated by steam distillation and GLC-ECD analysis for organochlorine pesticides (${\gamma}-BHC$, heptachlor, p,p'-DDE, dieldrin, p,p'-DDD, and p,p'-DDT) in Jeollanam-Do area. Total residues of organochlorine pesticide in orchard, plastic film house and up-land were 0.415, 0.234 and 0.156ppm, respectively. Ninety-four percent of total residue was p,p'-DDT and its homologues (p,p'-DDE and p,p'-DDD). ${\gamma}-BHC$ was detected in all soil samples at $trace{\sim}0.050ppm$ range. Residue levels of organochlorine pesticide increased in the order of p,p'-DDE, ${\gamma}-BHC$, heptachlor, dieldrin, p,p'-DDT and p,p'-DDD.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.29 no.4
• /
• pp.18-27
• /
• 1997

This study was performed to obtained the optimal delignified condition of exploded wood on the acid hydrolysis with sulfuric acid. Wood chips of pine wood(Pinus desiflora), oak wood(Quercus serrata) and birch wood (Betula platyphylla var. japonica) were treated with a high pressure steam (20-30kgf/$\textrm{cm}^2$, 2-6 minutes). The exploded wood was delignified with sodium hydroxide and sodium chlorite, and then hydrolyzed with sulfuric acid. The result can be summerized as follows ; In the exploded wood treated with sodium hydroxide, the optimal concentration of sodium hydroxide was 1% as content of lignin in the exploded wood. Lignin content of exploded wood treated with sodium chlorite was lower then that sodium hydroxide. The maximum reducing sugar yield of exploded wood treated with 1% sodium hydroxide was lower than non-treated exploded wood. In the case of sodium chlorite treated, the maximum reducing sugar yield was hgher than non-treated exploded wood. Sugar composition of acid hydrolysis solution was composed of xylose and glucose residue, and the rate of glucose residue was increased in high pressure condition.

• Journal of the Korean Wood Science and Technology
• /
• v.17 no.3
• /
• pp.1-7
• /
• 1989

This study was performed to obtain the optimal condition that hydrolyzed exploded pine(Pinus densiflora), oak(Quercus serrata) and birch wood(Betula platyphylla var. japonica) by using sulfuric acid. The results obtained were summarized as follows: In hydrolysis of wood meal with sulfuric acid. maximum yield of sugar appeared that pine was 12 hours. oak and birch were 24 hours with 65% sulfuric acid. Futhermore, when wood meal and exploded woods were hydrolyzed with 65% sulfuric acid at $23^{\circ}C$ for 6 hours(primary hydrolysis), diluted to 3% and hydrolyzed again at $100^{\circ}C$ for 2 hours(secondary hydrolysis), the maximum sugar yield of wood meals were 6 hours. those of higher steam exploded pine wood was 3 hours. of lower steam exploded oak and birch woods were 6 hours. The sugar analyses of exploded wood showed that the amount of arabinose and xylose residue rapidly decreased. content of nemicelluose decreased with increase of steaming time and pressure.

• Microbiology and Biotechnology Letters
• /
• v.30 no.1
• /
• pp.98-102
• /
• 2002

Lignocellulosic wastes available in abundance can be excellent substrates for the production of cellulase. Different types of substrates and various pretreatments were used to improve the production of cellulase. The steam-exploded wood chip gave the highest activities of FPase (0.84 IU/mL) and CMCase (6.5 IU/mL) in the shake-flask culture. In 30 L bioreactor the steam-exploded wood chip and residue after saccharification gave the FPase activity (0.72 IU/mL) and the CMCase activity (6.3 IU/mL), respectively, similar those obtained in lactose.

• Applied Chemistry for Engineering
• /
• v.20 no.1
• /
• pp.62-66
• /
• 2009

Utilization and interest of unconventional fuel and process residue such as oil sand and its residue, oil sand coke, have been increased because of the continuous rise of fuel price and conventional fuel availability. In this study, the gasification of oil sand coke produced from coking process of oil sand was performed to utilize as an energy resource using lab-scale fixed bed gasification system. The combustion characteristics of oil sand bitumen and oil sand coke were investigated by using TGA and lab-scale gasification system was applied to reveal the characteristics of produced syngas composition with oxygen/fuel ratio, temperature and steam injection rate. Oil sand coke shows a high carbon content, heating value and sulfur content and low ash content and reactivity. In case of oil sand coke gasification, generally with increasing temperature, the amount of steam introduced and decreasing oxygen injection rate, $H_2$ content in product gas increased while the $CO_2$ content decreased. The calorific value of syngas shows about $2100kcal/Nm^3$ and this result indicates that the oil sand coke can be used as a resource of hydrogen and fuel.

• Applied Chemistry for Engineering
• /
• v.29 no.4
• /
• pp.468-473
• /
• 2018

In this study, the reforming reaction of vacuum residues (VR), high viscosity oil residues produced from vacuum distillation process of petroleum oil, was carried out using catalytic aquathermolysis reaction. VR showed a prone to decrease the amount of resins and asphaltenes in the constituents, and to increase saturates and aromatics when reacting with steam at 30 bar and above $300^{\circ}C$ for 24 h. When the amount of steam is not enough at this reaction, the asphaltene content in the products was rather increased after the reaction. As a result of the catalytic aquathermolysis using the metal oxide-zeolite catalyst with the decaline as a hydrogen donor, a 10% decrease in resin and asphaltene as well as a 10% increase in the aromatic hydrocarbon were observed. Consequently, the viscosity of VR decreased by 70% after the reaction. GC-Mass spectroscopy showed that the aquathermolysis of VR resulted in the decomposition of the resins and asphaltens into a low molecular weight material.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.36 no.8
• /
• pp.811-819
• /
• 2012

An air-cooled condenser is a device that is used for converting steam into condensate by using ambient air. The air-cooled condenser is prone to suffer from a serious explosion when the condensate inside the tubes of a heat exchanger is frozen; in particular, tubes can break during winter. This is primarily due to the structural problem of the tube outlet of an existing conventional air-cooled condenser system, which causes the backflow of residual steam and noncondensable gases. To solve the backflow problem in such condensers, such a system was simulated and a new system was designed and evaluated in this study. The experimental results using the simulated condenser showed the occurrence of freezing because of the backflow inside the tube. On the other hand, no backflow and freezing occurred in the advanced new condenser, and efficient heat exchange occurred.

• Korean Journal of Food Science and Technology
• /
• v.27 no.6
• /
• pp.860-865
• /
• 1995

This study was conducted to extract and isolate the polysaccharides from buckwheat. Also the sugar composition of the polysaccharides was investigated. The soluble and indigestible polysaccharides were isolated from supernatant and residue after enzyme treatment of raw, roast and steam buckwheat. The yields of low molecular weight soluble polysaccharides(LMS-P: MW<10 Kda) and high molecular weight soluble polysaccharides(HMS-P: MW>10 Kda) were $74.9{\sim}84.2%$ and $5.5{\sim}9.4%$, respectively. The yields of indigestible polysaccharides were low molecular weight insoluble polysaccharides; $0.8{\sim}4.2%$, crude hemicellulose; $3.2{\sim}9.6%$, alcohol insoluble hemicellulose; $0.9{\sim}1.7%$, residue; $2.0{\sim}2.4%$, respectively. The free sugars were detected in the soluble polysaccharides and low molecular weight insoluble polysaccharides but were not detected in the crude hemicellulose, alcohol insoluble hemicellulose and residue. The protein of all fraction were detected and the content was $1.0{\sim}18.9%$. The main sugar of soluble polysaccharides was glucose and the indigestible polysaccharides were composed of glucose, arabinose, rhamnose, xylose, mannose and galactose.

• Korean Journal of Environmental Agriculture
• /
• v.8 no.1
• /
• pp.7-16
• /
• 1989

Application of steam distillation on the analysis of pesticide residue in soil, water and crops was studied using the nitrogen distillation apparatus. Most pesticides which were extracted by organic solvents could be analyzed by the steam distillation method. For instance, distillations of PCNB, ${\gamma}-BHC$, ${\alpha}-or$ ${\beta}-endosulfan$, IBP, diazinon, fenthion, fenitrothion, alachlor, butachlor, pretilachlor, metolachlor, pendimethalin, benthiocarb and molinate were possible, but not simazine, atrazine and nitrofen. The optimum volume of distillate for a sufficient extraction of pesticide varied according to kind of pesticide. In general, the volume needed was little for carbamate, but much more for organochlorine. When the definite amount of distillate was obtained and then the condenser was washed by acetone, the optimum volume of distillate was less. Using the steam distillation method, the amount of organic solvent needed for one extraction of pesticide from soil, water and vegetable was less than the conventional solvent extraction method, and the analytical procedure became simpler. The process of concentration and clean up was mostly unnecessary, although a ghost peak was apparent in the gas chromatogram according to the kind of materials distilled.

• Journal of Energy Engineering
• /
• v.10 no.3
• /
• pp.188-194
• /
• 2001

The process simulations are made on the IGCC power plant using heavy residue oil from refinery process. In order to model combined power block of IGCC, the present study employs the gas turbine of MS7001FA model integrated with ASU (Air Separation Unit), and considers the air extraction from gas turbine and the combustor dilution by returned nitrogen from ASU. The exhaust gas energy of gas turbine is recovered through the bottoming cycle with triple pressure HRSG (Heat Recovery Steam Generator). Clean syngas fuel of the gas turbine is assumed to be produced through Shell gasification of Visbreaker residue oil and Sulfinol-SCOT-Claus gas cleanup processes. The process optimization results show that the best efficiency of IGCC plant is achieved at 20% air extraction condition in the case without nitrogen dilution of gas turbine combustor find at the 40% with nitrogen dilution. Nitrogen dilution of combustor has very favorable and remarkable effect in reducing NOx emission level, while shifting the operation point of gas turbine to near surge point.